Lubricant compositions for transmissions
A lubricating composition includes one or more base oils, at least one dimercaptothiadiazole derivative, at least one ethylene and alpha-olefin copolymer and at least one amine thiophosphate. The composition can be used for lubricating transmissions such as gearboxes and axles, preferably the manual gearboxes of motor vehicles and enable a reduction in the fuel consumption of vehicles, in particular of motor vehicles, due to the combination of the ethylene and alpha-olefin copolymer, dimercaptothiadiazole derivative and amine thiophosphate which decreases the coefficient of friction of the lubricating composition.
1. A lubricant composition comprising one or more base oils, at least one dimercaptothiadiazole derivative, at least one ethylene and alpha-olefin copolymer and at least one amine thiophosphate of general formula (IVa):
in which X 1 and X 2 are independently of each other a sulphur atom or an oxygen atom, at least one of them being a sulphur atom, R 1 and R 2 are either a hydrogen atom or alkyl groups having between 1 and 22 carbon atoms, M is an ammonium formed from a primary, secondary or tertiary amine, of formula R 3 R 4 R 5 R 6 N, where R 3 , R 4 , R 5 , R 6 are either a hydrogen atom or an alkyl group comprising from 1 to 18 carbon atoms, and then n =1.
2. The lubricant composition according to claim 1 wherein the ethylene and alpha-olefin copolymer is an ethylene and alpha-olefin copolymer comprising from 3 to 30 carbon atoms.
3. The lubricant composition according to claim 1 wherein the ethylene and alpha-olefin copolymer has the general formula (I):
in which R is an alkyl group having from 1 to 8 carbon atoms, x and y are such that the ratio x/y is comprised between 0.5 and 2 and the sum x+y is comprised between 50 and 150.
4. The lubricant composition according to claim 1 wherein the quantity of ethylene and alpha-olefin copolymer is comprised between 1 and 20% by mass, with respect to the total mass of lubricant composition.
5. The lubricant composition according to claim 1 wherein the dimercaptothiadiazole derivative is chosen from 4,5-dimercapto-1,2,3-thiadiazole, 3,5-dimercapto-1,2,4-thiadiazole, 3,4-dimercapto-1,2,5-thiadiazole, and 2,5-dimercapto-1,3,4-thiadiazole derivatives, used alone or in a mixture.
6. The lubricant composition according to claim 1 wherein the dimercaptothiadiazole derivative has, as general formula, formula (II) or (III), used alone or in a mixture:
in which R 1 and R 2 are, independently of each other, hydrogen atoms, linear and/or branched alkyl groups comprising from 1 to 24 carbon atoms or aromatic substituents, n and m being independently of each other integers chosen from the group formed by the integers 1, 2, 3 or 4.
7. The lubricant composition according to claim 1 wherein the quantity of dimercaptothiadiazole derivative is comprised between 0.1 and 10% by mass, with respect to the total mass of the lubricant composition.
8. The lubricant composition according to claim 1 wherein the quantity of amine thiophosphate is comprised between 0.2 to 10% by mass, with respect to the total mass of lubricant composition.
9. The lubricant composition according to claim 1 further comprising a polymethacrylate.
10. The lubricant composition according to claim 1 further comprising a dispersant derived from polyisobutene.
11. The lubricant composition according to claim 1 further comprising an amine-type antioxidant additive.
12. The lubricant composition according to claim 1 further comprising a phenol-type anti-corrosion additive.
13. The lubricant composition according to claim 1 having a kinematic viscosity at 100° C. according to the standard ASTM D445 comprised between 4 and 40 cSt.
14. A process for using a lubricant comprising one or more base oils, at least one dimercaptothiadiazole derivative, at least one ethylene and alpha-olefin copolymer and at least one amine thiophosphate of general formula (IVa):
in which X 1 and X 2 are independently of each other a sulphur atom or an oxygen atom, at least one of them being a sulphur atom, R 1 and R 2 are either a hydrogen atom or alkyl groups having between 1 and 22 carbon atoms, M is an ammonium formed from a primary, secondary or tertiary amine, of formula R 3 R 4 R 5 R 6 N, where R 3 , R 4 , R 5 , R 6 are either a hydrogen atom or an alkyl group comprising from 1 to 18 carbon atoms, and then n =1; the process comprising lubricating a transmission member comprising bringing into contact the lubricant with at least one transmission member.
15. A process for lubricating with a lubricant comprising one or more base oils, at least one dimercaptothiadiazole derivative, at least one ethylene and alpha-olefin copolymer and at least one amine thiophosphate of general formula (IVa):
in which X 1 and X 2 are independently of each other a sulphur atom or an oxygen atom, at least one of them being a sulphur atom, R 1 and R 2 are either a hydrogen atom or alkyl groups having between 1 and 22 carbon atoms, M is an ammonium formed from a primary, secondary or tertiary amine, of formula R 3 R 4 R 5 R 6 N, where R 3 , R 4 , R 5 , R 6 are either a hydrogen atom or an alkyl group comprising from 1 to 18 carbon atoms, and then n =1; the process comprising reducing fuel consumption of a vehicle by bringing into contact an engine of the vehicle with the lubricant.