Ink, ink cartridge, and image-recording method
Provided is an ink containing a self-dispersible pigment, a polyurethane polymer particle, a surfactant, a water-soluble organic solvent, and water. The surfactant includes a fluorinated surfactant represented by Formula (1) and having an HLB value determined by a Griffin method of 11 or less. The water-soluble organic solvent includes at least one water-soluble organic solvent selected from a specific group, and the total content of the water-soluble organic solvents of the specific group is higher than the total content of the water-soluble organic solvents other than the solvents of the specific group.
1. An ink comprising:
a self-dispersible pigment;
a polyurethane polymer particle;
a surfactant;
a water-soluble organic solvent; and
water,
wherein the surfactant includes a fluorinated surfactant having an HLB value of 11 or less determined by a Griffin method and represented by Formula (1):
R 1 (CR 2 R 3 ) n CH 2 CH 2 (OCH 2 CH 2 ) m OH
wherein, R 1 represents a fluorine atom or a hydrogen atom; R 2 and R 3 each independently represent a fluorine atom or a hydrogen atom, provided that at least one of R 2 and R 3 represents fluorine atom; n represents a number of 1 or more and 30 or less; and m represents a number of 1 or more and 60 or less;
wherein the water-soluble organic solvent includes at least one water-soluble organic solvent selected from Group A consisting of glycerin, ethylene glycol, diethylene glycol, polyethylene glycol with a weight-average molecular weight of 10,000 or less, 1,3-propanediol, 1,4-butanediol, and diglycerol;
wherein the total content of the water-soluble organic solvents of the Group A in the ink is larger than the total content of water-soluble organic solvents other than the water-soluble organic solvents of Group A in the ink; and wherein the mass ratio of the total content of the water-soluble organic solvents of the Group A to the total content of water-soluble organic solvents other than the water-soluble organic solvents of Group A, based on the total mass of the ink, is 10 or more.
2. The ink according to claim 1 further comprising at least one additive selected from the following Group B consisting of tetritol, pentitol, hexitol, heptitol, octitol, and polyethylene glycols having weight-average molecular weight of more than 10,000 and 100,000 or less.
3. The ink according to claim 1 , wherein the mass ratio of the content of the self-dispersible pigment to the content of the polyurethane polymer particle, based on the total mass of the ink, is 0.5 or more and 4.0 or less.
4. An ink cartridge comprising an ink storage portion for storing ink, wherein the ink stored in the ink storage portion is the ink according to claim 1 .
5. An image-recording method comprising:
a conveying step of conveying a recording medium; and
an ink-applying step of applying ink to the recording medium,
wherein the ink is the ink according to claim 1 .
6. The image-recording method according to claim 5 , further comprising a heating step of heating the recording medium provided with the ink subsequently to the ink-applying step such that the surface temperature of the recording medium is 70° C. or more.
7. The image-recording method according to claim 5 , wherein the ink is applied to the recording medium with a tension of 20 N/m or more in the ink-applying step.
8. The image-recording method according to claim 5 , wherein the conveying speed of the recording medium in the conveying step is 50 m/minute or more.