Image display sealant dam composition and image display having the same
View Patent ↗The invention provides dam compositions which can give cured products serving as dam materials exhibiting appropriate hardness and adhesion with respect to adherends and which are preferably such that the dam materials also have inconspicuous joints with fillers. The invention also provides image displays manufactured with the compositions. An image display sealant dam composition includes (A) a polyorganosiloxane having a mercaptoalkyl group bonded to a silicon atom, and having a viscosity at 23° C. of 20 to 25000 cP; (B) an aliphatic unsaturated group-containing polyorganosiloxane including an aliphatic unsaturated group-containing linear polyorganosiloxane (B1) represented by Formula (I) and optionally further including a branched polyorganosiloxane (B2) having SiO 4/2 units, R′ 3 SiO 1/2 units and R′ 2 SiO 2/2 units, and optionally further having R′SiO 3/2 units, at least three R′ groups per molecule of the branched polyorganosiloxane (B2) are aliphatic unsaturated groups; (C) a photoreaction initiator; (D) an aliphatic unsaturated group-containing silane compound; and (E) a fumed silica having a BET specific surface area of 180 to 500 m 2 /g. In the composition, the ratio of the number of the mercaptoalkyl groups present in (A) to the total number of the aliphatic unsaturated groups in (B) and (D) is 0.45 to 1.50; the amount of (E) is 0.5 to 24 parts by weight per 100 parts by weight of (B); and the composition has a viscosity at 23° C. of 20,000 to 10,000,000 cP. An image display includes an image display component and a protective component sealed with the composition.
1. An image display sealant dam composition that comprises:
(A) a polyorganosiloxane having a mercaptoalkyl group bonded to a silicon atom, the polyorganosiloxane (A) having a viscosity at 23° C. of 20 to 25000 cP;
(B) an aliphatic unsaturated group-containing polyorganosiloxane including an aliphatic unsaturated group-containing linear polyorganosiloxane (B1) represented by the following formula (I):
wherein in the formula (I):
each R1 group independently represents an aliphatic unsaturated group,
each R group independently represents a C1 to C6 alkyl group or a C6 to C12 aryl group, and 1 to 60 mol % of the total R groups are C6 to C12 aryl groups, and
the letter n is a value such that the viscosity at 23° C. is 100 to 1,000,000 cP, and
optionally further including a branched polyorganosiloxane (B2) having SiO 4/2 units, R′ 3 SiO 1/2 units and R′ 2 SiO 2/2 units, and optionally further having R′SiO 3/2 units in the formulae, each R′ group is independently a C1 to C6 alkyl group or an aliphatic unsaturated group, wherein at least three R′ groups per molecule of the branched polyorganosiloxane (B2) are aliphatic unsaturated groups;
(C) a photoreaction initiator;
(D) at least one aliphatic unsaturated group-containing silane compound; and
(E) a hexamethyldisilazine-treated fumed silica having a BET specific surface area of 300 to 500 m 2 /g;
wherein a ratio of the number of the mercaptoalkyl groups present in (A) to the total number of the aliphatic unsaturated groups in (B) and (D) is 0.45 to 1.50;
(E) is in an amount of 0.5 to 24 parts by weight per 100 parts by weight of (B); and
said dam composition has a viscosity at 23° C. of 20,000 to 2,000,000 cP.
2. The image display sealant dam composition according to claim 1 , wherein a ratio of the number of the mercaptoalkyl groups in (A) to the number of the aliphatic unsaturated groups in (B) is 0.5 to 4.0.
3. The image display sealant dam composition according to claim 2 , wherein a ratio of the number of the mercaptoalkyl groups in (A) to the number of the aliphatic unsaturated groups in (D) is 1.2 to 3.5.
4. The image display sealant dam composition according to claim 2 , wherein a thixotropic ratio V 6rpm /V 12rpm of said dam composition is 1.05 to 2.0, wherein V 6rpm and V 12rpm are values of the viscosity in cP of said dam composition measured with a B-type rotational viscometer at 23° C. and a rotational speed of 6 rpm, and at 23° C. and a rotational speed of 12 rpm, respectively.
5. The image display sealant dam composition according to claim 2 , wherein (C) is in an amount of 0.05 to 50 parts by weight per 100 parts by weight of (B).
6. The image display sealant dam composition according to claim 2 , wherein the aliphatic unsaturated group-containing silane compound (D) is at least one compound selected from the group consisting of 3-methacryloxypropyltriethoxysilane, 3-methacryloxypropyltrimethoxysilane, vinyltrimethoxysilane and vinyltriethoxysilane.
7. The image display sealant dam composition according to claim 1 , wherein a ratio of the number of the mercaptoalkyl groups in (A) to the number of the aliphatic unsaturated groups in (D) is 1.2 to 3.5.
8. The image display sealant dam composition according to claim 7 , wherein a thixotropic ratio V 6rpm /V 12rpm is 1.05 to 2.0, wherein V 6rpm and V 12rpm are values of the viscosity in cP of said dam composition measured with a B-type rotational viscometer at 23° C. and a rotational speed of 6 rpm, and at 23° C. and a rotational speed of 12 rpm, respectively.
9. The image display sealant dam composition according to claim 7 , wherein (C) is in an amount of 0.05 to 50 parts by weight per 100 parts by weight of (B).
10. The image display sealant dam composition according to claim 1 , wherein a thixotropic ratio V 6rpm /V 12rpm of said dam composition is 1.05 to 2.0, wherein V 6rpm and V 12rpm are values of the viscosity in cP of said dam composition measured with a B-type rotational viscometer at 23° C. and a rotational speed of 6 rpm, and at 23° C. and a rotational speed of 12 rpm, respectively.
11. The image display sealant dam composition according to claim 10 , wherein (C) is in an amount of 0.05 to 50 parts by weight per 100 parts by weight of (B).
12. The image display sealant dam composition according to claim 1 , wherein (C) is in an amount of 0.05 to 50 parts by weight per 100 parts by weight of (B).
13. The image display sealant dam composition according to claim 1 , wherein the aliphatic unsaturated group-containing silane compound (D) is at least one compound selected from the group consisting of 3-methacryloxypropyltriethoxysilane, 3-methacryloxypropyltrimethoxysilane, vinyltrimethoxysilane and vinyltriethoxysilane.
14. An image display that comprises an image display component and a protective component sealed with the image display sealant dam composition according to claim 1 .