Rubber composition and pneumatic tire
Provided are a rubber composition achieving balanced improvements in fuel economy, wet-grip performance, abrasion resistance, and handling stability, and a pneumatic tire including the composition. The rubber composition includes a rubber component including at least 95% by mass of conjugated diene polymers having a Tg of −75-0° C. and a Mw of 1.5×10 5 -1.5×10 6 , the rubber component (100% by mass) including 5-65% by mass of SBR (A) having a styrene content of at least 5% by mass but less than 15% by mass and a vinyl bond content of 10-70 mol %, and 20-75% by mass of SBR (B) having a styrene content of at least 15% by mass but less than 30% by mass and a vinyl bond content of 10-70 mol %, the composition including, per 100 parts by mass of the rubber component, 1-30 parts by mass of a low-molecular-weight conjugated diene polymer having a Tg of −75-0° C. and a Mw of at least 1.0×10 3 but less than 1.5×10 5 , and 10-150 parts by mass of silica having a N 2 SA of 40-400 m 2 /g, the composition having a tan δ peak temperature of at least −20° C.
1. A rubber composition comprising:
a rubber component including, based on 100% by mass of the rubber component:
5 to 65% by mass of styrene butadiene rubber (A) having a styrene content of 6 to 14% by mass and a vinyl bond content in a 1,3-butadiene moiety of 10 to 70 mol %;
20 to 75% by mass of styrene butadiene rubber (B) having a styrene content of 16 to 28% by mass and a vinyl bond content in a 1,3-butadiene moiety of 10 to 70 mol %; and
5 to 50% by mass of styrene butadiene rubber (C) having a styrene content of 32 to 40% by mass and a vinyl bond content in a 1,3-butadiene moiety of 10 to 70 mol %,
the rubber composition further comprising, for each 100 parts by mass of the rubber component:
1 to 30 parts by mass of a low molecular weight conjugated diene polymer having a glass transition temperature of −75 to 0° C. and a weight average molecular weight (Mw) of at least 1.0×10 3 but less than 1.5×10 5 ; and
10 to 150 parts by mass of a silica having a nitrogen adsorption specific surface area of 40 to 400 m 2 /g,
wherein said rubber composition comprises not less than 95% by mass of high molecular weight conjugated diene polymers having a glass transition temperature of −75 to 0° C. and a weight average molecular weight (Mw) of 1.5×10 5 to 1.5×10 6 , and
wherein said rubber composition has a tan δ peak temperature of not lower than −20° C.
2. The rubber composition according to claim 1 , wherein the low molecular weight conjugated diene polymer has a weight average molecular weight (Mw) of 1.0×10 3 to 5.0×10 3 .
3. The rubber composition according to claim 1 , wherein at least one of the styrene butadiene rubbers (A), (B), and (C) is obtained by
polymerizing a monomer component including styrene, 1,3-butadiene, and a silicon-containing vinyl compound in the presence of a polymerization initiator represented by the following formula (I):
wherein i represents 0 or 1; R 11 represents a C 1-100 hydrocarbylene group; R 12 and R 13 each represent an optionally substituted hydrocarbyl group or a trihydrocarbylsilyl group, or R 12 and R 13 are bonded to each other to form a hydrocarbylene group optionally containing at least one, as a hetero atom, selected from the group consisting of a silicon atom, a nitrogen atom, and an oxygen atom; and M represents an alkali metal atom, to produce a copolymer, and then
reacting a compound containing at least one of a nitrogen atom and a silicon atom with an active terminal of the copolymer.
4. The rubber composition according to claim 3 , wherein the styrene butadiene rubber (A) is obtained by
polymerizing a monomer component including styrene, 1,3-butadiene, and a silicon-containing vinyl compound in the presence of a polymerization initiator represented by the formula (I) to produce a copolymer, and then
reacting a compound containing at least one of a nitrogen atom and a silicon atom with an active terminal of the copolymer.
5. The rubber composition according to claim 3 , wherein R 11 in the formula (I) is a group represented by the following formula (Ia):
wherein R 14 represents a hydrocarbylene group comprising at least one of a structural unit derived from a conjugated diene compound and a structural unit derived from an aromatic vinyl compound; and n represents an integer of 1 to 10.
6. The rubber composition according to claim 5 , wherein R 14 in the formula (Ia) is a hydrocarbylene group comprising from one to ten isoprene-derived structural unit(s).
7. The rubber composition according to claim 3 , wherein the silicon-containing vinyl compound is a compound represented by the following formula (II):
wherein m represents 0 or 1; R 21 represents a hydrocarbylene group; and X 1 , X 2 , and X 3 each represent a substituted amino group, a hydrocarbyloxy group, or an optionally substituted hydrocarbyl group.
8. The rubber composition according to claim 1 , wherein the low molecular weight conjugated diene polymer is a copolymer of styrene and 1,3-butadiene, and has a vinyl bond content in a 1,3-butadiene moiety of 20 to 70 mol %.
9. The rubber composition according to claim 1 , wherein the low molecular weight conjugated diene polymer is a copolymer of styrene and 1,3-butadiene, and has a styrene content of 10 to 45% by mass.
10. A pneumatic tire, formed from the rubber composition according to claim 1 .