Soft capsule based on starch and a method and device for the production thereof
A method for producing starch soft capsules comprises the following steps: preparing a mixture comprising starch, plasticizer and water, wherein more than 50 weight percent of the starch is present in the form of particles of granular starch; shaping the mixture to form a film in a shaping process; solidifying the mixture by increasing the temperature of the mixture during and/or after the shaping process by more than 5° C.; and shaping the film to form a soft capsule. Soft capsules produced by this method have starch particles bonded to one another. A device for performing this method comprises a shaping device to enable shaping of the starch material to form a film, and a heating device to perform a heat treatment to destructure the starch during and/or after the shaping. It comprises a rotary die device.
1. A method for producing a soft capsule based on starch comprising:
shaping a mixture comprising starch to form a film wherein in said mixture more than 50 weight percent of said starch is present as particles of granular starch in a liquid phase in which granular starch is destructured at most up to stage 1.2; and
increasing temperature to solidify said mixture by destructuring said granular starch thereby producing soft capsules from said film wherein said increasing temperature occurs during and/or after said shaping;
wherein 5-10% of the starch grains are not birefringent in a polarization microscope in stage 1.2.
2. The method of claim 1 wherein said mixture in shaping to form a film has a dynamic viscosity of <3000 Pas.
3. The method of claim 1 wherein said mixture has a water content which is reduced by up to 25 weight percent during solidification.
4. The method of claim 1 wherein the molecular weight of the starch is not significantly impaired and a M w 2/M w 1 quotient is >0.3, where M w 1 is the weight-average of the molecular weight distribution of said starch used and M w 2 is the weight-average of the molecular weight distribution of said starch in said soft capsule produced.
5. A method for producing a soft capsule comprising:
preparing a mixture comprising:
a dry mixture comprising more than 40 weight percent starch after subtracting plasticizer, wherein more than 50 weight percent of said starch is present as particles of granular starch in a liquid phase in which granular starch is destructured at most up to stage 1.2; and
15-70 weight percent of the dry mixture plasticizer;
15-90 weight percent of the total mixture water; and
shaping said mixture to form a film in a shaping process;
solidifying said mixture by destructuring the granular starch by increasing temperature of said mixture by more than 5° C. during and/or after said shaping process; and
shaping said film to form a soft capsule comprising particles of destructured starch;
wherein 5-10% of the starch grains are not birefringent in a polarization microscope in stage 1.2.
6. The method of claim 5 wherein said mixture further comprises additives and adjuvants.
7. The method of claim 5 wherein the mixture in shaping to form a film has a dynamic viscosity of <3000 Pas.
8. The method of claim 5 wherein the mixture has a water content which is reduced by up to 25 weight percent during solidification.
9. The method of claim 5 wherein the molecular weight of the starch is not significantly impaired and an M w 2/M w 1 quotient is >0.3, where M w 1 is the weight-average of the molecular weight distribution of the starch used and M w 2 is the weight-average of the molecular weight distribution of the starch in the soft capsule produced.
10. The method of claim 1 wherein the temperature is increased by more than 5° C. to solidify the mixture.
11. The method of claim 5 wherein said mixture comprises up to 50 weight percent thickener, based on the dry mixture and after subtracting the plasticizer.
12. The method of claim 5 wherein said mixture comprises up to 10 weight percent of the dry mixture, after subtracting the plasticizer, carrageen and carrageenans.