IP Library Granted Patent US 9,276,228
Granted Patent B2
US 9,276,228 · App. 13/957,612 · Granted Mar 1, 2016

Light-emitting element

Inventors: Satoshi Seo (Kanagawa, JP); Hiromi Seo (Kanagawa, JP); Tatsuyoshi Takahashi (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L51/5016H01L51/0072H01L51/0079H01L51/5004H01L51/5012H01L2251/552
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Quick Facts
Patent No.
US 9,276,228
App. No.
13/957,612
Granted
Mar 1, 2016
Kind
B2
Abstract

To provide a light-emitting element which uses a fluorescent material as a light-emitting substance and has higher luminous efficiency. To provide a light-emitting element which includes a mixture of a thermally activated delayed fluorescent substance and a fluorescent material. By making the emission spectrum of the thermally activated delayed fluorescent substance overlap with an absorption band on the longest wavelength side in absorption by the fluorescent material in an S 1 level of the fluorescent material, energy at an S 1 level of the thermally activated delayed fluorescent substance can be transferred to the S 1 of the fluorescent material. Alternatively, it is also possible that the S 1 of the thermally activated delayed fluorescent substance is generated from part of the energy of a T 1 level of the thermally activated delayed fluorescent substance, and is transferred to the S 1 of the fluorescent material.

Claims (33)

1. A light-emitting element comprising:

a pair of electrodes; and

an EL layer between the pair of electrodes,

wherein the EL layer comprises a light-emitting layer,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a fluorescent material,

wherein the first organic compound and the second organic compound form an exciplex which exhibits thermally activated delayed fluorescence, and

wherein, in the exciplex, a difference between levels of a triplet excited state and a singlet excited state is 0.2 eV or less.

2. The light-emitting element according to claim 1 , wherein light emission of the exciplex is overlapped with an absorption band on a lowest energy side of the fluorescent material.

3. The light-emitting element according to claim 2 , wherein a difference in energy between a peak wavelength of the absorption band on the lowest energy side of the fluorescent material and a peak wavelength of the exciplex is 0.2 eV or less.

4. The light-emitting element according to claim 2 , wherein a peak wavelength of light emission of the exciplex is longer than or equal to a peak wavelength of the absorption band on the lowest energy side of the fluorescent material.

5. The light-emitting element according to claim 2 , wherein a difference between a peak wavelength of light emission of the exciplex and a peak wavelength of light emission of the fluorescent material is 30 nm or less.

6. The light-emitting element according to claim 1 , wherein one of the first organic compound and the second organic compound is a material having an electron-transport property and the other is a material having a hole-transport property.

7. The light-emitting element according to claim 1 , wherein one of the first organic compound and the second organic compound is a n-electron deficient heteroaromatic compound and the other is a n-electron rich heteroaromatic compound or an aromatic amine compound.

8. The light-emitting element according to claim 1 , wherein the first organic compound is different from the second organic compound.

9. The light-emitting element according to claim 1 ,

wherein the exciplex generates the singlet excited state from the triplet excited state, and

wherein an energy is transferred to from a level of the singlet excited state of the exciplex to a level of a single exited state of the fluorescent material.

10. A light-emitting element comprising:

a pair of electrodes; and

an EL layer between the pair of electrodes,

wherein the EL layer comprises a light-emitting layer,

wherein the light-emitting layer comprises a thermally activated delayed fluorescence substance and a fluorescent material,

wherein the thermally activated delayed fluorescence substance comprises a first organic compound and a second organic compound, wherein the first organic compound and the second organic compound form and exciplex which exhibits thermally activated delayed fluorescence, and wherein, in the exciplex, a difference between levels of a triplet excited state and a singlet excited state is 0.2 eV or less.

11. The light-emitting element according to claim 10 , wherein light emission of the exciplex is overlapped with an absorption band on a lowest energy side of the fluorescent material.

12. The light-emitting element according to claim 11 , wherein a difference in energy between a peak wavelength of the absorption band on the lowest energy side of the fluorescent material and a peak wavelength of the exciplex is 0.2 eV or less.

13. The light-emitting element according to claim 11 , wherein a peak wavelength of light emission of the exciplex is longer than or equal to a peak wavelength of the absorption band on the lowest energy side of the fluorescent material.

14. The light-emitting element according to claim 11 , wherein a difference between a peak wavelength of light emission of the exciplex and a peak wavelength of light emission of the fluorescent material is 30 nm or less.

15. The light-emitting element according to claim 10 , wherein one of the first organic compound and the second organic compound is a material having an electron-transport property and the other is a material having a hole-transport property.

16. The light-emitting element according to claim 10 , wherein one of the first organic compound and the second organic compound is a π-electron deficient heteroaromatic compound and the other is a π-electron rich heteroaromatic compound or an aromatic amine compound.

17. The light-emitting element according to claim 10 , wherein the first organic compound is different from the second organic compound.

18. The light-emitting element according to claim 10 ,

wherein the exciplex generates the singlet excited state from the triplet excited state, and

wherein an energy is transferred to from a level of the singlet excited state of the exciplex to a level of a single exited state of the fluorescent material.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 2, 2013
From: SEO, SATOSHI; SEO, HIROMI; TAKAHASHI, TATSUYOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 030930/0916 →
Priority Claims (1)
JP 2012-172830 · Aug 3, 2012 · national
Continuity (1)
Related Publication 20140034930A1 · Feb 6, 2014