Toothed belt
A toothed belt is provided that has excellent environment resistance, high load resistance, high stiffness, and achieves high accuracy, light weight, compactness and low noise. A toothed belt is provided with a belt body including a plurality of core wires juxtaposed in the width direction of a rubber portion, a plurality of tooth rubber portions formed on one surface of the belt body, and a tooth cloth covering the surface of the tooth rubber portions. The rubber portion contains dioctyl sebacate and trimellitic acid ester in a mass part ratio of 1:19 to 1:1, the mass percentage of the dioctyl sebacate to the whole quantity of the rubber portion is less than 4 mass %, and the mass percentage of the total quantity of the dioctyl sebacate and the trimellitic acid ester to the whole quantity of the rubber portion is in a range from 4 mass % to 8 mass %.
1. A toothed belt, comprising:
a belt body formed of a rubber portion containing hydrogenated nitrile rubber and a polymer alloy formed by dispersing zinc methacrylate in the hydrogenated nitrile rubber, and in which a plurality of core wires are embedded;
a tooth rubber portion more than one of which is juxtaposed on at least one surface of the belt body; and
a tooth cloth portion formed by impregnating a cloth with a rubber composition containing hydrogenated nitrile rubber, and covering the tooth rubber portion,
wherein the rubber portion contains dioctyl sebacate and trimellitic acid ester in a mass part ratio of 1:19 to 1:1, a mass percentage of the dioctyl sebacate to a whole quantity of the rubber portion is less than 4 mass %, and a mass percentage of a total quantity of the dioctyl sebacate and the trimellitic acid ester to the whole quantity of the rubber portion is in a range from 4 mass % to 8 mass %.
2. The toothed belt according to claim 1 , wherein in the hydrogenated nitrile rubber containing the hydrogenated nitrile rubber as a base polymer of the polymer alloy, a quantity of bound acrylonitrile is not more than 19 mass %, an iodine value is not more than 15 mg/100 mg, a Mooney viscosity at 100 deg C. is not less than 60, and a mass percentage of the hydrogenated nitrile rubber to the whole quantity of the rubber portion is in a range from 15 mass % to 50 mass %.
3. The toothed belt according to claim 1 , wherein the rubber portion contains a hydrogenated nitrile rubber whose Mooney viscosity at 100 deg C. is not less than 100, in a range from 3 mass % to 20 mass % to the whole quantity of the rubber portion.
4. The toothed belt according to claim 1 , wherein the rubber portion contains sulfur and a sulfenamide vulcanization accelerator in a mass part ratio of 1:10 to 1:2, and a mass percentage of a total quantity of the sulfur and the sulfenamide vulcanization accelerator to the whole quantity of the rubber portion is in a range from 0.3 mass % to 1 mass %.
5. The toothed belt according to claim 2 , wherein the rubber portion contains sulfur and a sulfenamide vulcanization accelerator in a mass part ratio of 1:10 to 1:2, and a mass percentage of a total quantity of the sulfur and the sulfenamide vulcanization accelerator to the whole quantity of the rubber portion is in a range from 0.3 mass % to 1 mass %.
6. The toothed belt according to claim 3 , wherein the rubber portion contains sulfur and a sulfenamide vulcanization accelerator in a mass part ratio of 1:10 to 1:2, and a mass percentage of a total quantity of the sulfur and the sulfenamide vulcanization accelerator to the whole quantity of the rubber portion is in a range from 0.3 mass % to 1 mass %.
7. The toothed belt according to claim 1 , wherein the rubber portion contains organic peroxide and a co-cross-linking agent in a mass part ratio of 4:1 to 20:1, and a mass percentage of a total quantity of the organic peroxide and the co-cross-linking agent to the whole quantity of the rubber portion is in a range from 4 mass % to 8 mass %.
8. The toothed belt according to claim 4 , wherein the rubber portion contains organic peroxide and a co-cross-linking agent in a mass part ratio of 4:1 to 20:1, and a mass percentage of a total quantity of the organic peroxide and the co-cross-linking agent to the whole quantity of the rubber portion is in a range from 4 mass % to 8 mass %.
9. The toothed belt according to claim 1 , wherein the rubber portion contains a carbon black with an average particle size of not more than 70 nm in a proportion of more than 0 mass % and not more than 20 mass % to the whole quantity of the rubber portion.
10. The toothed belt according to claim 4 , wherein the rubber portion contains a carbon black with an average particle size of not more than 70 nm in a proportion of more than 0 mass % and not more than 20 mass % to the whole quantity of the rubber portion.
11. The toothed belt according to claim 1 , wherein the rubber portion contains silicon dioxide in a range from 2 mass % to 5 mass % to the whole quantity of the rubber portion.
12. The toothed belt according to claim 4 , wherein the rubber portion contains silicon dioxide in a range from 2 mass % to 5 mass % to the whole quantity of the rubber portion.
13. The toothed belt according to claim 1 , wherein the rubber portion contains wax in a range from 0.3 mass % to 2 mass % to the whole quantity of the rubber portion.
14. The toothed belt according to claim 4 , wherein the rubber portion contains wax in a range from 0.3 mass % to 2 mass % to the whole quantity of the rubber portion.
15. The toothed belt according to claim 1 , wherein a woof index value of the cloth is not less than 370000, a total index value of the cloth is not more than 930000, and an index value ratio of the cloth is in a range from 70% to 130%, where
the woof index value=a yarn size (dtex)×a number of twist×a number of filaments×a thread count per inch,
a warp index value=a yarn size (dtex)×a number of twist×a number of filaments×a thread count per inch,
the index value ratio=the woof index value/the warp index value (%), and
the total index value=the woof index value+the warp index value.
16. The toothed belt according to claim 15 , wherein a lateral tensile strength of the cloth is not less than 500 N/3 cm, and
a proportion of an area of the tooth rubber portion to a total area of the tooth rubber portion and the tooth cloth portion viewed from a belt width direction is not less than 45%.
17. The toothed belt according to claim 4 , wherein a woof index value of the cloth is not less than 370000, a total index value of the cloth is not more than 930000, and an index value ratio of the cloth is in a range from 70% to 130%, where
the woof index value=a yarn size (dtex)×a number of twist×a number of filaments×a thread count per inch,
a warp index value=a yarn size (dtex)×a number of twist×a number of filaments×a thread count per inch,
the index value ratio=the woof index value/the warp index value (%), and
the total index value=the woof index value+the warp index value.
18. The toothed belt according to claim 1 , wherein the rubber composition with which the cloth is impregnated contains the following: hydrogenated nitrile rubber; epichlorohydrin rubber formed of a copolymer of epichlorohydrin and ethylene oxide or a ternary copolymer where allylglycidylether is copolymerized as a third component and an allyl group is introduced into a polymer main chain in a pendant form; hydrogenated carboxylic nitrile rubber; hydrophobic silica; blocked isocyanate; and phenolic resin.
19. The toothed belt according to claim 1 , wherein the core wire is formed by impregnating a carbon fiber with a treatment agent containing hydrogenated nitrile rubber, a zirconic coupling agent, hydrophobic silica, phenolic resin and potassium titanate, and drying them.
20. The toothed belt according to claim 1 , wherein the tooth cloth portion is formed so that a junction is at an angle of five degrees to 15 degrees to the belt width direction.