Solid-state battery electrode
The invention provides a solid-state battery electrode formed of a lithium ion conductor, an active material, and a solid electrolyte and including a granule that contains a plurality of lithium ion conductors and a plurality of active materials, as well as a method of producing a solid-state battery electrode that has a step of preparing a granule that contains a plurality of lithium ion conductors and a plurality of active materials and a step of uniformly mixing the granule with a solid electrolyte.
1. A solid-state battery electrode comprising:
a granule that contains a composite precursor granule comprised of a plurality of lithium ion conductors and a plurality of active materials, wherein the plurality of active materials are formed as separate active material regions interspersed in the plurality of lithium ion conductors, and the granule is a composite particle formed by the composite precursor granule and a solid oxide electrolyte; and
a solid electrolyte,
wherein the solid electrolyte is in direct contact with at least one of the separate active material regions.
2. The solid-state battery electrode according to claim 1 , wherein the active material is a positive electrode active material.
3. The solid-state battery electrode according to claim 1 , wherein a mass ratio between the lithium ion conductor and the active material is 5:1 to 25:1.
4. The solid-state battery electrode according to claim 1 , wherein the solid electrolyte is a sulfide solid electrolyte.
5. A method of producing a solid-state battery electrode, the method comprising:
preparing a plurality of precursor granules that each comprise a raw material of a lithium ion conductor and an active material, wherein each precursor granule is prepared by:
preparing an organic solvent solution of the raw material of the lithium ion conductor, and
coating the active material with the organic solvent solution of the raw material of the lithium ion conductor in a tumbling fluidized bed granulator to form the plurality of precursor granules;
contacting the plurality of the precursor granules with each other to form at least one composite precursor granule;
preparing a granule that contains the at least one composite precursor granule such that the composite precursor granule contains a plurality of the lithium ion conductors and a plurality of the active materials, wherein the plurality of active materials are formed as separate active material regions interspersed in the plurality of lithium ion conductors; and
uniformly mixing the granule with a solid electrolyte such that at least one of the separate active material regions is in direct contact with the solid electrolyte,
wherein during the preparation of the at least one composite precursor granule in the tumbling fluidized bed granulator, an intake temperature of the tumbling fluidized bed granulator is adjusted to a temperature at which a surface of the active material coated with the organic solvent solution is wet.
6. The method of producing a solid-state battery electrode according to claim 5 , wherein granule preparation comprises
baking the at least one composite precursor granule.
7. The method of producing a solid-state battery electrode according to claim 5 , wherein a mass ratio between the lithium ion conductor and the active material is 5:1 to 25:1.
8. The method of producing a solid-state battery electrode according to claim 5 , wherein the intake temperature of the tumbling fluidized bed granulator is at least room temperature and not more than 50° C.