Polyolefin-based elastic meltblown fabrics
Disclosed herein is a process for forming a multilayer construction, and the multilayer constructions including at least one layer of an elastic meltblown fabric, the process comprising extruding one or more polyolefin polymer (e.g., a propylene-α-olefin copolymer) having a MFR from less than 90 dg/min through at least one die having a plurality of nozzles to form a plurality of continuous fibers, at least one die operating at a melt pressure from greater than 500 psi (3.45 MPa) to form at least one elastic meltblown fabric, and adhering the at least one elastic meltblown fabric to at least one extensible fabric.
1. A process for forming a multilayer construction comprising:
(a) forming a first spunbond layer;
(b) meltblowing to form at least one elastic meltblown layer comprising
(i) a propylene-α-olefin copolymer having a comonomer-derived content within the range from 5 to 35 wt % by weight of the copolymer, a peak melting temperature within the range from 10 to 105° C., and a MFR of less than 20 dg/min, wherein the elastic meltblown fabric has an Ultimate Elongation from greater than 300%, or
(ii) a propylene-α-olefin copolymer having a comonomer-derived content within the range from 5 to 35 wt % by weight of the copolymer, a peak melting temperature within the range from 10 to 105° C., and a MFR of less than 20 dg/min and H f value from less than 75 J/g;
wherein the propylene-α-olefin copolymer is meltblown at a melt pressure of from about 750 psi to about 2000 psi to form the elastic meltblown layer;
(c) forming a second spunbond layer; and
(d) adhering the elastic meltblown layer to the first and second spunbond layers, wherein the elastic meltblown layer is between the first and second spunbond layers; wherein the elastic meltblown layer is formed by meltblowing the one or more polyolefin polymer(s) directly upon at least one of the first or second spunbond layers; and wherein at least one of the first or second spunbond layers comprises spunlace.
2. The process of claim 1 , wherein the propylene-α-olefin copolymer possesses a molecular weight distribution within the range from 2.0 to 5.0.
3. The process of claim 1 , wherein the MFR of the propylene-α-olefin copolymer is within the range from 1 to 10 dg/min.
4. The process of claim 1 , wherein the elastic meltblown layer comprises fibers having a diameter within the range from 5 to 200 μm.
5. The process of claim 1 , wherein the number of continuous fibers per square inch (fiber density) of the elastic meltblown layer is within the range from 20 to 500 fibers/in 2 .
6. The process of claim 1 , wherein the elastic meltblown layer possesses an MD Elongation from less than 100% and a CD Elongation from greater than 100%.
7. The process of claim 1 , further comprising stretching or orienting the multilayer construction.
8. The process of claim 1 , wherein adhesives are substantially absent.
9. The process of claim 1 , wherein the elastic meltblown layer further comprises at least one of sodium benzoate, talc, oleamide, erucamide, carbon black, clay, talc, calcium carbonate, mica, silica, and silicate.
10. The process of claim 1 , wherein the spunbond layer comprising spunlace has a basis weight of from 10 to 150 g/m2.
11. The process of claim 1 , wherein the spunlace comprises polypropylene and polyolefin-terephthalate.
12. The process of claim 1 , wherein the propylene-α-olefin copolymer is meltblown at a melt temperature of from 200 to 275° C. to form the elastic meltblown layer.
13. The process of claim 1 , wherein the propylene-α-olefin copolymer is meltblown at a melt pressure of from 1200 psi to 1700 psi and a melt temperature of from 200 to 275° C. to form the elastic meltblown layer.