Method for manufacturing high strength galvanized steel sheet having excellent stability of mechanical properties, formability, and coating appearance
A method of manufacturing a high strength galvanized steel sheet has a first heating step including heating to 400° C. to 750° C. in an atmosphere containing O 2 : 0.1 to 20 percent and H 2 O: 1 to 50 percent and heating to 600° C. to 850° C. in an atmosphere containing O 2 : 0.01 to less than 0.1 percent and H 2 O: 1 to 20 percent is applied to a steel sheet, a second heating step includes holding the steel sheet in an atmosphere containing H 2 : 1 to 50 percent and having a dew point of 0° C. or lower at 750° C. to 900° C. for 15 to 600 s, cooling to a temperature of 450° C. to 550° C., and holding is performed at that temperature for 10 to 200 s, and a galvanization treatment is applied.
1. A method of manufacturing a high strength galvanized steel sheet having excellent stability of mechanical properties, formability, and coating appearance, comprising:
applying a first heating step to a steel sheet containing C: 0.04% or more and 0.13% or less, Si: 0.7% or more and 2.3% or less, Mn: 0.8% or more and 2.0% or less, P: 0.1% or less, S: 0.01% or less, Al: 0.1% or less, N: 0.008% or less, and the remainder composed of Fe and incidental impurities, on a percent by mass basis, in which, in a former part, heating is performed in an atmosphere containing O 2 : 0.1 to 20 percent by volume and H 2 O: 1 to 50 percent by volume at a temperature of 400° C. to 750° C. and, in a latter part, heating is performed in an atmosphere containing O 2 : 0.01 to less than 0.1 percent by volume and H 2 O: 1 to 20 percent by volume at a temperature of 600° C. to 850° C.;
applying a second heating step to the resultant steel sheet, in which holding is performed in an atmosphere containing H 2 : 1 to 50 percent by volume and having a dew point of 0° C. or lower at a temperature of 750° C. to 900° C. for 15 to 600 s, cooling to a temperature of 450° C. to 550° C. is performed, and holding is performed at a temperature of 450° C. to 550° C. for 10 to 200 s; and
applying a galvanization treatment,
wherein the galvanized steel sheet includes 75% or more of ferrite phase, 1.0% or more of bainitic ferrite phase, and 1.0% or more and 10.0% or less of pearlite phase, on an area ratio basis, the area ratio of martensite phase is 1.0% or more and less than 5.0%, and the area ratio of the martensite phase/(area ratio of bainitic ferrite phase+area ratio of pearlite phase)<0.6 is satisfied.
2. The method according to claim 1 , wherein the steel sheet further contains at least one type of element selected from Cr: 1.0% or less, V: 0.5% or less, Mo: 0.5% or less, Ni: 1.0% or less, and Cu: 1.0% or less on a percent by mass basis.
3. The method according to claim 1 , wherein the steel sheet further contains at least one type of element selected from Ti: 0.1% or less, Nb: 0.1% or less, and B: 0.0050% or less on a percent by mass basis.
4. The method according to claim 1 , wherein the steel sheet further contains at least one type of element selected from Ca: 0.005% or less and REM: 0.005% or less on a percent by mass basis.
5. The method according to claim 1 , wherein the former part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 1 or more and 1.3 or less and the latter part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 0.6 or more and less than 1.
6. The method according to claim 1 , wherein, after the galvanization treatment is applied, an alloying treatment of zinc coating is performed at a temperature of 500° C. to 600° C. under conditions satisfying Formula (1):
0.45≦exp[200/(400− T )]×ln( t )≦1.0 (1)
where
T: average holding temperature (° C.) at a temperature range of 500° C. to 600° C.,
t: holding time (s) at a temperature of 500° C. to 600° C., and exp(X) and ln(X) represent an exponential function and natural logarithm, respectively, of X.
7. The method according to claim 2 , wherein the steel sheet further contains at least one type of element selected from Ti: 0.1% or less, Nb: 0.1% or less, and B: 0.0050% or less on a percent by mass basis.
8. The method according to claim 2 , wherein the steel sheet further contains at least one type of element selected from Ca: 0.005% or less and REM: 0.005% or less on a percent by mass basis.
9. The method according to claim 3 , wherein the steel sheet further contains at least one type of element selected from Ca: 0.005% or less and REM: 0.005% or less on a percent by mass basis.
10. The method according to claim 2 , wherein the former part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 1 or more and 1.3 or less and the latter part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 0.6 or more and less than 1.
11. The method according to claim 3 , wherein the former part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 1 or more and 1.3 or less and the latter part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 0.6 or more and less than 1.
12. The method according to claim 4 , wherein the former part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 1 or more and 1.3 or less and the latter part of the first heating step is performed with a direct fired furnace or a non-oxidizing furnace under the condition of an air ratio of 0.6 or more and less than 1.