Mercury monitor

1. Apparatus comprising:

an analytical cell configured for use in conjunction with an atomic absorption spectrometer usable to determine a mercury concentration in a sample material,

wherein the analytical cell includes

a body, wherein the body generally bounds an interior area, is elongated along a longitudinal direction and includes a first end and a second end opposed of the first end,

a first window adjacent the first end and a second window adjacent the second end, wherein the first and second windows are generally transparent to resonant radiation of mercury, wherein one of the first and second windows is configured to be optically connected with an atomic absorption spectrometer,

a gas sample inlet port on the body and longitudinally intermediate of the first and second windows, wherein the gas sample inlet port is configured to deliver into the interior area heated sample material vapor,

a pair of gas outlet ports each of which gas outlet ports is configured to enable gas to leave the interior area,

wherein a first gas outlet port is positioned longitudinally intermediate of the gas inlet port and the first window, and a second gas outlet port is positioned longitudinally intermediate of the gas inlet port and the second window,

a pair of clean gas inlet flow ports, wherein each gas inlet flow port is configured to deliver into the interior area, sample material-free gas,

wherein a first clean gas inlet port is positioned to deliver sample material-free gas longitudinally intermediate of the first window and the first gas outlet port, and a second clean gas inlet port is positioned to deliver sample material-free gas longitudinally intermediate of the second gas outlet port and the second window,

wherein in operation of the analytical cell, the sample material-free gas flow reduces sample material reaching the first and second windows to maintain window transparency such that heated sample material vapor within the analytical cell can be analyzed through operation of the atomic absorption spectrometer directing radiation through the first and second windows.

2. The apparatus according to claim 1

wherein the analytical cell includes cell heaters.

3. The apparatus according to claim 2 wherein the cell heaters are configured to maintain the interior area at 600-700° C.

4. The apparatus according to claim 2

wherein the other of the first and second windows is operatively connected with a retroreflector.

5. The apparatus according to claim 4 and further comprising:

a thermal atomizer, wherein the thermal atomizer is in hermetic fluid sealed connection with the gas sample inlet port.

6. The apparatus according to claim 5

wherein the thermal atomizer heats sample material vapor to 600° to 950° C.

7. The apparatus according to claim 5 and further comprising:

a sample input unit, wherein the sample input unit is in hermetically sealed fluid connection with the thermal atomizer,

wherein the sample input unit includes a nebulizer in operative connection with a supply of liquid sample material.

8. The apparatus according to claim 5 and further comprising:

a sample injecting pump, wherein the injecting pump is in fluid communication with the thermal atomizer.

9. The apparatus according to claim 7

wherein the nebulizer includes a nozzle, and wherein the thermal atomizer includes an axial elongated interior area, wherein the nozzle is configured to deliver an aerosol spray of sample material coaxially aligned into the axial elongated interior area.

10. The apparatus according to claim 7 and further comprising:

a mixer, wherein the mixer has three ports,

wherein the nebulizer includes a gas port and wherein a first port of the mixer is in operative connection with the nebulizer gas port,

wherein a second port of the mixer is fluidly connected to a distilled water supply, wherein a third port of the mixer is fluidly connected to a supply of carrier gas.

11. The apparatus according to claim 7

wherein the sample input unit contains a holder of the nebulizer, wherein a cavity extends between an interior wall of the holder and the nebulizer,

wherein the cavity is fluidly connected with an internal cavity of the thermal atomizer, and

wherein the cavity of the nebulizer is fluidly connected with a supply of carrier gas.

12. The apparatus according to claim 7 and further comprising:

a gas collector in operative connection with the first and second gas outlet ports, wherein the gas collector includes a cooler and a liquid gas separator.

13. The apparatus according to claim 12

wherein the gas collector further includes a liquid holding reservoir in fluid connection with the liquid gas separator, and a return pump in fluid connection with the liquid holding reservoir.

14. The apparatus according to claim 13

wherein the clean gas inlet flow ports comprise openings through which sample vapor free air is enabled to enter the interior area.

15. The apparatus according to claim 1

wherein each of the pair of clean gas inlet flow ports includes an opening through which sample vapor free air is enabled to enter the interior area.

16. The apparatus according to claim 1

wherein the analytical cell is operatively coupled through the first window with an atomic absorption spectrometer and wherein the second window is optionally coupled with a retroreflector,

wherein the retroreflector is positioned so that radiation from the atomic absorption spectrometer passes through the first and second windows and is returned by the retroreflector through the second window and the first window back to the atomic absorption spectrometer.