Process for producing crosslinked, melt-shaped articles
Crosslinked, melt-shaped articles are manufactured by a process that does not require the use of post-shaping external heat or moisture, the process comprising the steps of: A. Forming a crosslinkable mixture of a 1. Organopolysiloxane containing one or more functional end groups; and 2. Silane-grafted or silane-copolymerized polyolefin; and B. Melt-shaping and partially crosslinking the mixture; and C. Cooling and continuing crosslinking the melt-shaped article. Crosslinking is promoted by the addition of a catalyst to the mixture before or during melt-shaping or to the melt-shaped article.
1. A process for the manufacture of crosslinked, melt-shaped articles, the process comprising the steps of:
A. Forming a crosslinkable mixture comprising:
1. an organopolysiloxane containing two functional end groups which are hydroxyl groups, wherein the organopolysiloxane is a polydimethylsiloxane of the formula
wherein Me is methyl and n is from 10 to 400; and
2. silane-copolymerized polyolefin;
B. Melt-shaping and partially crosslinking the mixture into an article;
C. Cooling the melt-shaped article; and
D. Storing the melt-shaped article and continuing crosslinking without external moisture diffusion,
wherein a crosslinking catalyst is added to the mixture before or during melt-shaping or to the melt-shaped article.
2. The process of claim 1 wherein the forming a crosslinkable mixture comprises mixing (1) at most 10 wt %, based on the total weight of the crosslinkable mixture, of the organopolysiloxane, and (2) the silane-copolymerized polyolefin.
3. The process of claim 1 wherein the melt-shaping and partially crosslinking the mixture comprises melt-shaping the mixture into an article having a thickness of greater than 0.2 mm.
4. The process of claim 1 wherein the storing of the melt-shaped article and continuing crosslinking without external moisture diffusion further comprises forming a crosslinked, melt-shaped article that passes the hot creep test (100% elongation) measured at 200° C., 0.2 MPa load held for 15 minutes in accordance with IEC 60811-2-1.
5. The process of claim 1 wherein the forming a crosslinkable mixture comprises mixing (1) the organopolysiloxane, and (2) an ethylene/silane copolymer.
6. The process of claim 5 wherein the forming a crosslinkable mixture comprises mixing (1) the organopolysiloxane, and (2) the ethylene/silane copolymer, wherein the silane is vinyl trialkoxysilane.
7. The process of claim 1 wherein the forming a crosslinkable mixture comprises mixing, based on the weight of the mixture, (1) 0.5 to 10 wt % of the organopolysiloxane, (2) the silane-copolymerized polyolefin, and (3) 0.01 to 0.2 wt % of the crosslinking catalyst.
8. The process of claim 1 further comprising subjecting at least one of the crosslinkable mixture or a component of the mixture to drying conditions prior to the melt-shaping.
9. The process of claim 1 further comprising at least partially soaking at least one of the organopolysiloxane and crosslinking catalyst into the silane-copolymerized polyolefin at a temperature below the melting temperature of the silane-copolymerized polyolefin prior to the melt-shaping.
10. The process of claim 1 wherein the melt-shaping and partially crosslinking the mixture into an article comprises melt-shaping the article into a cable coating.
11. The process of claim 1 further comprising adding the crosslinking catalyst which is a Lewis or Bronsted acid or base to the crosslinkable mixture before the melt-shaping.
12. The process of claim 1 further comprising adding the crosslinking catalyst which is a Lewis or Bronsted acid or base to the crosslinkable mixture during the melt-shaping.
13. The process of claim 1 further comprising adding the crosslinking catalyst which is a Lewis or Bronsted acid or base to the melt-shaped article.
14. The process of claim 1 further comprising adding the crosslinking catalyst which is a Bronsted acid to the crosslinkable mixture before the melt-shaping.
15. The process of claim 1 further comprising adding the crosslinking catalyst which is a Bronsted acid to the crosslinkable mixture during the melt-shaping.
16. The process of claim 1 further comprising adding the crosslinking catalyst which is a Bronsted acid to the melt-shaped article.
17. The process of claim 1 further comprising adding the crosslinking catalyst which is sulfonic acid to the crosslinkable mixture before the melt-shaping.
18. The process of claim 1 further comprising adding the crosslinking catalyst which is sulfonic acid to the crosslinkable mixture during the melt-shaping.
19. The process of claim 1 further comprising adding the crosslinking catalyst which is sulfonic acid to the melt-shaped article.