IP Library Granted Patent US 9,236,535
Granted Patent B2
US 9,236,535 · App. 14/001,443 · Granted Jan 12, 2016

Illumination devices

Inventors: Gerhard Wagenblast (Wachenheim, DE); Martin Koenemann (Mannheim, DE); Gerardus De Keyzer (Riehen, CH); Sorin Ivanovici (Heidelberg, DE); Michel Pepers (Neustadt, DE); Matthias Mueller (Pfungstadt, DE); Robert Send (Karlsruhe, DE)
Assignee: BASF SE
H01L33/502C09K11/06H05B33/10H05B33/14C09K2211/1007C09K2211/1011C09K2211/1014C09K2211/1029
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Quick Facts
Patent No.
US 9,236,535
App. No.
14/001,443
Granted
Jan 12, 2016
Kind
B2
Abstract

Illumination device comprising at least one LED and at least one color converter comprising at least one organic fluorescent colorant in a matrix consisting essentially of polystyrene or polycarbonate, wherein LED and color converter are present in a remote phosphor arrangement.

Claims (23)

1. An illumination device, comprising at least one LED and at least one colour converter comprising at least one organic fluorescent colorant in a matrix consisting essentially of polystyrene or polycarbonate, wherein the LED and the colour converter are present in a remote phosphor arrangement and wherein air, a noble gas, nitrogen, an other gas, or a mixture thereof are present between the colour converter and the LED.

2. The illumination device of claim 1 , wherein the at least one organic fluorescent colorant is an organic fluorescent dye.

3. The illumination device of claim 1 , Illumination wherein the at least one organic fluorescent colorant is a green-or red-or orange-fluorescing organic fluorescent dye.

4. The illumination device of claim 1 , wherein the at least one organic fluorescent colorant is a naphthalene or perylene derivative.

5. The illumination device of claim 1 , wherein the at least one organic fluorescent colorant is selected from the group consisting of

wherein:

R 1 is a linear or branched C 1 -C 18 alkyl radical, a C 4 -C 8 cycloalkyl radical which may be mono-or polysubstituted by halogen or by linear or branched C 1 -C 18 alkyl, or phenyl or naphthyl, where phenyl and naphthyl may be mono-or polysubstituted by halogen or by linear or branched C 1 -C 18 alkyl;

X represents substituents in the ortho and/or para position and is linear or branched C 1 to C 18 alkyl; and

y is a number from 0 to 3.

6. The illumination device of claim 5 , wherein the at least one organic fluorescent colorant is selected from the group consisting of N,N′-bis(2,6-diisopropylphenyl)-1,7-di(2,6-diisopropyl-phenoxy)perylene-3,4:9,10-tetracarboxdiimide, N,N′-bis(2,6-diisopropylphenyl)-1,6-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, 3,9-dicyanoperylene-4,10-bis(sec-butyl carboxylate), 3,10-dicyanoperylene-4,9-bis(sec-butyl carboxylate), 3,9-dicyanoperylene-4,10bis(isobutyl carboxylate), 3,10-dicyanoperylene-4,9-bis(isobutyl carboxylate), N-(2,6-di(isopropyl)phenyl)perylene-3,4-dicarboxylic monoimide, and a mixture thereof.

7. The illumination device according to claim 6 , wherein the at least one organic fluorescent colorant is selected from the group consisting of N,N′-bis(2,6-diisopropylphenyl)-1,7-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, N,N′-bis(2,6-diisopropylphenyl)-1,6-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide and a mixture thereof.

8. A color converter, comprising at least one organic fluorescent dye in a matrix consisting essentially of polystyrene or polycarbonate, wherein the at least one organic fluorescent dye is selected from the group consisting of N,N′-bis(2,6-diisopropylphenyl)-1,7-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, N,N′-bis(2,6-diisopropylphenyl)-1,6-di(2,6diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide,3,9-dicyanoperylene-4,10-bis(sec-butyl carboxylate),3,10-dicyanoperylene-4,9-bis(sec-butyl carboxylate), 3,9-dicyanoperylene-4,10-bis(isobutyl carboxylate), 3,10-dicyanoperylene-4,9-bis(isobutyl carboxylate), N-(2,6-di(isopropyl)phenyl)perylene-3,4-dicarboxylic monoimide, and a mixture thereof.

9. The color converter according to claim 8 , wherein the at least one organic fluorescent dye is selected from the group consisting of N,N′-bis(2,6-diisopropylphenyl)-1,7-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, N,N′-bis(2,6-diisopropylphenyl)-1,6-di(2,6-diisopropyl-phenoxy)perylene-3,4:9,10-tetracarboxdiimide, and a mixture thereof.

10. The color converter according to claim 8 , wherein the at least one organic fluorescent colorant is dissolved in the matrix.

11. The color converter of claim 8 , further comprising at least one inorganic white pigment as a scattering body.

12. The color converter of claim 8 , which is a film, a plaque or a sheet.

13. A process for producing the color converter of claim 8 , the process comprising dissolving the at least one organic fluorescent colorant in an organic solvent together with the matrix material and optionally scattering particles, and processing a resulting mixture into a film by removing the solvent.

14. The process of claim 13 , further comprising extruding and/or injection-molding the matrix with the at least one organic fluorescent colorant.

15. A process, comprising converting light produced by LEDs with at least one color converter according to claim 8 .

16. A remote phosphor structure, comprising the color converter of claim 8 and at least one LED.

17. An illumination device, comprising at least one LED and at least one colour converter comprising at least one organic fluorescent colorant in a matrix consisting essentially of polystyrene or polycarbonate, wherein the LED and the colour converter are present in a remote phosphor arrangement and wherein the at least one organic fluorescent colorant is selected from the group consisting of N,N′-bis(2,6-diisopropylphenyl)-1,7-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, N,N′-bis(2,6-diisopropylphenyl)-1,6-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, 3,9-dicyanoperylene-4,10-bis(sec-butyl carboxylate), 3,10-dicyanoperylene-4,9-bis(sec-butyl carboxylate), 3,9-dicyanoperylene-4,10-bis(isobutyl carboxylate), 3,10-dicyanoperylene-4,9-bis(isobutyl carboxylate), N-(2,6-di(isopropyl)phenyl)perylene-3,4-dicarboxylic monoimide, and a mixture thereof.

18. The illumination device according to claim 8 , wherein the at least one organic fluorescent colorant is selected from N,N′-bis(2,6-diisopropylphenyl)-1,7-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, N,N′-bis(2,6-diisopropylphenyl)-1,6-di(2,6-diisopropylphenoxy)perylene-3,4:9,10-tetracarboxdiimide, and a mixture thereof.

19. The illumination device according to claim 8 , wherein air, a noble gas, nitrogen, another gas, or a mixture thereof are present between the colour converter and the LED.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 28, 2013
From: WAGENBLAST, GERHARD; KOENEMANN, MARTIN; DE KEYZER, GERARDUS; IVANOVICI, SORIN; PEPERS, MICHEL; MUELLER, MATTHIAS; SEND, ROBERT
To: BASF SE
Reel/Frame 031099/0969 →
Priority Claims (2)
EP 11155901 · Feb 24, 2011 · regional
EP 11165344 · May 9, 2011 · regional
Continuity (2)
Provisional Application 61446139 · Feb 24, 2011
Related Publication 20130334546A1 · Dec 19, 2013