Polyacrylic acid-based water-absorbing resin powder and method for producing the same
A method for producing a polyacrylic water-absorbent resin powder includes the steps of: producing an acrylic monomer solution in which gas is dissolved and/or dispersed; polymerizing the monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent; during or after polymerizing, fragmenting the resulting hydrated gel crosslinked polymer; and drying the fragmented hydrated gel crosslinked polymer. The gas is dissolved and/or dispersed in the monomer solution by (a) applying pressure to the acrylic monomer solution and the gas; (b) creating swirling flows of the acrylic monomer solution and the gas; or (c) introducing the gas with the acrylic monomer solution via fine holes. The production method efficiently produces a water-absorbent resin having an excellent water-absorption rate without deteriorating a liquid-absorbent property of a sanitary product or the like.
1. A polyacrylic water-absorbent resin powder production method comprising the steps of:
producing an acrylic monomer solution in which gas is dissolved and/or dispersed;
polymerizing the acrylic monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent;
during or after the step of polymerizing, fragmenting a hydrated gel crosslinked polymer obtained by polymerizing the acrylic monomer solution; and
drying by heat the hydrated gel crosslinked polymer thus fragmented,
(1) the gas being dissolved and/or dispersed in the acrylic monomer solution by at least one of the methods (a) to (c):
(a) applying pressure to the acrylic monomer solution and the gas;
(b) creating swirling flows of the acrylic monomer solution and the gas; and
(c) introducing the gas with the acrylic monomer solution via fine holes,
(2) the acrylic monomer solution having a kaolin turbidity of more than 0 but not more than 1000 [mg/L (degree)], or
(3) the polyacrylic water-absorbent resin powder production method including a step of, after defoaming of the acrylic monomer solution to eliminate some of bubbles included in the acrylic monomer solution, polymerizing the acrylic monomer solution including the bubbles which acrylic monomer solution has been subjected to the defoaming.
2. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the acrylic monomer solution and inert gas are mixed with each other at a stirring Reynolds number of not less than 10000.
3. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein an acrylic monomer is polymerized by mixing the acrylic monomer solution with inert gas by use of a micro bubble generator whereby bubbles of the inert gas are suspended in the acrylic monomer solution.
4. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the defoaming lowers an expansivity of the acrylic monomer solution by not less than 0.01 times, and/or lowers a kaolin turbidity of the acrylic monomer solution by not less than 10 [mg/L (degree)].
5. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the polymerization is started with the acrylic monomer solution in which bubbles of inert gas which bubbles have a number average diameter of 50 nm to 500 μm are suspended.
6. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , being a method for continuously producing a water-absorbent resin by using the acrylic monomer solution of not less than 500 kg/hr.
7. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the gas dissolved and/or dispersed in the step of producing the acrylic monomer solution is inert gas.
8. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the defoaming defoams the acrylic monomer solution by letting the acrylic monomer solution stand for 10 seconds to 3600 seconds in an open system or stirring the acrylic monomer solution at 1 rpm to 100 rpm for 10 seconds to 3600 seconds in an open system.
9. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the gas and the acrylic monomer solution are pressurized at a pressure greater than atmospheric pressure in a tube or a device, and then subjected to a pressure equivalent to the atmospheric pressure.
10. The polyacrylic water-absorbent resin powder production method as set forth in claim 9 , wherein 0<T1<T where T1 is a time period from exposure to the atmospheric pressure to start of polymerization, and T is a time period from exposure to the atmospheric pressure to recovery of a kaolin turbidity obtained before the gas is dissolved or dispersed in the acrylic monomer solution.
11. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the step of producing the acrylic monomer solution is carried out by circulating in a circulation line the acrylic monomer solution supplied into a tank and injecting gas into the acrylic monomer solution in the circulation line,
the defoaming is carried out by flowing the acrylic monomer solution into the tank from the circulation line and storing the acrylic monomer solution in the tank until the acrylic monomer solution is re-flown out into the circulation line, and
the polyacrylic water-absorbent resin powder production method further comprises the step of neutralizing at least a part of the acrylic monomer solution supplied from the circulation line, so that the step of polymerizing polymerizes the acrylic monomer solution including the neutralized monomer solution.
12. The polyacrylic water-absorbent resin powder production method as set forth in claim 11 , wherein defoaming is such that the circulation tank has a headspace in which an oxygen concentration is not less than 1% by volume.
13. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the step of polymerizing the acrylic monomer solution is an expansivity of the acrylic monomer solution at a temperature and under a pressure where the polymerization of the acrylic monomer solution is started is not less than 1.0 time but not more than 1.1 times as great as that of an acrylic monomer solution in which gas is not dissolved and/or dispersed.
14. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the step of polymerizing the acrylic monomer solution is such that the acrylic monomer solution includes micro bubbles or nano bubbles having a volume average diameter of not less than 50 nm but not more than 100 μm.
15. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the polymerization of the acrylic monomer solution is started at not less than 40° C.
16. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein a temperature of the polymerization of the acrylic monomer solution the peak temperature is not less than 100° C.
17. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the polymerization of the acrylic monomer solution is the acrylic monomer solution having an acrylic monomer concentration of not less than 40% by weight.
18. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , further comprising the step of surface-crosslinking the polyacrylic water-absorbent resin powder after the step of drying it by heat.
19. The polyacrylic water-absorbent resin powder production method as set forth in claim 1 , wherein the acrylic monomer solution and the gas to which a shearing force is applied are pressurized at 0.1 MPa to 1 MPa, and then to atmospheric pressure.