IP Library Granted Patent US 9,202,952
Granted Patent B2
US 9,202,952 · App. 13/884,552 · Granted Dec 1, 2015

Plasmon induced hot carrier device, method for using the same, and method for manufacturing the same

Inventors: Mark William Knight (Houston, TX); Heidar Sobhani Khakestar (Houston, TX); Peter Nordlander (Houston, TX); Nancy J. Halas (Houston, TX)
Assignee: William Marsh Rice University
H01L31/02363H01L31/0384H01L31/108
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Quick Facts
Patent No.
US 9,202,952
App. No.
13/884,552
Granted
Dec 1, 2015
Kind
B2
Abstract

In general, the invention relates to a unit that includes a semiconductor and a plasmonic material disposed on the semiconductor, where a potential barrier is formed between the plasmonic material and the semiconductor. The unit further includes an insulator disposed on the semiconductor and adjacent to the plasmonic material and a transparent conductor disposed on the plasmonic material, where, upon illumination, the plasmonic material is excited resulting the excitation of an electron with sufficient energy to overcome the potential barrier.

Claims (35)

1. A unit comprising:

a semiconductor;

a plasmonic material disposed on the semiconductor, wherein a potential barrier is formed between the plasmonic material and the semiconductor;

an insulator disposed on the semiconductor and adjacent to the plasmonic material; and

a transparent conductor disposed on the plasmonic material;

wherein, upon illumination, the plasmonic material is excited resulting an excitation of an electron with sufficient energy to overcome the potential barrier,

wherein the insulator contacts the semiconductor,

wherein the transparent conductor contacts a top surface of the insulator and the plasmonic material, and

wherein the insulator and the plasmonic material having a same thickness in between the transparent conductor and the semiconductor.

2. The unit of claim 1 , further comprising:

an ohmic contact bonded to the semiconductor, wherein the ohmic contact is electrically connected to a device and the transparent conductor.

3. The unit of claim 2 , wherein the device comprises one selected from a group consisting of a charge coupled device (CCD) and an ammeter.

4. The unit of claim 1 , wherein the transparent conductor is indium tin oxide.

5. The unit of claim 1 , wherein the plasmonic material comprises gold.

6. The unit of claim 1 , wherein the plasmonic material comprises a plurality of nano-rods.

7. The unit of claim 1 , wherein the semiconductor is an n-type semiconductor.

8. The unit of claim 7 , wherein the semiconductor comprises silicon.

9. The unit of claim 1 , wherein the plasmonic material comprises a gold layer and a titanium layer, wherein the titanium layer is interposed between the gold layer and the semiconductor.

10. The unit of claim 1 , wherein the plasmonic material comprises at least one selected from a group consisting of isolated nanostructures, independent aggregates of coupled nanostructures, a metal film with periodic variations, a metal film with embedded nanostructures, and a metal film with defects.

11. An apparatus, comprising:

plurality of units, wherein each unit comprises:

a semiconductor;

a plasmonic material disposed on the semiconductor, wherein a potential barrier is formed between the plasmonic material and the semiconductor;

an insulator disposed on the semiconductor and adjacent to the plasmonic material; and

a transparent conductor disposed on the plasmonic material;

wherein, upon illumination, the plasmonic material is excited resulting an excitation of an electron with sufficient energy to overcome the potential barrier,

wherein the insulator contacts the semiconductor,

wherein the transparent conductor contacts a top surface of the insulator and the plasmonic material, and

wherein the insulator and the plasmonic material having a same thickness in between the transparent conductor and the semiconductor.

12. The apparatus of claim 11 , wherein the plasmonic material comprises at least one selected from a group consisting of isolated nanostructures, independent aggregates of coupled nanostructures, a metal film with periodic variations, a metal film with embedded nanostructures, and a metal film with defects.

13. The apparatus of claim 11 , wherein the plasmonic material comprises a gold layer and a titanium layer, wherein the titanium layer is interposed between the gold layer and the semiconductor.

14. The apparatus of claim 11 , wherein the plasmonic material in each of the plurality of units comprises rods of different sizes.

15. The apparatus of claim 11 , wherein the plasmonic material in each of the plurality of units comprises rods of different orientations.

16. The apparatus of claim 11 , wherein the plasmonic material in each of the plurality of units comprises rods of different sizes and different orientations.

17. The apparatus of claim 11 , wherein the apparatus is a sensing device.

Assignments (1)
CONFIRMATORY LICENSE Recorded Apr 29, 2015
From: RICE UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 035522/0376 →
Continuity (2)
Provisional Application 61413136 · Nov 21, 2010
Related Publication 20130299933A1 · Nov 14, 2013