Highly corrosion-resistant and wear-resistant member with thermal sprayed layer formed thereon and thermal-sprayed layer forming powder for forming the same
Provided is a corrosion-resistant and wear-resistant member where a thermal-sprayed layer having corrosion resistance and wear resistance is formed on a surface of a metallic member which is brought into contact with a resin which generates a highly corrosive gas. Also provided is a thermal-spraying powder. The highly corrosion-resistant and wear-resistant member having a thermal-sprayed layer is one obtained by thermally spraying metallic powder on a metallic base material to form a thermal-sprayed layer on a surface of the metallic base material. The member is characterized in that the thermal-sprayed layer is a composite boride cermet of a tetragonal Mo 2 (Ni,Cr)B 2 -type or a tetragonal Mo 2 (Ni,Cr,V)B 2 -type. The powder for forming a thermal-sprayed layer is made of a composite boride cermet of a Mo 2 (Ni,Cr)B 2 -type and comprises 4.0 to 6.5 mass % of boron, 39.0 to 64.0 mass % of molybdenum, and 7.5 to 20.0 mass % of chromium, a balance being 5 mass % or more of nickel and unavoidable elements.
1. A method of manufacturing powder for forming a thermal-sprayed layer, the method comprising the steps of:
preparing
(1) mixed powder consisting of 4.0 to 6.5 mass % of B, 39.0 to 64.0 mass % of Mo, and 7.5 to 20.0 mass % of Cr, a balance being 5 mass % or more of Ni and unavoidable elements, wherein the ratio by mass % of Mo to B is 8.9-11.1, or
(2) mixed powder which contains 4.0 to 6.5 mass % of B, 39.0 to 64.0 mass % of Mo, 7.5 to 20.0 mass % of Cr, and 0.1 to 10.0 mass % of V, a balance being 5 mass % or more of Ni and unavoidable elements, wherein the ratio by mass % of Mo to B is 8.9-11.1;
wet grinding the mixed powder to make a wet ground powder;
granulating the wet ground powder to make a granulated powder; and
sintering the granulated powder at a temperature of 1000 to 1150° C. for 30 to 90 minutes, at a temperature elevation speed in the sintering of 0.5 to 60° C./min.
2. The method of claim 1 wherein the sintered granulated powder obtained comprises a composite boride cermet of a tetragonal Mo 2 (Ni,Cr,V)B 2 -type, and contains 4.0 to 6.5 mass % of B, 39.0 to 64.0 mass % of Mo, 7.5 to 20.0 mass % of Cr, and 0.1 to 10.0 mass % of V, a balance being 5 mass % or more of Ni and unavoidable elements.
3. The method of claim 1 wherein the ratio by mass % of Mo to B is 8.975 to 11.08.