IP Library Granted Patent US 9,444,063
Granted Patent B2
US 9,444,063 · App. 14/276,621 · Granted Sep 13, 2016

Light-emitting element, light-emitting device, electronic device, and lighting device

Inventors: Yusuke Nonaka (Kanagawa, JP); Satoshi Seo (Kanagawa, JP); Harue Osaka (Kanagawa, JP); Tsunenori Suzuki (Kanagawa, JP); Takeyoshi Watabe (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L51/5012H01L51/5004H01L51/5016H01L51/5056H01L51/5278H01L2251/552
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Quick Facts
Patent No.
US 9,444,063
App. No.
14/276,621
Granted
Sep 13, 2016
Kind
B2
Abstract

To increase emission efficiency of a fluorescent light-emitting element by efficiently utilizing a triplet exciton generated in a light-emitting layer. The light-emitting layer of the light-emitting element includes at least a host material and a guest material. The triplet exciton generated from the host material in the light-emitting layer is changed to a singlet exciton by triplet-triplet annihilation (TTA). The guest material (fluorescent dopant) is made to emit light by energy transfer from the singlet exciton. Thus, the emission efficiency of the light-emitting element is improved.

Claims (78)

1. A light-emitting element comprising:

a hole-transport layer comprising a hole-transport material over a first electrode;

a light-emitting layer comprising a guest material and a host material over the hole-transport layer;

an electron-transport layer comprising an electron-transport material over and in contact with the light-emitting layer; and

a second electrode over the electron-transport layer,

wherein the host material is an anthracene compound,

wherein the guest material is a pyrene compound,

wherein a T1 level of the host material is lower than a T1 level of the guest material,

wherein a T1 level of the hole-transport material is higher than the T1 level of the host material,

wherein the host material and the electron-transport material are same compound, and

wherein the hole-transport material is a phenanthrene compound.

2. The light-emitting element according to claim 1 , wherein the guest material is a fluorescent material.

3. A light-emitting device comprising the light-emitting element according to claim 1 .

4. An electronic device comprising the light-emitting element according to claim 1 .

5. A lighting device comprising the light-emitting element according to claim 1 .

6. The light-emitting element according to claim 1 , wherein the pyrene compound is a pyrene diamine compound.

7. The light-emitting element according to claim 1 ,

wherein the anthracene compound comprises a carbazole group, and

wherein the pyrene compound is a pyrene diamine compound.

8. A light-emitting element comprising:

a hole-transport layer comprising a hole-transport material over a first electrode;

a light-emitting layer comprising a guest material and a host material over the hole-transport layer;

an electron-transport layer comprising an electron-transport material over and in contact with the light-emitting layer; and

a second electrode over the electron-transport layer,

wherein the host material is an anthracene compound,

wherein the guest material is a pyrene compound,

wherein a T1 level of the host material is lower than a T1 level of the guest material,

wherein a T1 level of the hole-transport material is higher than the T1 level of the guest material and the T1 level of the host material,

wherein the host material and the electron-transport material are same compound, and

wherein the hole-transport material is a phenanthrene compound.

9. The light-emitting element according to claim 8 , wherein the guest material is a fluorescent material.

10. A light-emitting device comprising the light-emitting element according to claim 8 .

11. An electronic device comprising the light-emitting element according to claim 8 .

12. A lighting device comprising the light-emitting element according to claim 8 .

13. The light-emitting element according to claim 8 , wherein the pyrene compound is a pyrene diamine compound.

14. The light-emitting element according to claim 8 ,

wherein the anthracene compound comprises a carbazole group, and

wherein the pyrene compound is a pyrene diamine compound.

15. A light-emitting element comprising:

a hole-transport layer comprising a hole-transport material over a first electrode;

a light-emitting layer comprising a guest material and a host material over the hole-transport layer;

an electron-transport layer comprising an electron-transport material over and in contact with the light-emitting layer; and

a second electrode over the electron-transport layer,

wherein the host material is an anthracene compound,

wherein the guest material is a pyrene compound,

wherein a T1 level of the host material is lower than a T1 level of the guest material,

wherein a T1 level of the hole-transport material is higher than the T1 level of the host material,

wherein a shape of a spectrum of delayed fluorescence is the same as a shape of a fluorescent spectrum of the guest material,

wherein a period where a ratio of an intensity of the delayed fluorescence with respect to an emission intensity during steadily injecting carriers is higher than or equal to 0.01 is 1×10 −6 sec or longer,

wherein the host material and the electron-transport material are same compound, and

wherein the hole-transport material is a phenanthrene compound.

16. A light-emitting device comprising the light-emitting element according to claim 15 .

17. An electronic device comprising the light-emitting element according to claim 15 .

18. A lighting device comprising the light-emitting element according to claim 15 .

19. The light-emitting element according to claim 15 , wherein the pyrene compound is a pyrene diamine compound.

20. The light-emitting element according to claim 15 ,

wherein the anthracene compound comprises a carbazole group, and

wherein the pyrene compound is a pyrene diamine compound.

21. A light-emitting element comprising:

a hole-transport layer comprising a hole-transport material over a first electrode;

a light-emitting layer comprising a guest material and a host material over the hole-transport layer;

an electron-transport layer comprising an electron-transport material over and in contact with the light-emitting layer; and

a second electrode over the electron-transport layer,

wherein the host material is an anthracene compound,

wherein the guest material is a pyrene compound,

wherein a T1 level of the host material is lower than a T1 level of the guest material,

wherein a T1 level of the hole-transport material is higher than the T1 level of the guest material and the T1 level of the host material,

wherein a shape of a spectrum of delayed fluorescence is the same as a shape of a fluorescent spectrum of the guest material,

wherein a period where a ratio of an intensity of the delayed fluorescence with respect to an emission intensity during steadily injecting carriers is higher than or equal to 0.01 is 1×10 −6 sec or longer,

wherein the host material and the electron-transport material are same compound, and

wherein the hole-transport material is a phenanthrene compound.

22. A light-emitting device comprising the light-emitting element according to claim 21 .

23. An electronic device comprising the light-emitting element according to claim 21 .

24. A lighting device comprising the light-emitting element according to claim 21 .

25. The light-emitting element according to claim 21 , wherein the pyrene compound is a pyrene diamine compound.

26. The light-emitting element according to claim 21 ,

wherein the anthracene compound comprises a carbazole group, and

wherein the pyrene compound is a pyrene diamine compound.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 13, 2014
From: NONAKA, YUSUKE; SEO, SATOSHI; OSAKA, HARUE; SUZUKI, TSUNENORI; WATABE, TAKEYOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 032881/0566 →
Priority Claims (2)
JP 2013/104016 · May 16, 2013 · national
JP 2013-220059 · Oct 23, 2013 · national
Continuity (1)
Related Publication 20140339522A1 · Nov 20, 2014