MOTFT with un-patterned etch-stop
A method of fabricating a high mobility semiconductor metal oxide thin film transistor including the steps of depositing a layer of semiconductor metal oxide material, depositing a blanket layer of etch-stop material on the layer of MO material, and patterning a layer of source/drain metal on the blanket layer of etch-stop material including etching the layer of source/drain metal into source/drain terminals positioned to define a channel area in the semiconductor metal oxide layer. The etch-stop material being electrically conductive in a direction perpendicular to the plane of the blanket layer at least under the source/drain terminals to provide electrical contact between each of the source/drain terminals and the layer of semiconductor metal oxide material. The etch-stop material is also chemical robust to protect the layer of semiconductor metal oxide channel material during the etching process.
1. A method of fabricating a high mobility semiconductor metal oxide thin film transistor comprising the steps of:
depositing a layer of semiconductor metal oxide channel material;
depositing a blanket layer of etch-stop material with opposed major surfaces on the layer of semiconductor metal oxide channel material, the blanket layer of etch-stop material defining a perpendicular direction orthogonal to the major surfaces and a horizontal direction orthogonal to the perpendicular direction and extending in the direction of the major surfaces, and the blanket layer of etch-stop material including one of the group consisting of a metal oxide, a metalloid oxide and an n-type organic material;
depositing a layer of source/drain metal on the blanket layer of etch-stop material;
patterning the layer of source/drain metal on the blanket layer of etch-stop material; and
the patterning including etching the layer of source/drain metal into spaced apart source/drain terminals positioned to define a channel area in the semiconductor metal oxide layer, the etch-stop material allowing for electrons to tunnel between the source/drain terminals and the semiconductor metal oxide channel material, and providing electrical insulation between the spaced apart source/drain terminals, and the etch-stop material being chemically robust to protect the layer of semiconductor metal oxide channel material during the source/drain metal etching process.
2. The method as claimed in claim 1 wherein the step of depositing the layer of semiconductor metal oxide channel material includes depositing one of Indium-Oxide (In—O), Tin-Oxide (Sn—O), Zinc-Oxide (Zn—O), Galium-Oxide (Ga—O), In—Zn—O, In—Sn—O, In—Ga—O, Al—Zn—O, Ga—Zn—O, Ta—Zn—O, Ti—Zn—O, In—Ga—Zn—O, In—Ga—Sn—O, In—Al—Zn—O, In—Al—Sn—O, In—Ta—Zn—O, In—Ta—Sn—O, and their combinations in blend form or in multiple layer form.
3. The method as claimed in claim 1 wherein the step of depositing the layer of semiconductor metal oxide channel material includes depositing the semiconductor metal oxide channel layer in one of amorphous, crystalline, single-phase or multiple-phase form.
4. The method as claimed in claim 1 further including a step of annealing the layer of semiconductor metal oxide channel material in an oxygen ambient prior to the step of depositing the blanket layer of etch-stop material.
5. The method as claimed in claim 1 wherein the step of depositing the blanket layer of etch-stop material includes depositing a metal oxide including one of the group consisting of Ta—O, Ti—O, V—O, Hf—O, Zr—O, Pa—O, Cr—O, Ni—O, and their combinations in blend form or multiple layer form thereof.
6. The method as claimed in claim 5 wherein the step of depositing the blanket layer of metal oxide etch-stop material includes depositing a metal oxide etch-stop material with an energy gap in a range of 3 eV-4.5 eV.
7. The method as claimed in claim 5 wherein the step of depositing the layer of etch-stop material includes depositing the material in one of the group consisting of amorphous, nano-crystalline, and polycrystalline form.
8. The method as claimed in claim 1 wherein the step of depositing the blanket layer of etch-stop material includes depositing an n-type organic material including one of the group consisting of Alq, BAlq, and fullerenes including one of the group consisting of graphene type carbon molecules, buckyball, C60 and derivatives thereof.
9. The method as claimed in claim 1 wherein the step of depositing the blanket layer of etch-stop material includes depositing the material by one of sputtering, plasma-enhanced chemical vapor deposition, MOCVD, atomic layer deposition (ALD), or a coating method from an organo-metallic precursor solution with subsequent annealing.
10. The method as claimed in claim 1 wherein the step of depositing the blanket layer of etch-stop material includes depositing a layer of etch-stop material with a thickness in a range of 5 nm to 100 nm.
11. The method as claimed in claim 1 further including a step of annealing the blanket layer of etch-stop material in an oxygen ambient subsequent to the step of etching the layer of source/drain metal into the source terminal and the drain terminal.
12. The method as claimed in claim 11 wherein the step of annealing the blanket layer of etch-stop material in an oxygen ambient provides at least one of diffusing metal from the S/D contacts into the ES layer, diffusing oxygen from the ES layer into the S/D contacts and/or forming an n+ layer at the interface under the S/D contacts.
13. The method as claimed in claim 1 wherein the step patterning the layer of source/drain metal on the blanket layer of etch-stop material includes patterning the layer of source/drain metal on the blanket layer of etch-stop material overlying a non-planar area under each of the source/drain terminals.
