Absorbent and absorbent article provided therewith
The present invention addresses the problem of providing a novel absorbent that comprises a water-absorbing cellulose-based fiber and a thermoplastic resin fiber, said thermoplastic resin fiber containing as a monomer component an unsaturated carboxylic acid or an unsaturated carboxylic acid anhydride, and has both a sufficient strength and a sufficient absorption property. The absorbent comprises a water-absorbing cellulose-based fiber and a thermoplastic resin fiber, said thermoplastic resin fiber containing as a monomer component an unsaturated carboxylic acid or an unsaturated carboxylic acid anhydride, wherein the mass ratio (the content of the water-absorbing cellulose-based fiber: the content of the thermoplastic resin fiber) is controlled to 90:10 to 50:50 and the density of the absorbent is controlled to 0.06 to 0.14 g/cm 3 .
1. An absorbent article comprising a liquid-permeable layer, a liquid-impermeable layer, and an absorbent body provided between the liquid-permeable layer and the liquid-impermeable layer, wherein:
the absorbent body obtained by injecting high-pressure steam onto a mixed material comprising cellulose-based water-absorbent fibers and thermoplastic resin fibers that comprise an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride or a mixture thereof as a monomer component, to increase a density of the mixed material
a mass ratio of the water-absorbent fibers to the thermoplastic resin fibers in the absorbent body is 80:20 to 50:50;
a density of the absorbent body is 0.06 to 0.14 g/cm 3 ;
a basis weight of the absorbent body is 100 to 400 g/m 2 ; and
the liquid-permeable layer comprises a blood modifying agent with an IOB of 0.00-0.60, a melting point of 45° C. or less, and a water solubility of 0.00-0.05 g in 100 g of water at 25° C.; wherein
the absorbent body has a ridge-furrow structure formed on a surface of the liquid-permeable layer side of the absorbent body and a surface of the liquid-impermeable layer side of the absorbent body; and
the ridge-furrow structure formed on the surface of the liquid-permeable layer side extends in the lengthwise direction of the absorbent article, while the ridge-furrow structure formed on the surface of the liquid-impermeable layer side extends in the widthwise direction of the absorbent article.
2. The absorbent article according to claim 1 , wherein the fibers in the absorbent body are bonded together.
3. The absorbent article according to claim 1 , wherein a temperature of the high-pressure steam is below a melting point of the thermoplastic resin fibers.
4. The absorbent article according to claim 1 , wherein the thermoplastic resin fibers are core-sheath composite fibers having as a sheath component a modified polyolefin that has been graft-polymerized with a vinyl monomer comprising an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride or a mixture thereof, or a polymer blend of the modified polyolefin with another resin, and as a core component a resin with a higher melting point than the modified polyolefin.
5. The absorbent article according to claim 1 , wherein the unsaturated carboxylic acid, unsaturated carboxylic acid anhydride or mixture thereof is maleic acid or its derivative, maleic anhydride or its derivative, or a mixture thereof.
6. The absorbent article according to claim 1 , wherein a difference between a dry maximum tensile strength and a wet maximum tensile strength of the absorbent body is 1 to 5 N/25 mm.
7. The absorbent article according to claim 1 , which comprises a superabsorbent material.
8. The absorbent article according to claim 1 , which is colored.
9. The absorbent article according to claim 1 , wherein a fiber density of the absorbent body increases from the surface of the liquid-permeable layer side toward the surface of the liquid-impermeable layer side.
10. The absorbent article according to claim 1 , wherein the blood modifying agent is selected from the group consisting of following items (i)-(iii) and combinations thereof:
(i) a hydrocarbon;
(ii) a compound having (ii-1) a hydrocarbon moiety, and (ii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii) a compound having (iii-1) a hydrocarbon moiety, (iii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituted for a hydrogen of the hydrocarbon moiety;
with the proviso that when 2 or more oxy groups are inserted in the compound of (ii) or (iii), the oxy groups are not adjacent.
