Process for preparing stable dispersions of starch particles
In one or more embodiments, the present disclosure provides for a process for preparing a dispersion of starch particles in an aqueous liquid. In one or more embodiments, the process includes introducing a feed starch and the aqueous liquid into a rotor stator mixer, maintaining the feed starch and the aqueous liquid in the rotor stator mixer at a temperature ranging from a gelation temperature to less than a solubilization temperature, and shearing the feed starch into starch particles with the rotor stator mixer to form the dispersion of starch particles in the aqueous liquid. In one or more embodiments, the starch particles produced by this process have an average particle size diameter of no larger than 2 micrometers and the dispersion has 20 to 65 weight percent of the starch particles based on a total weight of the dispersion.
1. A process for preparing a dispersion of starch particles in an aqueous liquid, the process comprising:
heating a feed starch and the aqueous liquid to a temperature ranging from a gelation temperature to less than a solubilization temperature for the feed starch; and
shearing the feed starch into starch particles having an average particle size diameter of no larger than 2 micrometers in the absence of a cross-linker at the temperature ranging from the gelation temperature to less than the solubilization temperature of the feed starch.
2. The process of claim 1 , including crosslinking the starch particles with a cross-linker after the shearing step.
3. The process of claim 1 , where shearing the feed starch into starch particles includes forming the dispersion having 20 to 65 weight percent of the starch particles based on a total weight of the dispersion.
4. The process of claim 1 , where shearing the feed starch into starch particles includes using a rotor stator to shear the feed starch into starch particles.
5. The process of claim 1 , where shearing the feed starch into starch particles is conducted in the absence of a surfactant.
6. The process of claim 1 , where shearing the feed starch produces soluble starch having a starting molecular weight; and
reducing the soluble starch from the starting molecular weight to an ending molecular weight less than the starting molecular weight.
7. The process of claim 6 , where reducing the soluble starch includes enzymatically reducing the soluble starch from the starting molecular weight to an ending molecular weight less than the starting molecular weight.
8. The process of claim 1 , where a viscosity of the dispersion having 20 to 65 weight percent of the starch particles based on a total weight of the dispersion is less than 10,000 cP after being at 25° C. for 24 hours.
9. The process of claim 1 , including at least partially removing the aqueous liquid from the starch particles of the dispersion.
10. The process of claim 1 , including at least partially removing the aqueous liquid from the starch particles of the dispersion thereby forming a dry redispersible powder.
11. The process of claim 1 , including at least partially removing the aqueous liquid from the starch particles of the dispersion thereby forming a dry redispersible powder having an average particle size diameter of no larger than 2 micrometer.
12. A coating composition comprising a dispersion of starch particles prepared by the process of claim 1 .
13. The coating composition of claim 12 , where the coating composition is a paper coating composition.
14. The coating composition of claim 12 , where the coating composition is applied to one or more surfaces of a substrate, and wherein a portion of the aqueous liquid is removed thereby forming a coating layer associated with one or more surfaces of the substrate.