Plasma reactor for carrying out gas reactions and method for the plasma-supported reaction of gases
A device for carrying out gas reactions, comprising a plasma reactor with a through-flow of gases which has a, particularly cylindrical, plasma chamber, wherein flow-forming elements for forming a flow of gases are arranged before and/or in and/or after the plasma reactor in order to form a gas stream within the plasma chamber such that at least one, particularly central, zone in the gas flow is formed which is flow-reduced. A method for carrying out gas reactions is also provided.
1. A method for carrying out gas reactions using a device comprising:
a plasma reactor having a plasma chamber for allowing a through-flow of gases;
and at least one flow-forming element for forming the through-flow of gases, the at least one flow-forming element being adjustably arranged;
said method comprising the steps of:
passing a stream of gas or of gasifiable substances through a microwave-excited plasma in the plasma chamber at a volume flow rate of 0.1 m 3 /h to 1000 m 3 /h, the gas stream comprising at least one reaction component which is converted while the gas stream is passed through the plasma chamber; and
adjusting the at least one flow-forming element to form at least one zone in the gas stream to reduce the velocity of the gas flow and allowing the plasma to remain stable.
2. The method according to claim 1 , wherein the at least one flow-forming element effects a rotation of the gas stream.
3. The method according to claim 1 , comprising the step of recovering heat that is generated by carrying out the gas reaction by using a heat exchanger integrated in a reaction tube axially arranged downstream of the plasma chamber.
4. The method according to claim 1 , further comprising the step of introducing gases or aerosols via nozzles, slots or tubes to control a temperature of the gas reaction.
5. The method according to claim 1 , wherein the microwave-excited plasma is pulse-operated.
6. The method according to claim 1 , wherein the microwave-excited plasma passed through the plasma chamber is non-thermal plasma.
7. The method according to claim 3 , and further comprising the step of recovering heat by a heat exchanger integrated in the reaction tube, wherein said heat exchanger comprises a black exchange surface.
8. The method according to claim 4 , wherein the gas includes hydrogen.
9. The method according to claim 4 , wherein the step of introducing the gases or aerosols comprises introducing the gases or aerosols to control the temperature in the reactor.
10. The method according to claim 5 , wherein the stream of gas or of gasifiable substances is pulse operated by pulse control in a microwave generator.
11. The method according to claim 5 , and further comprising the step of feeding microwave power into the plasma chamber through a resonator, and pulse-operating the plasma by pulsed coupling of the microwaves into the resonator at pulse frequencies of from 1 Hz to 50 Hz.
12. The method according to claim 1 , wherein the at least one flow-forming element is arranged at a position selected from the group consisting of before the plasma reactor, in the plasma reactor and after the plasma reactor.
13. The method according to claim 1 , wherein the at least one flow-forming element comprises a configuration selected from the group consisting of cones, drops, annular gaps, diaphragms, grids, baffle bodies, vortex tubes, cyclones and turbines.
14. The method according to claim 1 , wherein the flow forming elements are selected from the group consisting of nozzles, slots and tubes.
15. The method according to claim 2 , wherein the at least one zone in which the velocity of the gas flow is reduced is in the rotation center of the rotating gas stream.
16. The method according to claim 2 , wherein the at least one flow-forming element is selected from the group consisting of adjustable ring diaphragms, adjustable ring nozzles and tangentially feeding nozzles in annular arrangement.
17. The method according to claim 16 , wherein the plasma reactor has a gas inlet and a gas outlet, and said at least one flow-forming element is provided at the gas inlet or at the gas outlet.
18. The method according to claim 16 , wherein said plasma reactor has a reaction tube that is arranged axially after the reactor, and said at least one flow-forming element is provided at the beginning of the reaction tube.
19. The method according to claim 1 , wherein the plasma reactor has a reaction tube that is arranged axially after the reactor, and wherein the method further comprises the step of feeding a selected one of further reaction components, auxiliary gases or liquid substances into the reaction tube at the beginning of the reaction tube.
20. The method according to claim 1 , wherein the gas or gasifiable substance is selected from the group consisting of waste gases, residual gases from industrial processes, gaseous pollutants and vaporous pollutants.
21. The method according to claim 1 , wherein the gas or gasifiable substance is selected from the group consisting of CO 2 , N 2 , SF 6 , CF 4 , C 2 F 6 , H 2 O, H 2 , CO, hydrocarbons, fluorochlorinated hydrocarbons, fluorohydrocarbons, chlorohydrocarbons, dioxin, furans, crude oil and natural gases.
22. The method according to claim 1 , wherein the device has a reaction tube that is arranged axially after the reactor, and the method further comprises the step of introducing at least one catalyst into the reaction tube.
23. The method according to claim 1 , wherein the gas stream contains a suspension or a granulate to be conveyed through the plasma reactor.
24. The method according to claim 1 , wherein the gas stream is not impeded by any electrodes.