Polyester film and manufacturing method thereof
Provided is a polyester film having excellent high-temperature dimensional stability. More particularly, provided is a method for producing a polyester film, including: a) extruding and cooling a polyester resin to provide a non-oriented sheet; b) orienting the sheet in the machine direction (MD); c) orienting the MD oriented sheet in the transverse direction (TD); d) heat treating the sheet; and e) carrying out simultaneous relaxation by subjecting the heat treated sheet to MD relaxation at a ratio of 1% or higher, while subjecting it to TD relaxation in a tenter. Provided also is a polyester film obtained by the method.
1. A method for producing a polyethylene terephthalate film comprising:
(a) extruding and cooling a polyethylene terephthalate resin to provide a non-oriented polyethylene terephthalate sheet;
(b) orienting the polyethylene terephthalate sheet in machine direction (MD) to give a MD orientated polyethylene terephthalate film;
(c) orienting the MD oriented polyethylene terephthalate film obtained in step (b) in transverse direction (TD);
(d) heat treating the resulting biaxially oriented polyethylene terephthalate film obtained in step (c); and
(e) carrying out simultaneous relaxation by subjecting the heat treated polyethylene terephthalate film of step (d) to a MD relaxation at a ratio of 3-8%, while subjecting it to a TD relaxation at a ratio of 3-8% in a tenter,
wherein in step (b), the polyethylene terephthalate film is oriented at 1-10 times in the MD while being passed through an IR heater zone heated to 600-900° C., and then is further oriented 1-3 times while being passed through an IR heater zone heated to 500-800° C., so that the total MD-orientation is made 1-10 times;
the MD-oriented film is passed through a preheating zone, subjected to TD-orientation 1-10 times;
wherein the polyethylene terephthalate film has a shrinkage of 0.4% or less at 150° C. for 30 minutes in the MD, a maximum shrinkage stress of 0.20 kg/mm 2 or less at 150° C. for 3 minutes and an initial load 0.007 kg/mm 2 in MD, and a maximum shrinkage stress of 0.05 kg/mm 2 or less at 150° C. for 3 minutes and an initial load 0.007 kg/mm 2 in TD; and
wherein the polyethylene terephthalate film has a thickness of 50 to 350 μm.
2. The method for producing a polyethylene terephthalate film according to claim 1 , wherein the simultaneous relaxation is carried out by applying TD relaxation simultaneously with MD relaxation in at least one zone.
3. The method for producing a polyethylene terephthalate film according to claim 2 , wherein the simultaneous relaxation is carried out at a temperature 5-35° C. lower than the heat treatment temperature of step (d).
4. The method for producing a polyethylene terephthalate film according to claim 3 , wherein the simultaneous relaxation is carried out at a temperature of 170-240° C.
5. The method for producing a polyethylene terephthalate film according to claim 4 , wherein the simultaneous relaxation is carried out by simultaneously controlling an interval between adjacent clips and width in a tenter to relax stress of the film.