Bipolar all-solid-state battery
Provided is a bipolar all-solid-state battery capable of preventing breakage of a current collector of a bipolar electrode to suitably prevent a short circuit from occurring, and a method for producing the above-mentioned bipolar all-solid-state battery. The bipolar all-solid-state battery includes: a bipolar electrode having a current collector and an electrode active material layer including a cathode active material layer containing a cathode active material, formed on one surface of the current collector, and an anode active material layer containing an anode active material, formed on the other surface of the current collector, and a solid electrolyte layer containing a solid electrolyte. The bipolar all-solid-state battery has a plurality of the bipolar electrodes laminated via the solid electrolyte layer and a reinforcing layer formed on the surface of the current collector is disposed between the end of the electrode active material layer and the surface of the current collector.
1. A bipolar all-solid-state battery, comprising:
a plurality of bipolar electrodes, each of the bipolar electrodes comprising:
a current collector and an electrode active material layer comprising a cathode active material layer containing a cathode active material, formed on a first surface of the current collector, and an anode active material layer containing an anode active material, formed on a second surface of the current collector;
a reinforcing layer as an insulator formed on the first surface or the second surface of the current collector is disposed between an end of the electrode active material layer and the first surface or the second surface of the current collector; and
a solid electrolyte layer containing a solid electrolyte, wherein
the plurality of the bipolar electrodes are laminated via the solid electrolyte layer,
the electrode active material layer is formed inside an end of the current collector, and
the end of the electrode active material layer, the reinforcing layer, and the current collector are sequentially disposed in a thickness direction of the electrode.
2. The bipolar all-solid-state battery according to claim 1 , wherein the end of the current collector is covered with the insulator.
3. A method for producing the bipolar all-solid-state battery according to claim 1 , comprising steps of:
forming the reinforcing layer, which is the insulator, on the surface of the current collector so that the reinforcing layer is disposed between an end of an electrode active material layer forming region located inside the end of the current collector, where the electrode active material layer is formed, and the surface of the current collector to thereafter form the bipolar electrode by forming the electrode active material layer in the electrode active material layer forming region;
forming the solid electrolyte layer; and
assembling the bipolar all-solid-state battery by laminating the plurality of the bipolar electrodes via the solid electrolyte layer.
4. The bipolar all-solid-state battery according to claim 1 , wherein the reinforcing layer is formed on the first surface and the second surface of the current collector and is disposed (i) between the end of the electrode active material layer and the first surface of the current collector and (ii) between the end of the electrode active material layer and the second surface of the current collector.