Impact resistant modified compositions

1. A polymerizable composition, comprising

i) at least one benzoxazine compound and

ii) at least one polyether compound, consisting of one or more structural elements of the general formula (I) having terminal groups independently selected from hydroxyl, carboxyl, amino, thiol, oxirane, aziridine or thiirane groups,

in which n is a number from 5 to 10,000, each residue R a in each repeating unit independently denotes a divalent group of compounds comprising 1 to 100 C atoms, each residue X′ in each repeating unit is independently selected from —O—, —S—, —NH— or a carboxyl group of the general form —(C═O)O—, in which the C atom of the carboxyl group is always connected to the residue A, each residue Y in each repeating unit is independently selected from —OH, —SH and —NH 2 and each residue A in each repeating unit is independently selected from K or L, K denoting a divalent residue of aromatic dihydroxyl compounds following removal of both hydroxyl groups and L denoting a divalent residue of polyethers following removal of two terminal hydroxyl groups, with the proviso that, relative to the total number of all residues A in the polyether compound, 20 to 80% of all residues A denote K and 20 to 80% of all residues A denote L, wherein the polyether compound is free of oligomeric or polymeric urethane groups.

2. The polymerizable composition according to claim 1 , wherein the oligomeric or polymeric urethane group-free polyether compound is selected from compounds of the general formula (II),

in which E is selected from hydrogen or residues of the general formula (III),

F is selected from hydrogen or residues of the general formula (IV),

in which each residue W is independently selected from —O—, —S— or —NH— and the residues A, X′, R a and Y and n are each as defined in claim 1 .

3. The polymerizable composition according to claim 1 , wherein each residue R a in formula (I), (II), (Ill) or (IV) independently denotes a methylene group.

4. The polymerizable composition according to claim 1 , wherein each residue X′ in formula (I), (II) or (IV) independently denotes —O—.

5. The polymerizable composition according to claim 1 , wherein the residue Y in formula (I), (II) or (IV) denotes —OH.

6. The polymerizable composition according to claim 1 , wherein the residue W in formula (III) or (IV) denotes —O—.

7. The polymerizable composition according to claim 1 , wherein K denotes a residue selected from divalent residues of the general formula (V) or formula (VI),

in which i and j independently of each other denote a number from 0 to 4, R b and R c are selected independently of each other from halogen, C 1-40 alkyl, C 2-40 alkenyl, C 1-40 alkoxyl or C 7-13 aralkyl or divalent residues that make a corresponding naphthyl structure from the phenyl structure, and Q is selected from alkylene, oxygen, sulfur, sulfoxide, sulfone or a direct, covalent bond.

8. The polymerizable composition according to claim 1 , wherein L denotes a residue selected from divalent residues of the general formula (VII),

in which I denotes a number from 0 to 5000, each I′ in formula (VII) and in each repeating unit independently denotes a number from 1 to 10, each R in formula (VII) and in each repeating unit is independently selected from hydrogen or linear or branched optionally substituted C 1-12 alkyl groups.

9. A polymerizable composition, comprising

i) at least one benzoxazine compound and

ii) at least one polyether compound,

wherein the compound is free of oligomeric or polymeric urethane groups,

obtainable by reacting at least one component A with at least one component B,

component A being selected from the group consisting of

(A-1) aromatic compounds having at least two aromatic hydroxyl, carboxyl, amino or thiol groups and

(A-2) polyethers having at least two terminal hydroxyl, carboxyl, amino or thiol groups,

and component B being selected from the group consisting of

(B-1) polyethers having at least two terminal oxirane, aziridine or thiirane groups and

(B-2) aromatic compounds of the general formula (VIII)

in which each residue R d and R e independently denotes a divalent group of compounds comprising 1 to 100 C atoms, each residue X′ is independently selected from —O—, —S—, —NH— or a carboxyl group of the general form —(C═O)O—, in which the C atom of the carboxyl group is always connected to the residue D, W is selected from —O—, —S— or —NH— and the residue D comprises at least one aromatic group,

with the proviso that the exclusive reaction of one or more components satisfying the definition of (A-1) with one or more components satisfying the definition of (B-2) and the exclusive reaction of one or more components satisfying the definition of (A-2) with one or more components satisfying the definition of (B-1) is excluded.

10. The polymerizable composition according to claim 9 , wherein the oligomeric or polymeric urethane group-free polyether compound has at least one terminal oxirane, aziridine and/or thiirane group and/or at least one terminal hydroxyl, amino or thiol group.

11. The polymerizable composition according to claim 9 , wherein component (A-1) is selected from compounds of the general formula (Via),

in which j denotes a number from 0 to 4, R c is selected from halogen, C 1-40 alkyl, C 2-40 alkenyl, C 1-40 alkoxyl and C 7-13 aralkyl and Q is selected from the group consisting of alkylene, oxygen, sulfur, sulfoxide, sulfone and a direct, covalent bond.

12. The polymerizable composition according to claim 9 , wherein component (A-2) is selected from compounds of the general formula (IX),

P[—OH] m   Formula (IX)

in which m is a number from 2 to 100 and P denotes an m-valent polyalkylene oxide residue.

13. The polymerizable composition according to claim 9 , wherein component (B-1) is selected from compounds of the general formula (X),

in which u is a number from 2 to 5000, each u′ in each repeating unit independently denotes a number from 1 to 10, each R in formula (X) and in each repeating unit is independently selected from hydrogen or linear or branched optionally substituted C 1-12 alkyl groups, each residue R f and R g independently denotes a divalent group of compounds comprising 1 to 100 C atoms and W is selected from —O—, —S— or —NH—.

14. The polymerizable composition according to claim 1 , wherein the oligomeric or polymeric urethane group-free polyether compound has a weight-average molecular weight of 1000 to 100,000 g/mol.

15. A polymerization product of the polymerizable composition according to claim 1 .

16. The polymerization product according to claim 15 , wherein the polymerization product comprises a layer or a bundle of fibers, the fibers being treated prior to curing with a polymerizable composition according to claim 1 .

17. A method for producing a polymerization product according to claim 16 , comprising the following steps:

a) provision of a layer or a bundle of fibers;

b) provision of a polymerizable composition;

c) production of a composite system by treating a layer or a bundle of fibers with the polymerizable composition;

d) optional removal of an excess amount of the polymerizable composition from the composite system,

wherein said polymerization product is obtained by exposing the composite system to elevated temperature.

18. An adhesive, sealant or coating comprising a polymerizable composition according to claim 1 .

19. A polymerizable composition, comprising

i) at least one benzoxazine compound and

ii) as a toughening agent, from 5 to 40 wt. %, based on the total weight of the polymerizable composition, at least one polyether compound having a weight average molecular weight of from 1000 to 100,000 and comprising one or more structural elements of the general formula (I),

in which n is a number from 5 to 10,000, each residue R a in each repeating unit independently denotes a divalent group of compounds comprising 1 to 100 C atoms, each residue X′ in each repeating unit is independently selected from —O—, —S—, —NH— or a carboxyl group of the general form —(C═O)O—, in which the C atom of the carboxyl group is always connected to the residue A, each residue Y in each repeating unit is independently selected from —OH, —SH and —NH 2 and each residue A in each repeating unit is independently selected from K or L, K denoting a divalent residue of aromatic dihydroxyl compounds following removal of both hydroxyl groups and L denoting a divalent residue of polyethers following removal of two terminal hydroxyl groups, with the proviso that, relative to the total number of all residues A in the polyether compound, 20 to 80% of all residues A denote K and 20 to 80% of all residues A denote L, wherein the polyether compound is free of oligomeric or polymeric urethane groups.