Synthesis gas and nanocarbon production method and production system
A synthesis gas and nanocarbon production method has a lower hydrocarbon decomposition step for decomposing lower hydrocarbon to produce hydrogen and nanocarbon, a carbon dioxide reduction step for reacting a part of the nanocarbon produced with carbon dioxide to produce carbon monoxide, and a mixing step for mixing the hydrogen and carbon monoxide produced in a predetermined ratio, thereby nanocarbon and a synthesis gas having a desired gas ratio can be simultaneously produced easily.
1. A synthesis gas and nanocarbon production method, comprising:
a lower hydrocarbon decomposition step of directly decomposing lower hydrocarbon using a catalyst to produce hydrogen and nanocarbon;
a carbon dioxide reduction step of reacting a part of the nanocarbon produced in the lower hydrocarbon decomposition step with carbon dioxide to produce carbon monoxide; and
a mixing step of mixing the hydrogen produced in the lower hydrocarbon decomposition step and the carbon monoxide produced in the carbon dioxide reduction step in a predetermined ratio to obtain a synthesis gas.
2. The synthesis gas and nanocarbon production method according to claim 1 , further comprising a synthesis step of subjecting the synthesis gas obtained in the mixing step to a reaction to obtain a synthetic substance.
3. The synthesis gas and nanocarbon production method according to claim 1 , wherein the carbon dioxide reduction step includes a catalyst refreshing step of subjecting a part or the whole of the catalyst used in the lower hydrocarbon decomposition step to the reaction between the nanocarbon and the carbon dioxide, and removing a part or the whole of the nanocarbon produced in the lower hydrocarbon decomposition step from the catalyst in conducting the reaction.
4. The synthesis gas and nanocarbon production method according to claim 3 , wherein the catalyst refreshed in the catalyst refreshing step is again applied to the lower hydrocarbon decomposition step.
5. The synthesis gas and nanocarbon production method according to claim 1 , wherein the lower hydrocarbon contains methane.
6. The synthesis gas and nanocarbon production method according to claim 1 , wherein the catalyst comprises at least one of nickel and iron, supported on at least one of alumina, silica, magnecia, calcia, hydrotalcite, and carbon.
7. The synthesis gas and nanocarbon production method according to claim 1 , wherein the carbon dioxide is collected from at least one of combustion exhaust gas in the lower hydrocarbon decomposition step, exhaust gas in various industries, and biogas.
8. The synthesis gas and nanocarbon production method according to claim 1 , wherein at least one of lower hydrocarbon and hydrogen is used as a reducing agent in the carbon dioxide reduction step.
9. The synthesis gas and nanocarbon production method according to claim 1 , wherein the lower hydrocarbon decomposition step and the carbon dioxide reduction step are conducted by switching supply of the lower hydrocarbon and supply of the carbon dioxide to the same catalyst.
10. The synthesis gas and nanocarbon production method according to claim 1 , further comprising:
a collection step for collecting the nanocarbon produced in the lower hydrocarbon decomposition step,
wherein the nanocarbon collected in the collection step is supplied to the carbon dioxide reduction step.
11. The synthesis gas and nanocarbon production method according to claim 10 , wherein after pulverizing the nanocarbon collected together with the catalyst in the collection step, high purity carbon and nanocarbon containing high concentration of the catalyst are separated by at least one of specific gravity and magnetism, and the nanocarbon containing high concentration of the catalyst is preferentially supplied to the carbon dioxide reduction step.
12. The synthesis gas and nanocarbon production method according to claim 1 ,
wherein the lower hydrocarbon decomposition step comprises while heating a vessel accommodating the catalyst by a furnace that uses the lower hydrocarbon as a fuel, supplying the lower hydrocarbon to the heated vessel so as to decompose the lower hydrocarbon by using the catalyst to produce the hydrogen and the nanocarbon, and
wherein the carbon dioxide reduction step comprises reacting the part of the nanocarbon produced in the lower hydrocarbon decomposition step with the carbon dioxide that is collected from combustion exhaust gas in the lower hydrocarbon decomposition step to produce the carbon monoxide.
13. The synthesis gas and nanocarbon production method according to claim 12 ,
wherein the lower hydrocarbon decomposition step further comprises:
discharging exhaust gas containing unreacted lower hydrocarbon and the hydrogen from the vessel; and
separating the unreacted lower hydrocarbon and the hydrogen from the exhaust gas so as to transfer the hydrogen to a mixing part and to return the unreacted lower hydrocarbon to be used again as the fuel, and
wherein the carbon dioxide reduction step further comprises transferring the carbon monoxide to the mixing part, and
wherein the mixing step comprise mixing the hydrogen produced in the lower hydrocarbon decomposition step and the carbon monoxide produced in the carbon dioxide reduction step in a predetermined ratio in the mixing part to obtain the synthesis gas.