Adhesive for rotor blades for wind power plants
The invention relates to two-component polyurethane compositions which have a long open time and, even alter extended exposure to a high-moisture climate (for example 70% relative humidity), even after 40 minutes, and in particular even after 60 minutes, can still be glued and cured to form polymers having high mechanical strength, whereby a structural adhesive bond is created. The composition comprises castor oil, at least one alkoxylated aromatic diol, at least one polyol having 5 to 8 hydroxyl groups, and at least one polyisocyanate. The two-component polyurethane compositions are suitable in particular for use as structural adhesives, in particular for the adhesive bonding of wing half-shells of rotor blades for wind power plants.
1. A two-component polyurethane composition consisting of a polyol component and a polyisocyanate component, wherein:
the polyol component comprises:
castor oil;
at least one alkoxylated aromatic diol;
at least one polyol with 5 to 8 hydroxyl groups; and
optionally, an aliphatic triol;
the polyisocyanate component comprises at least one polyisocyanate; and
a weight ratio of a total amount of the castor oil and the alkoxylated aromatic diol to a total amount of the polyol with 5 to 8 hydroxyl groups and the aliphatic triol is 1.5 to 3.0.
2. The two-component polyurethane composition according to claim 1 , wherein the alkoxylated aromatic diol is an ethoxylated and/or a propoxylated aromatic diol.
3. The two-component polyurethane composition according to claim 2 , wherein the alkoxylated aromatic diol is represented by the following formula (I):
in which
R 1 =CH 2 , CH(CH 3 ) or C(CH 3 ) 2 ,
R 2 =H and R 3 =methyl, or R 2 =methyl and R 3 =H,
n+n′+m+m′=1 to 20, and
the dotted lines show that the sequence of the alkylene glycol segments a 1 and a 2 that are connected to each other, and a 1′ and a 2′ that are connected to each other, is variable.
4. The two-component polyurethane composition according to claim 3 , wherein n=n′=0.
5. The two-component polyurethane composition according to claim 3 , wherein n+n′+m+m′=1 to 8.
6. The two-component polyurethane composition according to claim 3 , wherein R 1 =CH 2 or CH(CH 3 ).
7. The two-component polyurethane composition according to claim 1 , wherein the polyol with 5 to 8 hydroxyl groups is a polyetherpolyol based on a sugar.
8. The two-component polyurethane composition according to claim 7 , wherein the polyol with 5 to 8 hydroxyl groups is a polyetherpolyol based on sorbitol.
9. The two-component polyurethane composition according to claim 1 , wherein the polyol component comprises the aliphatic triol.
10. The two-component polyurethane composition according to claim 9 , wherein the aliphatic triol is an alkoxylated aliphatic triol.
11. The two-component polyurethane composition according to claim 10 , wherein the alkoxylated aliphatic triol has a molecular weight between 500 and 1,000 g/mol.
12. The two-component polyurethane composition according to claim 1 , wherein the polyisocyanate is an aromatic polyisocyanate.
13. The two-component polyurethane composition according to claim 1 , wherein the polyol component further comprises a polyamine in an amount of 1.5 to 2.5 wt %.
14. The two-component polyurethane composition according to claim 1 , wherein the polyol component further comprises a polyamine selected from the group consisting of 4,4′-methylene bis-(3-chloro,2,6-diethyl)-aniline, 4,4′-methylene bis(3-chloro-2,6-diethylaniline), 4,4′-methylene bis(2,6-diethylaniline), 4,4′-methylene bis(2,6-diisopropylaniline) and 4,4′-methylene bis(2-isopropyl-6-methylaniline).
15. The two-component polyurethane composition according to claim 1 , wherein a weight ratio of an amount of the castor oil to an amount of the alkoxylated aromatic diol is greater than or equal to 2.
16. The two-component polyurethane composition according to claim 1 , wherein the polyol component further comprises a polyamine in an amount of 0.5 to 5 wt %.
17. A method of adhering a plurality of substrate surfaces, the method comprising:
mixing the polyol component and the polyisocyanate component of the two-component polyurethane composition according to claim 1 ,
applying the mixed two-component polyurethane composition onto at least one of the substrate surfaces,
joining the substrate surfaces within an open time, and
curing the polyurethane composition.
18. The method according to claim 17 , wherein at least one of the substrates is formed of a plastic.
19. The method according to claim 17 , wherein at least one of the substrates is a mold part based on glass fibers and/or carbon fibers in a polyester matrix or polyepoxide matrix.
20. An adhered article formed by adhering the substrate surfaces by the method according to claim 17 .
21. A two-component polyurethane composition consisting of a polyol component and a polyisocyanate component, wherein:
the polyol component comprises:
castor oil;
at lead one alkoxylated aromatic diol;
at least one polyol with 5 to 8 hydroxyl groups; and
optionally, an aliphatic triol;
the polyisocyanate component comprises at least one polyisocyanate, and
a weight ratio of an amount of alkoxylated aromatic diol to a total amount of the castor oil, the polyol with 5 to 8 hydroxyl groups, and the aliphatic triol is 0.1 to 0.5.
22. A two-component polyurethane composition consisting of a polyol component and a polyisocyanate component, wherein:
the polyol component contains:
5-30 wt % castor oil,
2-15 wt % alkoxylated aromatic diol,
0.5-30 wt % polyol with 5 to 8 hydroxyl groups, and
0-30 wt % aliphatic triol, and
the polyisocyanate component comprises at least one polyisocyanate.
23. The two-component polyurethane composition according to claim 22 , wherein the polyol component contains:
10-25 wt % castor oil,
8-15 wt % alkoxylated aromatic diol,
1-10 wt % polyol with 5 to 8 hydroxyl groups, and
0-25 wt % aliphatic triol.
24. The two-component polyurethane composition according to claim 22 , wherein the polyol component contains 7-25 wt % aliphatic triol.