Composition for reducing moisture in a battery electrolyte
In at least one embodiment, a lithium-ion battery is provided comprising a positive electrode, a negative electrode, an electrolyte, and a separator situated between the electrodes. At least one of the electrodes may include a proton absorbing material. The proton absorbing material may be an atomic intermetallic material including a proton absorbed state. The proton absorbing material may react with protons in the electrolyte to reduce moisture formation and cathode degradation in the battery. The proton absorbing material may absorb at least 0.5 wt. % hydrogen and may be present in the anode and/or cathode in an amount from 0.01 to 5 wt. %.
1. A lithium-ion battery comprising:
a positive electrode;
a negative electrode;
an electrolyte including LiPF 6 ;
a separator situated between the electrodes; and
at least one of the electrodes including an atomic intermetallic material including a proton absorbed state.
2. The battery of claim 1 , wherein the positive electrode includes 0.01 to 5 wt. % of the atomic intermetallic material.
3. The battery of claim 1 , wherein the atomic intermetallic material has a hydrogen absorbency from 0.0% to 3.5% by weight of the atomic intermetallic material.
4. The battery of claim 1 , wherein the atomic intermetallic material reacts with a proton to form a metal hydride in the proton absorbed state.
5. The battery of claim 4 , wherein the atomic intermetallic material includes an A x B y alloy, wherein A is a first metal or metal alloy, B is a second metal or metal alloy different from the first, and x and y are integers greater than or equal to 1.
6. The battery of claim 1 , wherein the atomic intermetallic material is included in both the positive electrode and the negative electrode.
7. The battery of claim 1 , wherein the atomic intermetallic material is formed as a powder.
8. The battery of claim 1 , wherein the atomic intermetallic material is formed as a film.
9. The battery of claim 1 , wherein the atomic intermetallic material is coated on a surface of at least one of the electrodes adjacent to the separator.
10. The battery of claim 1 , wherein the atomic intermetallic material is mixed throughout a bulk of at least one of the electrodes.
11. A lithium-ion battery comprising:
an anode;
a cathode;
an electrolyte including an organic solvent and a lithium salt; and
a separator situated between the anode and cathode;
the cathode including from 0.01 to 5 wt. % of an atomic intermetallic material including a proton absorbed state.
12. The battery of claim 11 , wherein the atomic intermetallic material reacts with a proton to form a metal hydride in the proton absorbed state.
13. The battery of claim 12 , wherein the atomic intermetallic material includes an A x B y alloy, wherein A is a first metal or metal alloy, B is a second metal or metal alloy different from the first, and x and y are integers greater than or equal to 1.
14. The battery of claim 11 , wherein the cathode includes from 0.05 to 1 wt. % of the atomic intermetallic material.
15. A lithium-ion battery comprising:
an anode;
a cathode;
an electrolyte including an organic solvent and a lithium salt; and
a separator situated between the anode and cathode;
the cathode having a first layer including a cathode active material and a second layer including a proton absorbing material that is different from the cathode active material and has a hydrogen absorbency from 0.75% to 3.5% by weight of the proton absorbing material.
16. The battery of claim 15 , wherein the proton absorbing material includes an atomic intermetallic material including a proton absorbed state.
17. The battery of claim 16 , wherein the atomic intermetallic material reacts with a proton to form a metal hydride in the proton absorbed state.
18. The battery of claim 17 , wherein the atomic intermetallic material includes an A x B y alloy, wherein A is a first metal or metal alloy, B is a second metal or metal alloy different from the first, and x and y are integers greater than or equal to 1.
19. The battery of claim 15 , wherein the cathode includes from 0.01 to 5 wt. % of the proton absorbing material.
20. The battery of claim 11 , wherein the lithium salt includes one or more of LiPF 6 , LiAsF 6 , LiClO 4 , LiBF 4 , or LiCF 3 SO 3 .