Article having a relatively soft support material and a relatively hard decorative layer and also a method for its manufacture
The invention relates to an object comprising a relatively soft carrier material, optionally, an adhesive layer and/or an adhesive layer system, which are applied to the carrier material, and a relatively hard decorative layer. The object is characterized in that an intermediate layer is provided between the carrier material and the decorative layer and/or between the adhesive layer and the adhesive layer system and the decorative layer and comprises at least DLC (diamond like carbon) as the main component. The invention also relates to a method for producing said type of object.
1. An article having a relatively soft support material with a Vickers hardness (HV 0.025 ) of below 300, a bond layer or a bond layer system applied to the support material, and a relatively hard decorative layer having a hardness greater than the hardness of the support material, wherein
an intermediate layer which contains DLC, at least as a main component, is provided between the or the bond layer system and the decorative layer, the bond layer consisting of a metal layer which merges with a reducing proportion of metal and an increasing proportion of WC into a WC layer which is subsequently provided with a W—C:H layer on which the intermediate layer with the main component DLC bonds and with the metal of the metal layer being selected from the group comprising Cr, Ti, Al, Zr, V or combinations thereof.
2. An article in accordance with claim 1 , wherein the support material is selected from a group consisting of aluminium, brass, magnesium and stainless steel.
3. An article in accordance with claim 1 , wherein the bond layer consists of a Cr layer which merges with a reducing proportion of Cr and increasing proportion of WC into a WC layer which is subsequently provided with a W—C:H layer on which the intermediate layer with the main component DLC bonds.
4. An article in accordance with claim 1 , wherein the bond layer consists of a CrN layer, optionally in the form of a gradient CrN layer with a reducing proportion of Cr and an increasing proportion of N, which gradually merges into a WC layer, with the proportion of WC increasing in the direction away from the CrN layer and the WC layer subsequently being provided with a W—C:H layer on which the intermediate layer with the main component DLC bonds.
5. An article in accordance with claim 1 , wherein the bond layer consists of a Ti layer which merges with a reducing proportion of Ti and an increasing proportion of WC into a WC layer which is subsequently provided with a W—C:H layer on which the intermediate layer with the main component DLC bonds.
6. An article in accordance with claim 1 , wherein the bond layer is an organo-silicon layer which is for example deposited by means of a PACVD process onto a support material of plastic or metal.
7. An article in accordance with claim 1 , wherein the bond layer is a CuNi layer sequence which is deposited galvanically onto a support material of plastic or metal.
8. An article in accordance with claim 1 , wherein the decorative layer applied by means of PVD and/or CVD is a black layer of non-reactively applied Ti with a reactively attached coating of TiCrCN.
9. An article in accordance with claim 1 , wherein the decorative layer is a ZrCN layer deposited by means of PVD with a brass, gold, nickel or bronze colour.
10. An article in accordance with claim 1 , wherein the decorative layer is a TiCN layer with a gold, stainless steel, bronze or copper colour.
11. An article in accordance with claim 1 , wherein the decorative layer is a CrCN layer deposited by means of PVD with a stainless steel colour.
12. An article in accordance with claim 1 , wherein the decorative layer is a ZrCrCN layer deposited by means of PVD with an anthracite colour.
13. An article in accordance with claim 1 , wherein the support material consists of a metal or a metal alloy.
14. An article in accordance with claim 13 , wherein the metal is stainless steel with 16 to 18% Cr and 8 to 12% Ni.
15. An article in accordance with claim 1 , wherein the support material consists of at least one plastic.
16. An article in accordance with claim 15 , wherein the plastic is selected from the group consisting of ABS, polycarbonate, PMMA, polypropylene, polystyrene, polyethylene, polyamide or synthetic resin or mixtures of the above-named plastics including one or more of the above-named plastics with fibre reinforcement.
17. An article in accordance with claim 1 , wherein the decorative layer is an oxide or oxynitride layer having a rainbow colour such as blue or green deposited by means of PVD.
18. An article in accordance with claim 17 , wherein the oxide or oxynitride layer is an oxide or oxynitride of a metal of the group Ti, Cr or a combination of these metals.