IP Library › Granted Patent US 9,290,422
Granted Patent B2
US 9,290,422 · App. 13/686,328 · Granted Mar 22, 2016

Hybrid plant for liquid fuel production

Inventors: Raymond F. Drnevich (Clarence Center, NY); Shrikar Chakravarti (East Amherst, NY); Minish M. Shah (East Amherst, NY)
Assignee: PRAXAIR TECHNOLOGY, INC.
C07C1/12C01B3/382C07C29/1518C10G2/30C10K1/003C10K1/005C10K3/06C01B2203/0233C01B2203/0244C01B2203/0283C01B2203/043C01B2203/0475C01B2203/062C01B2203/0811C01B2203/1241C01B2203/1258C01B2203/142C01B2203/148C10J3/721C10J2300/1659C10J2300/1665C10J2300/1678C10J2300/1815C10J2300/1838C10K3/04
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,290,422
App. No.
13/686,328
Granted
Mar 22, 2016
Kind
B2
Abstract

A hybrid plant and method for producing liquid fuel product from hydrogen and carbon monoxide containing streams produced by gasifying solid carbonaceous feedstock and steam reforming of light fossil fuels. When a gasification unit in the hybrid plant is operating at reduced capacity or is not operational, oxygen that would have been used in the gasification unit is diverted to a light fossil fuel conversion unit containing an autothermal reformer to increase H 2 -rich syngas flow to a liquid fuel production unit and maintain liquid fuel production at near nameplate capacity.

Claims (16)

1. A method of operating a hybrid plant, where a gasification unit in the hybrid plant is operating at less than its design capacity or is not operational, comprising:

a) increasing a light fossil fuel feed to a light fossil fuel conversion unit of the hybrid plant;

b) increasing oxygen input to an autothermal reformer in said fossil fuel conversion unit by diverting at least a portion of oxygen that would have been fed to said gasification unit, conditioned on the autothermal reformer temperature and exiting volumetric gas flow not to exceed a design value;

c) decreasing said light fossil fuel conversion unit steam to carbon ratio, and

d) producing a liquid fuel product at a production rate between 70% to 110% of the hybrid plant design production rate.

2. A method according to claim 1 , wherein at least 10% of the oxygen that would have been fed to said gasification unit is diverted to said light fossil fuel conversion unit.

3. A method according to claim 1 , wherein the steam to carbon ratio in step (c) is greater than 0.4.

4. A method according to claim 1 , wherein the additional light fossil fuel feed to the light fossil fuel conversion unit in step (a) is introduced into an autothermal reformer in the light fossil fuel conversion unit.

5. A method according to claim 1 , wherein the additional light fossil fuel feed to the light fossil fuel conversion unit in step (a) is introduced into a steam methane reformer coupled to a downstream autothermal reformer in the light fossil fuel conversion unit.

6. A method according to claim 1 , wherein the additional light fossil fuel feed to the light fossil fuel conversion unit in step (a) is divided into two streams, where the first stream is fed to a steam methane reformer coupled to a downstream autothermal reformer in the light fossil fuel conversion unit and the second stream is fed directly to said downstream autothermal reformer.

7. A method according to claim 1 , wherein a hydrogen and carbon monoxide containing H 2 — rich syngas produced in the light fossil fuel conversion unit is further treated to recover a hydrogen product.

8. A method according to claim 1 , wherein oxygen input diverted from the gasification unit to the light fossil fuel conversion unit is from an air separation unit within the hybrid plant or from an air separation unit external to the hybrid plant.

9. A method according to claim 1 , wherein a CO 2 stream is recycled from a CO 2 removal unit in the hybrid plant to the autothermal reformer.

10. A method according to claim 1 , wherein a CO 2 stream is recycled from a CO 2 removal unit in the hybrid plant to a steam methane reformer in the light fossil fuel conversion unit.

11. A method according to claim 1 , wherein a CO 2 stream is recycled from a CO 2 removal unit in the hybrid plant to both, a steam methane reformer coupled to a downstream autothermal reformer in the light fossil fuel conversion unit and to said downstream autothermal reformer.

12. A method according to claim 9 , wherein a hydrogen and carbon monoxide containing H 2 — rich syngas flow exiting said CO 2 removal unit does not exceed a design value.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 21, 2013
From: DRNEVICH, RAYMOND F.; CHAKRAVARTI, SHRIKAR; SHAH, MINISH M.
To: PRAXAIR TECHNOLOGY, INC.
Reel/Frame 029850/0969 →
Continuity (1)
Related Publication 20140148519A1 · May 29, 2014