Block copolymer battery separator
View Patent ↗The invention herein described is the use of a block copolymer/homopolymer blend for creating nanoporous materials for transport applications. Specifically, this is demonstrated by using the block copolymer poly(styrene-block-ethylene-block-styrene) (SES) and blending it with homopolymer polystyrene (PS). After blending the polymers, a film is cast, and the film is submerged in tetrahydrofuran, which removes the PS. This creates a nanoporous polymer film, whereby the holes are lined with PS. Control of morphology of the system is achieved by manipulating the amount of PS added and the relative size of the PS added. The porous nature of these films was demonstrated by measuring the ionic conductivity in a traditional battery electrolyte, 1M LiPF 6 in EC/DEC (1:1 v/v) using AC impedance spectroscopy and comparing these results to commercially available battery separators.
1. A method for preparing a nanoporous polymer film comprising:
a) mixing a poly(styrene-block-ethylene-block-styrene) with polystyrene homopolymer;
b) casting a film from the mixture; and thereafter,
c) submerging the film in an organic solvent to remove the polystyrene homopolymer to produce a nanoporous film wherein the pores are lined with polystyrene.
2. The method of claim 1 wherein the organic solvent is tetrahydrofuran.
3. The method of claim 1 further including the step of:
(d) drying the film after removal from the solvent.
4. The method of claim 1 wherein the amount of polystyrene added is controlled to control pore size.
5. The method of claim 4 wherein additionally the relative size of the polystyrene added is controlled.
6. The method of claim 5 wherein the molecular weight of the polystrene homopolymers range from 1.8 kg/mol to 30 kg/mol.
7. A lithium ion battery, including a battery separator comprising a film formed according to the method of claim 3 .