Organic light-emitting device
Aspects of the present invention provide a blue organic light-emitting device having a continuous operation lifetime. An organic light-emitting device includes a light-emitting layer containing a dopant having the ability to trap electrons or holes, and a hole-blocking layer or electron-blocking layer, in which the difference between the LUMO of the dopant and the LUMO of a host material, the size relationship between the HOMO of the host material and the HOMO of the dopant, and the difference between the T 1 of the host material and the T 1 of the hole-blocking layer or between the T 1 of the host material and the T 1 of the electron-blocking layer, are specified.
1. An organic light-emitting device comprising:
a pair of electrodes having an anode and a cathode;
a light-emitting layer arranged between the pair of electrodes, the light-emitting layer containing a host material and a blue-fluorescent dopant material having the ability to trap electrons; and
a hole-blocking layer adjacent to the light-emitting layer,
wherein the energy of the lowest unoccupied molecular orbital of the host material (LUMO (host)) and the energy of the LUMO of the blue-fluorescent dopant material (LUMO (dopant)) satisfy the following expression:
|LUMO(dopant)|−|LUMO(host)|>0.15 eV,
the energy of the highest occupied molecular orbital of the host material (HOMO (host)) and the energy of the HOMO of the blue-fluorescent dopant material (HOMO (dopant)) satisfy the following expression:
|HOMO(host)|<|HOMO(dopant)|,
the energy of the lowest excited triplet state of the host material (T 1 (host)) and the energy of the lowest excited triplet state of the hole-blocking layer (T 1 (HBL)) satisfy the following expression:
T1(host)−T1(HBL)>0.1 eV,
the host material and a material for the hole-blocking layer are different hydrocarbon compounds, each of the hydrocarbon compounds having a plurality of mono- or higher-valent unsubstituted or alkyl-substituted aromatic hydrocarbon moieties, and the aromatic hydrocarbon moieties being linked together only by a single bond, and
a substructure containing the single bond and the aromatic hydrocarbon moieties linked together by the single bond is represented only by general formula [1] or [2]:
(wherein thick lines illustrated in formulae [1] and [2] each indicate the single bond).
2. The organic light-emitting device according to claim 1 , wherein the minimum exposed surface area of the single bond of each of the host material and the material for the hole-blocking layer is higher than 87 Å 2 .
3. The organic light-emitting device according to claim 1 , wherein the blue-fluorescent dopant material having the ability to trap electrons is a hydrocarbon compound having the substructure containing a fluoranthene skeleton.
4. An organic light-emitting device comprising:
a pair of electrodes having an anode and a cathode,
a light-emitting layer arranged between the pair of electrodes, the light-emitting layer containing a host material and a blue-fluorescent dopant material having the ability to trap holes, and
an electron-blocking layer adjacent to the light-emitting layer,
wherein the energy of the lowest unoccupied molecular orbital of the host material (LUMO (host)) and the energy of the LUMO of the blue-fluorescent dopant material (LUMO (dopant)) satisfy the following expression:
|LUMO(host)|>|LUMO(dopant)|,
the energy of the highest occupied molecular orbital of the host material (HOMO (host)) and the energy of the HOMO of the blue-fluorescent dopant material (HOMO (dopant)) satisfy the following expression:
|HOMO(host)|−|HOMO(dopant)|>0.15 eV,
the energy of the lowest excited triplet state of the host material (T 1 (host)) and the energy of the lowest excited triplet state of the electron-blocking layer (T 1 (EBL)) satisfy the following expression:
T1(host)−T1(EBL)>0.1 eV,
the host material and a material for the electron-blocking layer are different hydrocarbon compounds, each of the hydrocarbon compounds having a plurality of mono- or higher-valent unsubstituted or alkyl-substituted aromatic hydrocarbon moieties, and the aromatic hydrocarbon moieties being linked together only by a single bond, and
a substructure containing the single bond and the aromatic hydrocarbon moieties linked together by the single bond is represented only by general formula [1] or [2]:
(wherein thick lines illustrated in formulae [1] and [2] each indicate the single bond).
5. The organic light-emitting device according to claim 4 , wherein the minimum exposed surface area of the single bond of each of the host material and the material for the electron-blocking layer is higher than 87 Å 2 .
6. The organic light-emitting device according to claim 1 , wherein the host material contained in the light-emitting layer has an energy of the lowest excited triplet state T 1 of 2.5 eV or less.