Process for producing aviation fuel base oil
The present invention provides a process of producing an aviation fuel base oil having excellent combustibility, oxidation stability and life cycle characteristics, hydrotreating in the presence of hydrogen a feedstock comprising an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat (preferably an animal or vegetable fat that contains fatty acids each having 10 to 14 carbon atoms in the fatty acid carbon chain in the total amount of 60 percent by mass or more) and a sulfur-containing hydrocarbon compound. The present invention also provides a process for producing an aviation fuel base oil by blending such an aviation fuel base oil and an aviation fuel base oil produced by refining crude oil.
1. A process for producing an aviation fuel base oil comprising hydrotreating in the presence of hydrogen a feedstock comprising an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat and a sulfur-containing hydrocarbon compound which is selected from the group consisting of sulfide, disulfide, polysulfide, thiol, thiophene, benzothiophene, dibenzothiophene and derivatives thereof,
wherein the feedstock further comprises a recycled oil in an amount of 0.5 to 5 times by mass of the oxygen-containing hydrocarbon compound originating from an animal or vegetable fat,
wherein the feedstock contains sulfur in an amount of 1 to 50 ppm by mass in terms of sulfur on the basis of the total mass of the feedstock, and
wherein the hydrotreating comprises steps (a) and (b):
step (a): hydrotreating the feedstock by a fixed bed mode in the presence of hydrogen using a catalyst to produce a hydrotreated oil, wherein the catalyst comprises a support comprising a porous inorganic oxide comprising aluminum and at least one element selected from the group consisting of silicon, zirconium, boron, titanium and magnesium in a total amount of 1 to 20 percent by mass, and one or more types of metals selected from the group consisting of the Groups 6A and 8 elements of the periodic table, supported thereon, under conditions where the hydrogen pressure is from 2 to 13 MPa, the liquid hourly space velocity is from 0.1 to 3.0 h −1 , the hydrogen/oil ratio is from 150 to 1500 NL/L, and the reaction temperature is from 150 to 480° C.; and
step (b): isomerizing the hydrotreated oil produced in step (a) in the presence of hydrogen using a catalyst comprising a porous inorganic oxide comprising a substance selected from aluminum, silicon, zirconium, boron, titanium, magnesium and zeolite and one or more types of metals selected from the group consisting of the Group 8 elements of the periodic table, supported thereon, under conditions where the hydrogen pressure is from 2 to 13 MPa, the liquid hourly space velocity is from 0.1 to 3.0 h −1 , the hydrogen/oil ratio is from 250 to 1500 NL/L and the reaction temperature is from 150 to 380° C.,
wherein the recycled oil contains a portion of the hydrotreated oil produced in step (a), and wherein the portion is produced by removing by-products from the hydrotreated oil.
2. The process according to claim 1 , wherein said feedstock further comprises a petroleum base oil produced by refining crude oil.
3. The process according to claim 1 , wherein the total of the compositions of the fatty acids having a fatty acid hydrocarbon chain of 10 to 14 carbon atoms in said animal or vegetable fat is 60 percent by mass or more.
4. A process for producing an aviation fuel base oil comprising blending an aviation fuel base oil produced by the process according to claim 1 and an aviation fuel base oil produced by refining crude oil.
5. The process according to claim 1 , wherein the Group 8 element in step (b) is selected from the group consisting of Pd, Pt, Rh, Ir and Ni.