Olefin polymerization method
A method of olefin polymerization enables production of polyolefin with high productivity while suppressing sheeting or caking in the reactor. The method of olefin polymerization includes: feeding a circulating gas including at least one alpha-olefin and an inert gas into a reactor; polymerizing the alpha-olefin into a polyolefin in a reaction region in the reactor; and discharging the polyolefin from the reactor, which reactor consists of a cylindrical base section a positioned in the lower part thereof and a conical top section b positioned on the top of the cylindrical base section and having an open top. The inside of the reactor is divided into a reaction region A that is a fluidized bed region having an olefin polymerization occurring therein, and a free region B positioned on the top of the reaction region A and having solid polyolefin particles separated from the gas phase.
1. A method of olefin polymerization comprising:
feeding a circulating gas including at least one alpha-olefin and an inert gas into a reactor;
polymerizing the alpha-olefin into a polyolefin in a reaction region in the reactor;
and discharging the polyolefin from the reactor,
wherein the reactor comprises a cylindrical base section a positioned in the lower part thereof and a conical top section b positioned on the top of the cylindrical base section and having an open top and a boundary between the cylindrical base section a and the conical top section b,
wherein the conical top section b has an angle of inclination in the range of 4° to 7° with respect to a perpendicular line,
wherein the inside of the reactor is divided into a reaction region A that is a fluidized bed region having an olefin polymerization occurring therein, and a free region B positioned on the top of the reaction region A and having solid polyolefin particles separated from the gas phase,
wherein the fluidized bed A is at least as high as the cylindrical base section a and 80 percent or less the height of the conical top section b;
wherein a draft tube is provided in the fluidized bed A, so the circulating gas and polyolefin particles are discharged from the top of the draft tube to the fluidized bed A from a discharging portion of the draft tube positioned at the boundary between the cylindrical base section a and the conical top section b.
2. The method of olefin polymerization as claimed in claim 1 , wherein the fluidized bed is 5 to 50 percent the height of the conical top section b.
3. The method of olefin polymerization as claimed in claim 1 , wherein the conical top section b has an angle of inclination in the range of 5° to 6°, and the fluidized bed is 10 to 30 percent the height of the conical top section b.
4. The method of olefin polymerization as claimed in claim 1 , wherein the ratio of the total height of the reactor (a+b) to the height of the cylindrical base section a is in the range of 1:0.2 to 0.85.
5. The method of olefin polymerization as claimed in claim 1 , wherein the velocity of the circulating gas in the reaction region A is 0.1 m/sec to 1.5 m/sec.
6. The method of olefin polymerization as claimed in claim 1 , wherein a condensate is fed into the reaction region A to operate the reactor in a supercondensed or condensed mode.
7. The method of olefin polymerization as claimed in claim 1 , wherein a separate olefin polymerization reactor is further provided in the upstream or downstream of the reactor to perform a polymerization of olefin in a continuous multi-step manner.