Ultraviolet curable type ink-jet ink composition, recording method and recording apparatus using the same
Provided is a UV curable type ink-jet ink composition containing a monomer A which is expressed by the following general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I) (in the formula, R 1 is a hydrogen atom or methyl radical, R 2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R 3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), a compound B containing five or more (meth)acryloyl radicals per molecule, and a monofunctional (meth)acrylate C having an aromatic ring skeleton, wherein the monofunctional (meth)acrylate C which is in a range of 5 to 35 wt % with respect to the total weight of the ink composition is contained.
1. A UV curable type ink composition containing a polymerizable compound and a photopolymerization initiator,
wherein the polymerizable compound contains a monomer A which is in a range of 40 to 90 wt % with respect to the total amount of the ink composition and expressed by the following general formula (I):
CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I)
(in the formula, R 1 is a hydrogen atom or methyl radical, R 2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R 3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), and
wherein the photopolymerization initiator contains an acylphosphine oxide which is in a range of 7 to 12 wt % with respect to the total amount of the ink composition, and the acylphosphine oxide contains at least a mono acylphosphine oxide and a bisacylphosphine oxide, and wherein the contained amount of the mono acylphosphine oxide is in a range of equal to or more than 50 wt % with respect to the total amount of the acylphosphine oxide.
2. The UV curable type ink-jet ink composition according to claim 1 , wherein the curing is performed through illumination of ultraviolet rays of which the light emitting peak wavelength is in a range of 350 to 420 nm with an illumination energy of equal to or less than 300 mJ/cm 2 .
3. The UV curable type ink-jet ink composition according to claim 1 , wherein viscosity at 20° C. is in a range of 3 to 30 mPa·s.
4. An ink jet recording method of ejecting the UV curable type ink-jet ink composition according to claim 1 on a recording medium and curing the ejected UV curable type ink-jet ink composition through illumination using a UV-LED of which the light emitting peak wavelength is in a range of 350 to 420 nm.
5. The UV curable type ink composition according to claim 1 , wherein the monomer A is acrylic acid 2-(vinyloxyethoxy) ethyl.
6. The UV curable type ink composition according to claim 1 , wherein the photopolymerization initiator further contains a thioxanthone compound which is in a range of 0.5 to 5 wt % with respect to the total amount of the ink composition.
7. The UV curable type ink composition according to claim 1 , wherein the thioxanthone compound is 2,4-diethyl thioxanthone.
8. The UV curable type ink composition according to claim 1 , wherein a phenoxyethyl (meth)acrylate which is in a range of 10 to 50 wt % with respect to the total amount of the ink composition is contained as the polymerizable compound.