Optoelectronic devices containing a converter carrier layer, and methods of producing an optoelectronic device containing a converter carrier layer
An optoelectronic device includes a layer sequence having an active layer that emits electromagnetic primary radiation, and at least one converter carrier layer arranged in the beam path of the electromagnetic primary radiation. The at least one converter carrier layer includes converter particles and an inorganic-organic hybrid material and/or a silicate glass.
1. An optoelectronic device comprising:
a layer sequence having an active layer that emits electromagnetic primary radiation;
at least one converter carrier layer arranged in the beam path of the electromagnetic primary radiation,
wherein 1) the at least one converter carrier layer comprises converter particles and an inorganic-organic hybrid material produced by hydrolysis, mutual condensation and crosslinking at least of a compound of formula I′ or I″ and at least one compound of formula II:
where M and M′ are the same or different and can represent a central atom with the charge m or m′,
where R and R′ are the same or different and represent hydrogen and/or an organic residue,
where Y represents an organic residue having a reactive group suitable for crosslinking,
where x=m,
where 0<n<m′, 1<x′<m′ and x′+n=m′,
where a=2, 3, 4, 5, 6, 7 or 8,
where b and b′ are the same or different and b, b′=1, 2, 3, 4, 5, 6, 7 or 8, 2) the converter particles are distributed in the inorganic-organic hybrid material and 3) the converter particles convert the electromagnetic primary radiation at least partially into electromagnetic secondary radiation.
2. The optoelectronic device according to claim 1 , wherein the converter carrier layer has a thermal conductivity of 0.2 W/mK to 10.0 W/mK.
3. The optoelectronic device according to claim 1 , wherein M and M′ are selected from the group consisting of B, Al, Si, Ti, Zr and Zn.
4. The optoelectronic device according to claim 1 , wherein the reactive group suitable for crosslinking is selected from the group consisting of fluorine, chlorine, bromine, iodine, amino, amide, aldehyde, keto, carboxy, thiol, hydroxy, acryloxy, methacryloxy, epoxy, isocyanate, ester, sulfonic acid, phosphoric acid and vinyl substituents.
5. The optoelectronic device according to claim 1 , wherein the converter particles are bonded by chemical bonds to the inorganic-organic hybrid material.
6. The optoelectronic device according to claim 1 , wherein the converter carrier layer is free of pores and cracks.
7. The optoelectronic device according to claim 1 , wherein the converter particles have a particle diameter of 1 to 50 μm.
8. The optoelectronic device according to claim 1 , wherein the converter carrier layer is formed as a casting compound and/or as a platelet, provided above the layer sequence.
9. The optoelectronic device according to claim 8 , wherein an adhesive layer is arranged between the layer sequence and the platelet.
10. A method of producing an optoelectronic device comprising a converter carrier layer having a thermal conductivity of 0.2 W/mK to 10.0 W/mK, and the converter carrier layer is a casting compound, the method comprising:
A) forming a housing having a recess,
B) introducing a layer sequence having an active layer, which emits electromagnetic primary radiation, into the recess of the housing,
C) mixing converter particles, and
Ca) at least one compound of formula I′ or I″ and at least one compound of formula II:
where M and M′ are the same or different and can represent a central atom with the charge m or m′,
where R and R′ are the same or different and represent hydrogen and/or an organic residue,
where Y represents an organic residue having a reactive group suitable for crosslinking,
where x=m and
where 0<n<m′, 1<x′<m′ and x′+n=m′,
where a=2, 3, 4, 5, 6, 7 or 8,
where b and b′ are the same or different and b, b′=1, 2, 3, 4, 5, 6, 7 or 8 and/or
Cb) salts and esters of Si(OH) 4 and at least one compound selected from the group consisting of Al 2 O 3 , Bi 2 O 3 , P 2 O 3 , Sc 2 O 3 and Y 2 O 3 ,
D) introducing the mixture into the recess,
E) hydrolyzing and condensing the compounds stated in Ca) and/or Cb),
F) crosslinking the compounds produced in E).
11. A method of producing an optoelectronic device comprising a converter carrier layer having a thermal conductivity of 0.2 W/mK to 10.0 W/mK, and the converter carrier layer is a platelet, the method comprising:
A) forming a housing having a recess,
B) introducing a layer sequence having an active layer which emits electromagnetic primary radiation, into the recess of the housing,
C′) producing a plate comprising C) mixing converter particles and
Ca) at least one compound of formula I′ or I″ and at least one compound of formula II:
where M and M′ are the same or different and can represent a central atom with the charge m or m′,
where R and R′ are the same or different and represent hydrogen and/or an organic residue,
where Y represents an organic residue having a reactive group suitable for crosslinking,
where x=m and
where 0<n<m′, 1<x′<m′ and x′+n=m′,
where a=2, 3, 4, 5, 6, 7 or 8,
where b and b′ are the same or different and b, b′=1, 2, 3, 4, 5, 6, 7 or 8 and/or
Cb) salts and esters of Si(OH) 4 and at least one compound selected from the group consisting of Al 2 O 3 , Bi 2 O 3 , P 2 O 3 , Sc 2 O 3 and Y 2 O 3 ,
D′) introducing the mixture into a two-dimensional mold,
E) hydrolyzing and condensing the compounds stated in Ca) and/or Cb),
F) crosslinking the compounds produced in E),
G) separating the plate to form a plurality of platelets, and
H) applying the platelet above the layer sequence.
12. The method according to claim 11 , wherein method step E) takes place at a temperature of 20° C. to 150° C.