IP Library Granted Patent US 9,181,653
Granted Patent B2
US 9,181,653 · App. 14/069,171 · Granted Nov 10, 2015

Method for producing modified cellulose

Inventors: Jouni Paltakari (Espoo, FI); Janne Laine (Espoo, FI); Monika Österberg (Espoo, FI); Ramjee Subramanian (Espoo, FI); Jan-Erik Teirfolk (Turku, FI)
Assignee: UPM-KYMMENE OYJ
D21C9/007D21H11/18D21H17/18D21H17/24D21H17/25Y10T428/298
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Quick Facts
Patent No.
US 9,181,653
App. No.
14/069,171
Granted
Nov 10, 2015
Kind
B2
Abstract

The present invention provides a method for producing modified nanofibrillated cellulose characterized by bringing cellulosic material into a fiber suspension, adsorbing a cellulose derivative or polysaccharide or polysaccharide derivative onto fibers in said fiber suspension under special conditions and subjecting the obtained fiber suspension derivative to mechanical disintegration. A modified nanofibrillated cellulose obtainable by a method of the present invention is provided. Furthermore, the invention relates to the use of said modified nanofibrillated cellulose.

Claims (25)

1. A method for producing modified nanofibrillated cellulose, comprising:

preparing a suspension containing fibers from cellulosic material;

adsorbing a cellulose derivative or polysaccharide or polysaccharide derivative onto the fibers in said suspension under special conditions; and

subjecting the fiber suspension comprising said cellulose derivative or polysaccharide or polysaccharide derivative to mechanical disintegration;

to obtain modified nanofibrillated cellulose modified with said cellulose derivative or polysaccharide or polysaccharide derivative.

2. The method according to claim 1 , wherein the cellulosic material is a pulp selected from the group consisting of a chemical pulp, mechanical pulp, thermo mechanical pulp and chemi-thermo mechanical pulp produced from wood, non-wood material or recycled fibers.

3. The method according to claim 2 , wherein wood is from softwood tree, hardwood tree, or a mixture of softwoods and hardwoods.

4. The method according to claim 1 , wherein the cellulose derivative is carboxymethyl cellulose.

5. The method according to claim 2 , wherein the cellulose derivative or polysaccharide or polysaccharide derivative is adsorbed onto the fibers prior to or during mechanical disintegration.

6. The method according to claim 3 , wherein the cellulose derivative or polysaccharide or polysaccharide derivative is adsorbed onto the fibers both prior to and during mechanical disintegration.

7. The method according to claim 1 , wherein the cellulose derivative or polysaccharide or polysaccharide derivative is adsorbed onto the fibers at a temperature of at least 5° C. up to 180° C.

8. The method according to claim 1 , wherein the cellulose derivative or polysaccharide or polysaccharide derivative is adsorbed onto the fibers at a temperature of 75° C.-80° C.

9. The method according to claim 1 , wherein the cellulose derivative or polysaccharide or polysaccharide derivative is adsorbed onto the fibers for at least 1 minute.

10. The method according to claim 1 , wherein the method takes place in the presence of monovalent or polyvalent cations.

11. The method according to claim 1 , wherein the pH value of the fiber suspension is at least pH 2 up to pH 12.

12. The method according to claim 1 , wherein the amount of added cellulose derivative or polysaccharide or polysaccharide derivative is at least 5 mg/g of fiber suspension up to 1000 mg/g of fiber suspension.

13. The method according to claim 1 , wherein mechanical disintegration is carried out with a refiner, grinder, homogenizer, colloider, friction grinder, fluidizer such as microfluidizer, macrofluidizer or fluidizer-type homogenizer.

14. The method according to claim 1 , wherein the fiber suspension is passed through mechanical disintegration at least once.

15. The method according to claim 1 , wherein the fiber suspension containing the cellulose derivative or polysaccharide or polysaccharide derivative is redispersed in water to a concentration of at least 0.1% up to 10% prior to mechanical disintegration.

16. The method according to claim 1 , comprising:

washing the fiber suspension comprising the cellulose derivative, polysaccharide or polysaccharide derivative with water prior to mechanical disintegration.

17. The method according to claim 16 , comprising:

removing the water from the fiber suspension comprising the cellulose derivative, polysaccharide or polysaccharide derivative to form a moist pulp cake prior to mechanical disintegration.

18. The method according to claim 17 , comprising:

redispersing the moist pulp cake in water prior to mechanical disintegration.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE FIFTH INVENTOR'S INCORRECT NAME OF TIERFOLK, JAN-ERIK PREVIOUSLY RECORDED ON REEL 032687 FRAME 0464. ASSIGNOR(S) HEREBY CONFIRMS THE FIFTH INVENTOR'S CORRECT NAME IS TEIRFOLK, JAN-ERIK. Recorded Apr 29, 2014
From: PALTAKARI, JOUNI; LAINE, JANNE; OSTERBERG, MONIKA; SUBRAMANIAN, RAMJEE; TEIRFOLK, JAN-ERIK
To: UPM-KYMMENE OYJ
Reel/Frame 032785/0058 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT ASSIGNEE ADDRESS ETELAESOKANADU 2 PREVIOUSLY RECORDED ON REEL 031588 FRAME 0874. ASSIGNOR(S) HEREBY CONFIRMS THE CORRECT ASSIGNEE ADDRESS IS ETELAESPLANADI 2. Recorded Apr 15, 2014
From: PALTAKARI, JOUNI; LAINE, JANNE; OSTERBERG, MONIKA; SUBRAMANIAN, RAMJEE; TIERFOLK, JAN-ERIK
To: UPM-KYMMENE OYJ
Reel/Frame 032687/0464 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 13, 2013
From: PALTAKARI, JOUNI; LAINE, JANNE; OSTERBERG, MONIKA; SUBRAMANIAN, RAMJEE; TEIRFOLK, JAN-ERIK
To: UPM-KYMMENE OYJ
Reel/Frame 031588/0874 →
Priority Claims (1)
FI 20095140 · Feb 13, 2009 · national
Continuity (2)
Division 13147346
Related Publication 20140182797A1 · Jul 3, 2014