Laminate, polarizing plate, liquid crystal display device, and method of manufacturing polarizing plate
Provided is a polarizing plate having improved single plate transmittance under high-temperature and high-humidity conditions, and a liquid crystal display device using the same. A laminate including a polarizer, and an adhesive layer adjoining to at least one surface of the polarizer, the adhesive layer containing a resin and a compound, etc. represented by the formula (1) below. In the formula (1), each of R 1 and R 3 independently represents a hydrogen atom, C 1-20 straight-chain alkyl group, C 3-20 branched alkyl group, C 3-20 cycloalkyl group, C 2-20 alkenyl group or C 6-20 aromatic group, and R 5 represents a substituent Formula (1) polarizing plate
1. A laminate comprising a polarizer, and an adhesive layer adjoining to at least one surface of the polarizer, the adhesive layer containing a resin, and at least one species selected from the group consisting of a compound represented by the formula (1), a hydrate of the compound represented by the formula (1), a solvate of the compound represented by formula (1), and a salt of the compound represented by formula (1);
in the formula (1), R 1 and R 3 each independently represents a hydrogen atom, C 1-20 straight-chain alkyl group, C 3-20 branched alkyl group, C 3-20 cycloalkyl group, C 2-20 alkenyl group or C 6-20 aromatic group, and R 5 represents an alkyl group or an aralkyl group; provided that at least one of R 1 , R 3 , and R 5 may contain a water-soluble group.
2. The laminate of claim 1 , wherein the content of the compound represented by the formula (1), the hydrate of the compound represented by formula (1), the solvate of the compound represented by formula (1), and the salt of the compound represented by formula (1) in the adhesive layer exceeds 0.5% by mass and 50% by mass or less of the resin.
3. The laminate of claim 1 , wherein the resin is a water-soluble adhesive or UV-curable adhesive.
4. The laminate of claim 2 , wherein the resin is a water-soluble adhesive or UV-curable adhesive.
5. A polarizing plate comprising the laminate described in claim 1 , and a protective film formed on the surface of the adhesive layer of the laminate.
6. The polarizing plate of claim 5 , wherein the protective film is a cellulose acylate film.
7. A liquid crystal display device comprising the polarizing plate described in claim 5 .
8. A method of manufacturing a polarizing plate, the method comprising bonding a polarizer with a protective film or with a substrate, using an adhesive or pressure sensitive adhesive containing a resin and a compound selected from the group consisting of a compound represented by the formula (1), a hydrate of the compound represented by the formula (1), a solvate of the compound represented by the formula (1), and a salt of the compound represented by the formula (1);
in the formula (1), R 1 , R 3 and R 5 each independently represents a hydrogen atom, C 1-20 straight-chain alkyl group, C 3-20 branched alkyl group, C 3-20 cycloalkyl group, C 2-20 alkenyl group or C 6-20 aromatic group, and R 5 represents an alkyl group or an aralkyl group; provided that at least one of R 1 , R 3 , and R 5 may contain a water-soluble group.
9. The laminate of claim 1 , wherein R 5 represents an aralkyl group.
10. The laminate of claim 1 , wherein R 5 represents a C 7-20 aralkyl group.
11. The laminate of claim 1 , wherein R 5 represents a benzyl group.