14. The method of fabricating a high mobility semiconductor metal oxide thin film transistor as claimed in claim 1 wherein the step of depositing the blanket layer of etch-stop material includes depositing etch-stop material with sufficient insulating characteristics to complete shut-off the thin film transistor in I d -V gs performance.
15. A high mobility MOTFT with a gate electrode, a semiconductor metal oxide active layer, and source/drain electrodes, the MOTFT comprising:
a blanket layer of etch-stop material positioned on and covering the semiconductor metal oxide active layer, the blanket layer including one of the group consisting of a metal oxide, a metalloid oxide and an n-type organic material in one of amorphous, crystalline, single-phase or multiple-phase form;
the source/drain electrodes positioned on the blanket layer of etch-stop material on a side opposite the semiconductor metal oxide active layer and further positioned to define a channel area in the semiconductor metal oxide layer; and
the etch-stop material allowing for electrons to tunnel between the source/drain electrodes and the semiconductor metal oxide channel material, and providing electrical insulation between the spaced apart source/drain electrodes.
16. A high mobility MOTFT comprising:
a substrate;
a metal gate positioned on the substrate;
a layer of gate dielectric positioned over the metal gate and surrounding portions of the substrate;
an active channel layer of semiconductor metal oxide positioned over the layer of gate dielectric;
a blanket layer of etch-stop material with opposed major surfaces positioned over and covering the active channel layer, the blanket layer of etch-stop material defining a perpendicular direction orthogonal to the major surfaces and a horizontal direction orthogonal to the perpendicular direction and extending in the direction of the major surfaces, and the blanket layer of etch-stop material including one of the group consisting of a metal oxide, a metalloid oxide and an n-type organic material; and
spaced apart metal source/drain terminals positioned on the blanket layer of etch-stop material with the blanket layer of etch-stop material interposed between the spaced apart metal source/drain terminals and the active channel area, the etch-stop material allowing for electrons to tunnel between the source/drain terminals and the semiconductor metal oxide channel material, and providing electrical insulation between the spaced apart source/drain terminals, and the spaced apart metal source/drain terminals being further positioned to define a channel area in the active channel layer.
17. The high mobility MOTFT of claim 16 wherein the active channel layer of semiconductor metal oxide material includes one of the group consisting of Indium-Oxide (In—O), Tin-Oxide (Sn—O), Zinc-Oxide (Zn—O), Gallium-Oxide (Ga—O), In—Zn—O, In—Sn—O, In—Ga—O, Al—Zn—O, Ga—Zn—O, Ta—Zn—O, Ti—Zn—O, In—Ga—Zn—O, In—Ga—Sn—O, In—Al—Zn—O, In—Al—Sn—O, In—Ta—Zn—O, In—Ta—Sn—O, and their combinations in blend form or in multiple layer form.
18. The high mobility MOTFT of claim 16 wherein the semiconductor metal oxide channel layer is in amorphous, crystalline, single-phase or multiple-phase forms.
19. The high mobility MOTFT of claim 16 wherein the blanket layer of etch-stop material includes a metal oxide including one of the group consisting of Ta—O, Ti—O, V—O, Hf—O, Zr—O, Pa—O, Cr—O, Ni—O, and combinations thereof.
20. The high mobility MOTFT of claim 19 wherein the layer of etch-stop material includes the metal oxide in one of the group consisting of amorphous, nano-crystalline, and polycrystalline form.
21. The high mobility MOTFT of claim 16 wherein the blanket metal oxide etch-stop material has an energy gap in a range of 3 eV-4.5 eV.
22. The high mobility MOTFT of claim 16 wherein the blanket layer of etch-stop material includes an n-type organic material including one of the group consisting of Alq, BAlq, and fullerenes including one of the group consisting of graphene type carbon molecules, buckyball, C60 and derivatives thereof.
23. The high mobility MOTFT of claim 16 wherein the blanket layer of etch-stop material has a thickness in a range of 5 nm to 100 nm.
24. The high mobility MOTFT of claim 16 wherein the blanket layer of etch-stop material includes etch-stop material with sufficient insulating characteristics to complete shut-off the high mobility MOTFT in I d -V gs performance.
25. A thin film electronic backpanel circuit comprising a plurality of high mobility MOTFTs, each MOTFT including:
a substrate;
a metal gate positioned on the substrate;
a layer of gate dielectric positioned over the metal gate and surrounding portions of the substrate;
an active layer of semiconductor metal oxide positioned over the layer of gate dielectric;
a blanket layer of etch-stop material positioned over and covering the active layer, the blanket layer of etch-stop material including one of the group consisting of a compound comprising one of a metal oxide, a metalloid oxide or an n-type organic material;
spaced apart metal source/drain terminals positioned on the blanket layer of etch-stop material with the blanket layer of etch-stop material interposed between the spaced apart metal source/drain terminals and the active channel area, and further positioned to define a channel area in the active layer; and
the etch-stop material allowing for electrons to tunnel between the source/drain terminals and the semiconductor metal oxide channel material, and providing electrical insulation between the spaced apart source/drain terminals.