IP Library Granted Patent US 9,440,868
Granted Patent B2
US 9,440,868 · App. 14/056,035 · Granted Sep 13, 2016

Compositions and methods for the removal of phosphates and other contaminants from aqueous solutions

Inventors: Steven A. Odom (Miramar Beach, FL); Denny J. Ivey (Carrollton, GA)
Assignee: NClear Inc.
C02F1/62C02F1/5236C02F1/5245C02F1/58C02F2101/101C02F2101/105C02F2101/163C02F2101/20
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Quick Facts
Patent No.
US 9,440,868
App. No.
14/056,035
Granted
Sep 13, 2016
Kind
B2
Abstract

Compositions and methods for removing phosphates, nitrates and heavy metals from aqueous solutions.

Claims (29)

1. A method of producing a composition capable of removing phosphates, nitrates and heavy metals from a solution, comprising:

(a) forming a slurry from calcium oxide, silicon dioxide, and liquid alkali, wherein the molar ratio of the calcium oxide:silicon dioxide:liquid alkali ranges from 2.43-2.97:1.12-1.38:0.9-1.1

(b) subjecting the slurry to a hydrothermal process from about 1 to 6 hours under about 13.5-16.5 psi of pressure, forming a hydrothermal residue thereby; and

(c) producing the composition capable of removing phosphates, nitrates and heavy metals from a solution by heating the hydrothermal residue at about 540-660° C. for at least about 27 minutes.

2. The method of claim 1 , wherein the liquid alkali is sodium hydroxide.

3. The method of claim 2 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

4. The method of claim 1 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

5. A method of producing a composition capable of removing phosphates, nitrates and heavy metals from a solution, comprising:

(a) forming a slurry from calcium oxide, silicon dioxide, liquid alkali and a metal halide salt, wherein the molar ratio of the calcium oxide:silicon dioxide:liquid alkali:metal halide salt ranges from 48.6-59.4:22.5-27.5:18-22:4.95-6.05

(b) subjecting the slurry to a hydrothermal process from about 1 to 6 hours under about 13.5-16.5 psi of pressure, forming a hydrothermal residue thereby; and

(c) producing the composition capable of removing phosphates, nitrates and heavy metals from a solution by heating the hydrothermal residue at about 540-660° C. for at least about 27 minutes.

6. The method of claim 5 , wherein the liquid alkali is sodium hydroxide.

7. The method of claim 6 , wherein the metal halide salt is ferric chloride hexahydrate.

8. The method of claim 7 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

9. The method of claim 6 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

10. The method of claim 5 , wherein the metal halide salt is ferric chloride hexahydrate.

11. The method of claim 10 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

12. The method of claim 5 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

13. A composition capable of removing phosphates, nitrates and heavy metals from a solution produced by:

(a) forming a slurry from calcium oxide, silicon dioxide, liquid alkali and a metal halide salt, wherein the molar ratio of the calcium oxide:silicon dioxide:liquid alkali:metal halide salt ranges from 48.6-59.4:22.5-27.5:18-22:4.95-6.05

(b) subjecting the slurry to a hydrothermal process from about 1 to 6 hours under about 13.5-16.5 psi of pressure, forming a hydrothermal residue thereby; and

(c) heating the hydrothermal residue at about 540-660° C. for at least about 27 minutes.

14. The composition of claim 13 , wherein the liquid alkali is sodium hydroxide.

15. The composition of claim 14 , wherein the metal halide salt is ferric chloride hexahydrate.

16. The composition of claim 15 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

17. The composition of claim 14 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

18. The composition of claim 13 , wherein the metal halide salt is ferric chloride hexahydrate.

19. The composition of claim 18 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

20. The composition of claim 13 , wherein the heating step of claim (c) is performed at 600° C. for 30 minutes.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE ADDRESS PREVIOUSLY RECORDED AT REEL: 039428 FRAME: 0526. ASSIGNOR(S) HEREBY CONFIRMS THE CONVERSION AND CHANGE OF NAME. Recorded Aug 16, 2016
From: NCLEAR IP, LLC
To: NCLEAR INC.
Reel/Frame 039690/0709 →
CONVERSION AND CHANGE OF NAME Recorded Jul 22, 2016
From: NCLEAR IP, LLC
To: NCLEAR INC.
Reel/Frame 039428/0526 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2014
From: ODOM, STEVEN A.; IVEY, DENNY J.
To: NCLEAR IP, LLC
Reel/Frame 031925/0675 →
Continuity (3)
Provisional Application 61715812 · Oct 18, 2012
Provisional Application 61780267 · Mar 13, 2013
Related Publication 20140110627A1 · Apr 24, 2014