Polymer films having improved heat sealing properties
A polymer composition comprising an ethylene alpha-olefin copolymer, wherein the polymer composition is characterized as having (a) a density in the range of from greater than about 0.910 g/cc to about 0.930 g/cc, as determined according to ASTM D1505; (b) a melt index in the range of from greater than about 0.5 g/10 min to about 3 g/10 min, as determined by ASTM D1238, Condition 190° C./2.16 kg; (c) a molecular weight distribution of from about 3.4 to about 12, as determined by gel permeation chromatography (GPC); (d) a weight average molecular weight of from greater than about 85 kg/mol to about 160 kg/mol, as determined by gel permeation chromatography (GPC); and (e) a z-average molecular weight of from greater than about 210 kg/mol to about 500 kg/mol, as determined by gel permeation chromatography (GPC).
1. A film prepared from an ethylene alpha-olefin copolymer having:
(a) a density in the range of from greater than about 0.910 g/cc to about 0.930 g/cc, as determined according to ASTM D1505;
(b) a melt index in the range of from greater than about 0.5 g/10 min to about 3 g/10 min, as determined according to ASTM D1238, Condition 190° C./2.16 kg;
(c) a molecular weight distribution of from about 3.4 to about 12, as determined by gel permeation chromatography;
(d) a weight average molecular weight of from greater than about 85 kg/mol to about 160 kg/mol, as determined by gel permeation chromatography;
(e) a z-average molecular weight of from greater than about 210 kg/mol to about 500 kg/mol, as determined by gel permeation chromatography;
(f) a ratio of high load melt index to melt index of from about 16 to about 30;
(g) less than 22 branches per 1000 carbon atoms; and
(h) a number average molecular weight of from about 7 kg/mol to about 50 kg/mol.
2. The film of claim 1 wherein the copolymer has a high load melt index of from about 10 g/10 min. to about 27 g/10 min.
3. The film of claim 1 wherein the copolymer has a zero shear viscosity of from about 3000 Pa·s to about 25000 Pa·s.
4. The film of claim 1 wherein the copolymer has a CY-a of from about 0.400 to about 0.600.
5. The film of claim 1 having a Elmendorf tear strength in the machine direction of from about 70 g/mil to about 300 g/mil.
6. The film of claim 1 having an Elmendorf tear strength in the transverse direction of from about 250 g/mil to about 650 g/mil.
7. The film of claim 1 having a seal initiation temperature of from about 85° C. to about 105° C.
8. A fabricated film article comprising an ethylene alpha-olefin copolymer having:
(a) a density in the range of from greater than about 0.910 g/cc to about 0.930 g/cc, as determined according to ASTM D1505;
(b) a melt index in the range of from greater than about 0.5 g/10 min to about 3 g/10 min, as determined according to ASTM D1238, Condition 190° C./2.16 kg;
(c) a molecular weight distribution of from about 3.4 to about 12, as determined by gel permeation chromatography;
(d) a weight average molecular weight of from greater than about 85 kg/mol to about 160 kg/mol, as determined by gel permeation chromatography;
(e) a z-average molecular weight of from greater than about 210 kg/mol to about 500 kg/mol, as determined by gel permeation chromatography;
(f) a ratio of high load melt index to melt index of from about 16 to about 30 such that the film article fabricated from the copolymer is characterized as having a hot tack initiation temperature of less than about 96° C., as determined according to ASTM F1921-98, method A; and
(g) less than 22 branches per 1000 carbon atoms,
wherein the film at 1 mil thickness has a dart drop strength of from 700 g to about 2000 g.
9. The film of claim 8 wherein the copolymer has a number average molecular weight of from about 7 kg/mol to about 50 kg/mol.
10. The film of claim 8 wherein the copolymer has a high load melt index of from about 10 g/10 min. to about 27 g/10 min.
11. The film of claim 8 wherein the copolymer has a zero shear viscosity of from about 3000 Pa·s to about 25000 Pa·s.
12. The film of claim 8 wherein the copolymer has a CY-a of from about 0.400 to about 0.600.
13. A fabricated film article comprising an ethylene alpha-olefin copolymer having:
(a) a density in the range of from greater than about 0.910 g/cc to about 0.930 g/cc, as determined according to ASTM D1505;
(b) a melt index in the range of from greater than about 0.5 g/10 min to about 3 g/10 min, as determined according to ASTM D1238, Condition 190° C./2.16 kg;
(c) a molecular weight distribution of from about 3.4 to about 12, as determined by gel permeation chromatography;
(d) a weight average molecular weight of from greater than about 85 kg/mol to about 160 kg/mol, as determined by gel permeation chromatography;
(e) a z-average molecular weight of from greater than about 210 kg/mol to about 500 kg/mol, as determined by gel permeation chromatography;
(f) a ratio of high load melt index to melt index of from about 16 to about 30 such that the film article fabricated from the copolymer is characterized as having:
(i) a hot tack initiation temperature of less than about 96° C., as determined according to ASTM F1921-98, method A; and
(ii) a hot tack initiation temperature range of greater than about 20° C., as determined according to ASTM F1921-95, method A; and
(g) less than 22 branches per 1000 carbon atoms,
wherein the film at 1 mil thickness has a dart drop strength of from 700 g to about 2000 g.
14. A method comprising forming the film of claim 13 into a package, placing an item into the package, and heat sealing the package to enclose the item placed therein.
15. The film of claim 1 wherein the copolymer melt index value lies within a range that spans less than 2.5 g/10 min, and wherein the copolymer ratio of high load melt index to melt index value lies within a range that spans 14 values.
16. The film of claim 13 wherein the copolymer has a number average molecular weight of from about 7 kg/mol to about 50 kg/mol.