Methods for preparing and regenerating materials containing amorphous iron oxide hydroxide and desulfurizer comprising the same
Methods for preparing a composition containing amorphous iron oxide hydroxide. Methods for regeneration of the amorphous iron oxide hydroxide after it has been used as desulfurizer. Regenerable desulfurizer with high sulfur capacity containing amorphous iron oxide hydroxide, not less than 88% w/w, and organic binder not less than 7% w/w. The organic binder is sodium carboxymethylcellulose, sesbania powder, cellulose powder, or a mixture thereof A method for preparing the desulfurizer. A method for regenerating the waste agent produced after the desulfurizer and the composition containing the desulfurizer are used as desulfurizer. This method allows the desulfurizer and the composition containing the desulfurizer to be regenerated and reused avoiding the need for landfill disposal and environmental pollution.
1. A desulfurizer comprising 88-93 wt. % of a composition comprising amorphous iron oxide hydroxide and 7-12 wt. % of an organic binder, wherein the composition comprising amorphous iron oxide hydroxide is prepared according to the following steps:
(1) preparing a ferrous salt solution;
(2) mixing the ferrous salt solution with a carbonate solution, a bicarbonate solution, a carbonate solid, or a bicarbonate solid to form a first mixture, and allowing the first mixture to react to yield a second mixture;
(3) filtering the second mixture to remove generated soluble salt and yield a filter cake; and
(4) charging the filter cake with a gas comprising oxygen to yield the composition comprising the amorphous iron oxide hydroxide.
2. The desulfurizer of claim 1 , further comprising an additive.
3. The desulfurizer of claim 2 , wherein the desulfurizer is comprised of 88-92 wt. % of the composition comprising amorphous iron oxide hydroxide, 7-11 wt. % of the organic binder, and 1-5 wt. % of the additive.
4. The desulfurizer of claim 1 , wherein the organic binder is sodium carboxymethylcellulose, sesbania powder, cellulose powder, or a mixture thereof.
5. The desulfurizer of claim 2 , wherein the additive is sawdust powder, rice hull powder, wheat bran powder, or a mixture thereof.
6. The desulfurizer of claim 1 , wherein step (4) comprises forming a suspension comprising the filter cake produced in step (3), charging the suspension with air, and then filtering and drying the suspension to yield the composition comprising amorphous iron oxide hydroxide.
7. The desulfurizer of claim 1 , wherein step (4) comprises air-drying the filter cake produced in step (3) washing the filter cake with water, forming a suspension comprising the filter cake, and then filtering and drying the filter cake to yield the composition comprising amorphous iron oxide hydroxide.
8. The desulfurizer of claim 1 , wherein the pH value of the second mixture in step (2) is between 7.5 and 8.5.
9. The desulfurizer of claim 6 , wherein the filter cake constitutes between 5 wt. % and 30 wt. % of the suspension.
10. The desulfurizer of claim 7 , wherein the suspension is charged with air until ferrous iron in the suspension is less than 1 wt. % of total iron in the suspension.