Ink composition for making a conductive silver structure
View Patent ↗An ink composition for making a conductive silver structure comprises a silver salt and a complex of (a) a complexing agent and a short chain carboxylic acid or (b) a complexing agent and a salt of a short chain carboxylic acid, according to one embodiment. A method for making a silver structure entails combining a silver salt and a complexing agent, and then adding a short chain carboxylic acid or a salt of the short chain carboxylic acid to the combined silver salt and a complexing agent to form an ink composition. A concentration of the complexing agent in the ink composition is reduced to form a concentrated formulation, and the silver salt is reduced to form a conductive silver structure, where the concentrated formulation and the conductive silver structure are formed at a temperature of about 120° C. or less.
1. An ink composition for making a conductive silver structure, the ink composition comprising:
a silver salt; and
a complex of (a) a complexing agent and a short chain carboxylic acid, or (b) a complexing agent and a salt of a short chain carboxylic acid.
2. The ink composition of claim 1 , wherein the short chain carboxylic acid is selected from the group consisting of formic acid, acetic acid, propionic acid, pentanoic acid, and butyric acid.
3. The ink composition of claim 2 , wherein the short chain carboxylic acid is formic acid.
4. The ink composition of claim 1 , wherein the complexing agent is selected from the group consisting of an alkyl amine and ammonia.
5. The ink composition of claim 4 , wherein the alkyl amine is selected from the group consisting of methylamine, ethylamine, propylamine, butylamine, and amylamine.
6. The ink composition of claim 1 , wherein the silver salt is selected from the group consisting of silver acetate, silver formate, silver carbonate, silver fluoride, silver nitrate, silver nitrite, silver chloride, silver bromide, silver iodide, silver phosphate, and silver oxide.
7. The ink composition of claim 1 , further comprising methylenediamine or ethylenediamine.
8. The ink composition of claim 1 , further comprising a solvent selected from the group consisting of ethanol, butanol, propylene glycol, water, and combinations thereof.
9. The ink composition of claim 1 , wherein the ink composition has a viscosity of between about 1 mPa·s and about 10 6 mPa·s at 23° C. under low shear conditions.
10. The ink composition of claim 1 , wherein the silver salt is silver acetate,
wherein the complexing agent is selected from the group consisting of methylamine, ethylamine, propylamine, butylamine, amylamine, and ammonia, and
wherein the short chain carboxylic acid is formic acid.
11. The ink composition of claim 10 , further comprising ethylenediamine.
12. The ink composition of claim 10 , further comprising a solvent selected from the group consisting of ethanol, butanol, propylene glycol, water, and combinations thereof.
13. The ink composition of claim 1 , wherein the ink composition comprises water and an alcohol.
14. The ink composition of claim 1 , wherein the complexing agent comprises a short chain diamine, and at least one of an alkyl amine and ammonia.
15. The ink composition of claim 14 , wherein the short chain diamine comprises at least one of methylenediamine and/or ethylenediamine.
16. The ink composition of claim 1 , wherein the complexing agent comprises an alkyl amine and a short chain diamine, and wherein the ratio of the alkyl amine to the short chain diamine is in a range from about 4:1 to about 1:4 on a volume:volume basis.
17. The ink composition of claim 1 , wherein each of the complexing agent and the short chain carboxylic acid has a boiling point of about 120° C. or less.
18. The ink composition of claim 10 , wherein the complexing agent further comprises a short chain diamine.
19. The ink composition of claim 18 , wherein the short chain diamine comprises methyldiamine, ethylenediamine, or both.
20. The ink composition of claim 1 , wherein the ink composition is substantially free of elemental silver particles.
21. The ink composition of claim 1 , comprising the complexing agent and the silver salt a molar ratio not less than 4:1.
22. An ink composition for making a conductive silver structure, the ink composition comprising:
a silver salt;
a complexing agent for dissolving the silver salt, the complexing agent not being a reducing agent for the silver salt; and
an acid for complexing with the complexing agent and reducing the silver salt;
wherein each of the complexing agent and the acid has a boiling point of about 120° C. or less.
23. The ink composition of claim 22 , further comprising a solvent having a boiling point of about 120° C. or less.
24. The ink composition of claim 22 , wherein the complexing agent comprises a short chain diamine, and at least one of an alkyl amine and ammonia.