Hydroprocessing catalyst, preparation method thereof and use of same
The invention relates to a hydrocarbon hydroprocessing catalyst comprising a support based on at least one refractory oxide, at least one metal from group VIII and at least one metal from group VIB. The inventive catalyst is characterized in that it also comprises at least one organic compound having formula (I) or (II) in which each R 1 represents independently an alkyl group at C 1-18 , an alkenyl group at C 2-18 , an aryl group at C 6-18 , a cycloalkyl group at C 3-8 , an alkylaryl or arylalkyl group at C 7-20 , or the two R 1 groups together form a divalent group at C 2-18 , and R 2 represents an alkylene group at C 1-18 , an arylene group at C 6-18 , a cycloalkylene group at C 3-7 , or a combination of same. The invention also relates to a method of preparing one such catalyst and to the use thereof for hydroprocessing or hydrocracking.
1. A hydroprocessing catalyst for use in desulfurization, denitrogenation, dearomatization in the presence of hydrogen, and hydrocracking, comprising a carrier based on at least one refractory oxide, at least one metal of group VIII and at least one metal of group VIB of the Periodic Table of Elements, and at least one organic compound selected from C 1 -C 4 dialkyl succinates;
wherein the at least one organic compound is present in an amount of at least 0.001 to 10 moles per mole of metals of groups VIB and VIII; and
wherein the hydroprocessing catalyst has been subjected to a thermal treatment at a temperature between 60° C. and 180° C. following an impregnation step during preparation of the hydroprocessing catalyst.
2. The catalyst as claimed in claim 1 , wherein the at least one organic compound is dimethyl succinate.
3. A hydroprocessing catalyst for use in desulfurization, denitrogenation, dearomatization in the presence of hydrogen, and hydrocracking, comprising a carrier based on at least one refractory oxide, at least one metal of group VIII and at least one metal of group VIB of the Periodic Table of Elements, and at least one organic compound selected from C 1 -C 4 dialkyl succinates;
wherein the at least one organic compound is present in an amount of from 0.001 to 10 moles per mole of metals of groups VIB and VIII; and
wherein the hydroprocessing catalyst has been subjected to a thermal treatment at a temperature between 60° C. and 180° C. following an impregnation step during preparation of the hydroprocessing catalyst.
4. The hydroprocessing catalyst for use in desulfurization according to claim 3 , wherein the at least one organic compound is dimethyl succinate.
5. A hydroprocessing catalyst for use in desulfurization, denitrogenation, dearomatization in the presence of hydrogen, and hydrocracking, comprising a carrier based on at least one refractory oxide, at least one metal of group VIII and at least one metal of group VIB of the Periodic Table of Elements, and at least one organic compound selected from C 1 -C 4 dialkyl succinates, and
wherein the at least one organic compound is present in an amount of from 0.001 to 10 moles per mole of metals of groups VIB and VIII; and
wherein the hydroprocessing catalyst has been subjected to a thermal treatment at a temperature between 60° C. and 180° C. following an impregnation step during preparation of the hydroprocessing catalyst.
6. The hydroprocessing catalyst for use in desulfurization according to claim 5 , wherein the at least one organic compound is dimethyl succinate.
7. A method for preparing a hydroprocessing catalyst as claimed in claim 1 , comprising:
an impregnation step of bringing a nonmodified catalyst into contact with at least one organic compound selected from C 1 -C 4 dialkyl succinates, wherein the nonmodified catalyst comprises a carrier based on at least one refractory oxide, at least one metal of group VIII and at least one metal of group VIB; and
a step of subjecting the product of the impregnation step to a thermal treatment at a temperature between 60° C. and 180° C.
8. The method of preparation as claimed in claim 7 , characterized in that the nonmodified catalyst is a regenerated catalyst.
9. The method of preparation as claimed in claim 7 , characterized in that the impregnation step is followed by at least one maturation step carried out at a temperature of from 0 to 100° C. for a time between a few minutes and a few years.
10. The method of preparation as claimed in claim 7 , characterized in that the nonmodified catalyst is brought into contact with the at least one organic compound in the presence of at least one of a solvent or an acid.
11. The method of preparation as claimed in claim 10 , characterized in that the at least one organic compound is at least partially soluble in the solvent used.
12. The method of preparation as claimed in claim 10 , characterized in that the solvent is selected from water, toluene, xylenes, ethylene glycol, diethylene glycol, triethylene glycol, glycerol, ethanol, tert-butanol, polyethylene glycol (PEG), white spirit and petroleum ether.
13. The method of preparation as claimed in claim 12 , wherein the polyethylene glycol has a molecular weight from 118 to 1000.
14. The method of preparation as claimed in claim 13 , wherein the polyethylene glycol is triethylene glycol.
15. The method of preparation as claimed in claim 7 , characterized in that the nonmodified catalyst is brought into contact with the at least one organic compound ex situ outside the hydroprocessing reactor.
16. The method of preparation as claimed in claim 7 , characterized in that the nonmodified catalyst is brought into contact with the at least one organic compound in the presence of hydrogen and at least one sulfurization agent in a hydroprocessing reactor.
17. The method of preparation as claimed in claim 16 , wherein the sulfurization agent is selected from hydrogen sulfide, elemental sulfur, CS 2 , mercaptans, sulfides, polysulfides and hydrocarbon fractions with a boiling point of less than 400° C. containing sulfur compounds.
18. A method of using an activated hydroprocessing catalyst comprising
(i) a step of placing the hydroprocessing catalyst as claimed in claim 1 into contact with hydrogen and at least one sulfurization agent, and
(ii) a step of bringing the activated hydroprocessing catalyst obtained in step (i) into contact with hydrocarbons.
19. The method of using an activated hydroprocessing catalyst as claimed in claim 18 , wherein the sulfurization agent is selected from hydrogen sulfide, elemental sulfur, CS 2 , mercaptans, sulfides, polysulfides and hydrocarbon fractions with a boiling point of less than 400° C. containing sulfur compounds.
20. The method of using an activated hydroprocessing catalyst as claimed in claim 19 , characterized in that the sulfurization agent is dimethyl disulfide.
21. The method of using an activated hydroprocessing catalyst as claimed in claim 18 , wherein the hydrocarbons are derived from petroleum fractions with a boiling point of between 40 and 560° C.
22. The method of using an activated hydroprocessing catalyst as claimed in claim 18 , wherein the method is carried out during hydroprocessing or hydrocracking of the hydrocarbons.