Method for producing water absorbent polyacrylic acid (salt) resin powder, and water absorbent polyacrylic acid (salt) resin powder
An object of the present invention is to provide a method for producing water absorbent resin powder in which permeability potential (SFC) is improved while a water absorbing rate (FSR) is being kept. The method is a method for producing water absorbent polyacrylic acid (salt) resin powder including the steps of: (i) polymerizing an acrylic acid (salt) monomer aqueous solution; (ii) during or after the step of (i), performing gel grinding of a hydrogel crosslinked polymer obtained by the polymerization, wherein the hydrogel crosslinked polymer has resin solid content of 10 wt % to 80 wt %, and the gel grinding is carried out with gel grinding energy (GGE) of 18 [J/g] to 60 [J/g]; (iii) drying a particulate hydrogel crosslinked polymer obtained by the gel grinding, wherein the drying is performed at 150° C. to 250° C.; and (iv) carrying out a surface treatment to the particulate hydrogel crosslinked polymer thus dried.
1. Water absorbent polyacrylic acid (salt) resin having:
95 wt % or more of particles whose diameter is not less than 150 μm and less than 850 μm;
logarithmic standard deviation (σζ) of particle size distribution of 0.25 to 0.50;
absorption against pressure (AAP) of 20 [g/g] or more; a water absorbing rate (FSR) of 0.30 [g/g/s] or more;
a saline flow conductivity (SFC) of 20[×10 −7 ·cm 3 ·s·g −1 ] or more; and
an internal cell ratio of greater than 1.0% to 2.5%, which is calculated by {(real density)−(apparent density)}/(real density)×100, the water absorbent polyacrylic acid (salt) resin containing a polyvalent metal salt.
2. The water absorbent polyacrylic acid (salt) resin as set forth in claim 1 , further containing at least one of a cationic polymer and inorganic fine particles.
3. The water absorbent polyacrylic acid (salt) resin as set forth in claim 1 , wherein the saline flow conductivity (SFC) is 50[×10 −7 ·cm 3 ·s·g −1 ] or more.
4. The water absorbent polyacrylic acid (salt) resin as set forth in claim 1 , wherein a water-soluble content is 10 wt % or less.
5. The water absorbent polyacrylic acid (salt) resin as set forth in claim 1 , wherein bulk specific gravity is in a range of 0.50[g/cm 3 ] to 0.80[g/cm 3 ].
6. The water absorbent polyacrylic acid (salt) resin as set forth in claim 1 , being crosslinked by combination use of an ionic bonding surface crosslinking agent and a covalent bonding surface crosslinking agent.
7. The water absorbent polyacrylic acid (salt) resin as set forth in claim 1 , wherein the polyvalent metal salt is aluminum or zirconium.