Invert emulsion fluids
Invert emulsion fluids comprising a fatty dimer diamine having 28 to 48 carbon atoms per molecule and an acid or an acid derivative and methods of using such invert emulsion fluids for the treatment of at least a portion of a subterranean formation are provided. The invert emulsion fluids can be suitable for use as, for example, packer fluids and drilling fluids.
1. A method comprising contacting at least a portion of a subterranean formation with an invert emulsion fluid comprising a rheology modifier comprising a fatty dimer diamine having 28 to 48 carbon atoms per molecule and an acid or an acid derivative, wherein the invert emulsion fluid has a sag factor of less than 0.53 and exhibits oil separation of less than 0.1% after static aging for seven days.
2. The method of claim 1 , wherein the invert emulsion fluid has a yield point greater than about 50 lb/100 ft 2 .
3. The method of claim 1 , wherein the invert emulsion fluid is formulated without the addition of organophilic clays or lignites, and organophilic clays and lignites are not added to the fluid during use.
4. The method of claim 1 , wherein the acid is adipic acid and the fatty dimer diamine has the following chemical structure:
5. The method of claim 4 , wherein the adipic acid is present in a concentration of between about 0.25 ppb to about 10 ppb and the fatty dimer diamine is present in a concentration of between about 0.25 ppb to about 18 ppb.
6. The method of claim 5 , wherein the adipic acid is present in a concentration of between about 4 ppb to about 6 ppb and the fatty dimer diamine present in a concentration of between about 1 ppb to about 3 ppb.
7. The method of claim 1 , wherein the 10 second gel strength at 120° F. is greater than about 50 lb/100 ft2.
8. The method of claim 1 , wherein the invert emulsion fluid has a yield point greater than about 30 lb/100 ft 2 .
9. The method of claim 1 , the method further comprising contacting at least a portion of an annulus of a wellbore with the invert emersion fluid.
10. The method of claim 9 , wherein the acid is adipic acid and the fatty dimer diamine has the following chemical structure:
11. The method of claim 10 , wherein the adipic acid is present in a concentration of between about 0.25 ppb to about 10 ppb and the fatty dimer diamine is present in a concentration of between about 0.25 ppb to about 18 ppb.
12. The method of claim 9 , wherein the invert emulsion fluid has a yield point greater than about 30 lb/100 ft2.
13. The method of claim 1 , wherein the acid is selected from the group of acids consisting of: lactic acid; formic acid; acrylic acid; acetic acid; chloroacetic acid;
dichloroacetic acid; trichloroacetic acid; trifluoroacetic acid; propanoic acid; butyric acid;
pentanoic acid; hexanoic acid; heptanoic acid; oxalic acid; malonic acid; succinic acid; glutaric acid; adipic acid; pimelic acid; suberic acid; azelaic acid; sebacic acid; maleic acid; fumaric acid;
aspartic acid; citric acid; isocitric acid; aconitic acid; tartaric acid; benzoic acid; p-amino benzoic acid; phthalic acid; terephthalic acid; trimesic acid; sulfuric acid; sulphinic acid; sulphamic acid;
sulfonic acid; nitric acid; hydrofluoric acid; hydrochloric acid; phosphinic acid; phosphoric acid;
phosphonic acid; an organosulfonic acid; an organophosphoric acid; boric acid; boronic acid;
carboxylic acid; para toluene sulphonic acid; vinyl phosphonic acid; and any combination thereof.
14. The method of claim 9 , wherein contacting at least a portion of the annulus of the wellbore comprises contacting a swellable packer or bridge packer.