Polyester resin for coating metal plate, resin-coated metal plate being coated with the same, and metal can and lid
A polyester resin for metal plate coating which contains a dimer acid in an amount of 2 to 10 mol %, as a dicarboxylic acid component and has a weight average molecular weight (Mw) ranging from 70,000 to 160,000. Thus, there can be provided a polyester resin for metal plate coating that has not only excellent film forming capability and corrosion resistance but also excellent impact resistance. Further, there can be provided a resin-coated metal plate excelling in properties, such as corrosion resistance, impact resistance (dent resistance), workability and flavor, and provided, fabricated from the resin-coated metal plate, a metal can and can lid.
1. A polyester resin for coating metal plate containing a fully-hydrogenated dimeric acid in an amount of 2 mol % to 4 mol % and an isophthalic acid in an amount of 1 to 15 mol % of the entire dicarboxylic acid component constituting the polyester resin, said polyester resin having a weight average molecular weight (Mw) in a range of 70,000 to 160,000 and a glass transition temperature in a range of 53 to 64° C., and a rate of crystallization at 185° C. of not higher than 0.014 sec −1 , and said hydrogenated dimeric acid comprising 23 mol % of aliphatic dimeric acid, 64 mol % of alicyclic dimeric acid and 13 mol % of aromatic dimeric acid.
2. A film comprising the resin of claim 1 .
3. A resin-coated metal plate coated with the resin of claim 1 .
4. The resin-coated metal plate according to claim 3 , comprising a layer of the polyester resin as a lower layer and further comprising an upper layer of a polyethylene terephthalate disposed on said lower layer having a composition different from that of the lower layer and including the isophthalic acid of the lower layer as a copolymerizable component.
5. A metal can made from the resin-coated metal plate of claim 3 .
6. A lid made from the resin-coated metal plate of claim 3 .