Fire resistant, high flow poly(aryl ether sulfone) composition
Polymer composition (C) containing (i) a poly(aryl ether sulfone) material (M12) composed of a poly(biphenyl ether sulfone) (P1) and, optionally in addition, a poly(aryl ether sulfone) (P2) containing recurring units with arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and (ii) a per(halo)fluoropolymer material (M34), composed of a per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are derived from a per(halo)fluoromonomer other than tetrafluoroethylene, and a polytetrafluoroethylene (P4). Shaped article, especially aircraft interior component, comprising the polymer composition (C).
1. A polymer composition (C) comprising:
50 wt. % or more and below 98 wt. %, based on the total weight of the polymer composition (C), of a poly(aryl ether sulfone) material (M12) which comprises
from 55 to 100 wt. %, based on the total weight of the poly(aryl ether sulfone) material (M12), of at least one poly(biphenyl ether sulfone) (P1), and
from 45 to 0 wt. %, based on the total weight of the poly(aryl ether sulfone) material (M12), of at least one poly(aryl ether sulfone) (P2) of which more than 50 wt. % of the recurring units are recurring units (R2) containing at least one ether group (—O—), at least one sulfone group (—SO2-) and at least two arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and
0.1-25 wt. %, based on the total weight of the polymer composition (C), of a per(halo)fluoropolymer material (M34) which comprises
from 5 to 95 wt. %, based on the total weight of the per(halo)fluoropolymer material (M34), of at least one per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are recurring units (R3) derived from at least one per(halo)fluoromonomer other than tetrafluoroethylene, and
from 95 to 5 wt. %, based on the total weight of the per(halo)fluoropolymer material (M34), of at least one polytetrafluoroethylene (P4).
2. The polymer composition according to claim 1 , wherein the weight of the poly(aryl ether sulfone) material (M12), based on the total weight of polymer composition (C), ranges between 90% and 98 wt. %.
3. The polymer composition according to claim 1 , wherein the poly(aryl ether sulfone) material (M12) consists essentially of the poly(biphenyl ether sulfone) (P1).
4. The polymer composition according to claim 1 , wherein the weight of the poly(biphenyl ether sulfone) (P1), based on the total weight of the poly(aryl ether sulfone) material (M12), ranges from 65% up to less than 95%.
5. The polymer composition according to claim 1 , wherein essentially all the recurring units of the poly(biphenyl ether sulfone) (P1) are recurring units (R1) of formula:
6. The polymer composition according to claim 1 , wherein essentially all the recurring units of the poly(aryl ether sulfone) (P2) are recurring units (R2) of formula:
7. The polymer composition according to claim 5 , wherein essentially all the recurring units of the poly(aryl ether sulfone) (P2) are recurring units (R2) of formula:
8. The polymer composition according to claim 1 , wherein the weight of the per(halo)fluoropolymer material (M34), based on the total weight of polymer composition (C), ranges between 2.0 and 5.0 wt. %.
9. The polymer composition according to claim 1 , wherein the per(halo)fluoropolymer (P3) is contained in the per(halo)fluoropolymer material (M34) in an amount of from 50% to 70 wt. %, based on the total weight of the per(halo)fluoropolymer material (M34).
10. The polymer composition according to claim 1 , wherein the per(halo)fluoropolymer (P3) is a copolymer essentially all the recurring units of which are a mix composed of from 7.0% to 20 wt. % of recurring units (R3) derived from perfluoromethylvinylether and at from 80% to 93.0% of recurring units derived from tetrafluoroethylene.
11. The polymer composition according to claim 1 , wherein the polymer composition (C) further comprises titanium dioxide.
12. A shaped article comprising the polymer composition according to claim 1 .
13. The shaped article according to claim 12 , which is an aircraft interior component.
14. The shaped article according to claim 13 , wherein the aircraft interior component is selected from the group consisting of overhead passenger service units, window reveals, air return grills, wall panels, overhead storage lockers, serving trays, seat backs, cabin partitions, and ducts.
15. An aircraft comprising the shaped article according to claim 14 .
16. The polymer composition according to claim 1 , wherein the weight of the poly(aryl ether sulfone) (P2), based on the total weight of the poly(aryl ether sulfone) material (M12), is above 5% to 45 wt. %.
17. The polymer composition according to claim 1 , wherein the polytetrafluoroethylene (P4) is non fibrillating.
18. The polymer composition according to claim 1 , wherein the polytetrafluoroethylene (P4) is non-melt-processable.
19. A polymer composition (C) comprising:
75 wt. % or more and below 98 wt. %, based on the total weight of the polymer composition (C), of a poly(aryl ether sulfone) material (M12) which comprises:
from 65 to 100 wt. %, based on the total weight of the poly(aryl ether sulfone) material (M12), of at least one poly(biphenyl ether sulfone) (P1), and
from 45 to 0 wt. %, based on the total weight of the poly(aryl ether sulfone) material (M12), of at least one poly(aryl ether sulfone) (P2) of which more than 50 wt. % of the recurring units are recurring units (R2) containing at least one ether group (—O—), at least one sulfone group (—SO2-) and at least two arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and
1-5 wt. %, based on the total weight of the polymer composition (C), of a per(halo)fluoropolymer material (M34) which comprises
from 5 to 95 wt. %, based on the total weight of the per(halo)fluoropolymer material (M34), of at least one per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are recurring units (R3) derived from at least one per(halo)fluoromonomer other than tetrafluoroethylene, and
from 95 to 5 wt. %, based on the total weight of the per(halo)fluoropolymer material (M34), of at least one polytetrafluoroethylene (P4).
20. The polymer composition according to claim 19 comprising 90 wt. % or more and below 98 wt. % of the poly(aryl ether sulfone) material (M12).
21. The polymer composition according to claim 19 comprising from 75 to 100 wt. % of the at least one poly(biphenyl ether sulfone) (P1).
22. The polymer composition according to claim 19 comprising from 65 to 99 wt. % of the at least one poly(biphenyl ether sulfone) (P1).
23. The polymer composition according to claim 19 comprising from 45 to 5 wt. % of the at least one poly(aryl ether sulfone) (P2).
24. The polymer composition according to claim 19 comprising from 45 to 10 wt. % of the at least one poly(aryl ether sulfone) (P2).
25. The polymer composition according to claim 19 comprising from 20 to 10 wt. % of the at least one poly(aryl ether sulfone) (P2).
26. The polymer composition according to claim 19 , wherein the per(halo)fluoropolymer material (M34) comprises from 50 to 70 wt. % of the at least one per(halo)fluoropolymer (P3).
27. The polymer composition according to claim 19 , wherein the per(halo)fluoropolymer material (M34) comprises from 30 to 50 wt. % of the at least one polytetrafluoroethylene (P4).