11. The absorbent article according to claim 1 , wherein the blood modifying agent is selected from the group consisting of following items (i′)-(iii′) and combinations thereof:
(i′) a hydrocarbon;
(ii′) a compound having (ii′-1) a hydrocarbon moiety, and (ii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—), ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii′) a compound having (iii′-1) a hydrocarbon moiety, (iii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—), ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii′-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituted for a hydrogen on the hydrocarbon moiety;
with the proviso that when 2 or more same or different bonds are inserted in a compound of (ii′) or (iii′), the bonds are not adjacent.
12. The absorbent article according to claim 1 , wherein the blood modifying agent is selected from the group consisting of following items (A)-(F) and combinations thereof:
(A) an ester of (A1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituted for hydrogens on the chain hydrocarbon moiety, and (A2) a compound having a chain hydrocarbon moiety and 1 carboxyl group substituted for a hydrogen on the chain hydrocarbon moiety;
(B) an ether of (B1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituted for hydrogens on the chain hydrocarbon moiety, and (B2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituted for a hydrogen on the chain hydrocarbon moiety;
(C) an ester of (C1) a carboxylic acid, hydroxy acid, alkoxy acid or oxoacid comprising a chain hydrocarbon moiety and 2-4 carboxyl groups substituted for hydrogens on the chain hydrocarbon moiety, and (C2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituted for a hydrogen on the chain hydrocarbon moiety;
(D) a compound having a chain hydrocarbon moiety and one bond selected from the group consisting of ether bonds (—O—), carbonyl bonds (—CO—), ester bonds (—COO—) and carbonate bonds (—OCOO—) inserted between a C—C single bond of the chain hydrocarbon moiety;
(E) a polyoxy C 2 -C 6 alkylene glycol, or its ester or ether; and
(F) a chain hydrocarbon.
13. The absorbent article according to claim 1 , wherein the blood modifying agent is selected from the group consisting of (a 1 ) an ester of a chain hydrocarbon tetraol and at least one fatty acid, (a 2 ) an ester of a chain hydrocarbon triol and at least one fatty acid, (a 3 ) an ester of a chain hydrocarbon diol and at least one fatty acid, (b 1 ) an ether of a chain hydrocarbon tetraol and at least one aliphatic monohydric alcohol, (b 2 ) an ether of a chain hydrocarbon triol and at least one aliphatic monohydric alcohol, (b 3 ) an ether of a chain hydrocarbon diol and at least one aliphatic monohydric alcohol, (c 1 ) an ester of a chain hydrocarbon tetracarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 4 carboxyl groups, and at least one aliphatic monohydric alcohol, (c 2 ) an ester of a chain hydrocarbon tricarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 3 carboxyl groups, and at least one aliphatic monohydric alcohol, (c 3 ) an ester of a chain hydrocarbon dicarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 2 carboxyl groups, and at least one aliphatic monohydric alcohol, (d 1 ) an ether of an aliphatic monohydric alcohol and an aliphatic monohydric alcohol, (d 2 ) a dialkyl ketone, (d 3 ) an ester of a fatty acid and an aliphatic monohydric alcohol, (d 4 ) a dialkyl carbonate, (e l ) a polyoxy C 2 -C 6 alkylene glycol, (e 2 ) an ester of a polyoxy C2-C6 alkylene glycols and at least one fatty acid, (e 3 ) an ether of a polyoxy C 2 -C 6 alkylene glycol and at least one aliphatic monohydric alcohol, (e 4 ) an ester of a polyoxy C 2 -C 6 alkylene glycols and a chain hydrocarbon tetracarboxylic acid, chain hydrocarbon tricarboxylic acid or chain hydrocarbon dicarboxylic acid, (e 5 ) an ether of a polyoxy C 2 -C 6 alkylene glycol and a chain hydrocarbon tetraol, chain hydrocarbon triol or chain hydrocarbon diol, and (f 1 ) a chain alkane, and combinations thereof.