Carbon nanosheets
There is disclosed a combined hydrothermal and activation process that uses hemp bast fiber as the precursor to achieve graphene-like carbon nanosheets, a carbon nanosheet comprising carbonized crystalline cellulose, a carbon nanosheet formed by carbonizing crystalline cellulose, a capacitative structure comprises interconnected carbon nanosheets of carbonized crystalline cellulose, a method of forming a nanosheet comprising carbonizing crystalline cellulose to create carbonized crystalline cellulose. The interconnected two-dimensional carbon nanosheets also contain very high levels of mesoporosity.
1. A graphene-like carbon nanosheet comprising carbonized crystalline cellulose, macroporous voids of 1-2 μm in diameter, and mesopores of 2-5 nm in diameter, wherein the carbonized crystalline cellulose comprises carbonized exfoliated crystalline cellulose hemp fibrils.
2. The graphene-like carbon nanosheet of claim 1 , wherein the carbonized crystalline cellulose comprises activated carbonized crystalline cellulose fibrils.
3. The graphene-like carbon nanosheet of claim 1 , wherein the activated carbonized crystalline cellulose comprises activated hydrothermal carbonized crystalline cellulose.
4. The graphene-like carbon nanosheet of claim 1 , wherein the graphene-like carbon nanosheet is between 10 and 30 nanometers thick.
5. The carbon nanosheet of claim 1 , wherein the graphene-like carbon nanosheet is at least partly graphitized, and wherein the carbon nanosheet is interconnected.
6. A graphene-like carbon nanosheet formed by carbonizing crystalline cellulose, wherein the graphene-like carbon nanosheet comprises macroporous voids of 1-2 μm in diameter and mesopores of 2-5 nm in diameter, wherein the crystalline cellulose comprises exfoliated crystalline cellulose hemp fibrils.
7. The graphene-like carbon nanosheet of claim 6 , wherein the carbonizing comprises a hydrothermal treatment.
8. The graphene-like carbon nanosheet of claim 6 , wherein the carbonizing comprises activating.
9. The graphene-like carbon nanosheet of claim 8 , wherein the activating comprises alkali activating.
10. The graphene-like carbon nanosheet of claim 6 , wherein the graphene-like carbon nanosheet is between 10 and 30 nanometers thick.
11. The graphene-like carbon nanosheet of claim 6 , wherein the graphene-like carbon nanosheet is at least partly graphitized.
12. A capacitative structure comprising interconnected graphene-like carbon nanosheets of carbonized crystalline cellulose, wherein the graphene-like carbon nanosheets comprise macroporous voids of 1-2 μm in diameter, and mesopores of 2-5 nm in diameter, wherein the carbonized crystalline cellulose comprises exfoliated carbonized crystalline cellulose hemp fibrils.
13. The capacitative structure of claim 12 , wherein the carbonized crystalline cellulose comprises activated hydrothermal carbonized crystalline cellulose.
14. The capacitative structure of claim 12 , wherein the graphene-like carbon nanosheet is between 10 and 30 nanometers thick.
15. The capacitative structure of claim 12 , wherein the graphene-like carbon nanosheet is at least partly graphitized.