Nonaqueous electrolyte secondary battery and manufacturing method thereof
The present invention provides a method of manufacturing a nonaqueous electrolyte secondary battery in which graphite fissuring during rolling of the negative electrode mixture layer is prevented and a deterioration in the performance of the battery is thereby suppressed. The manufacturing method provided by the present invention is a method of manufacturing a nonaqueous electrolyte secondary battery that has a positive electrode and a negative electrode, and includes: a coating step of coating a current collector 22 with a positive electrode mixture 23 containing graphite 25 ; a magnetic field application step of applying, to the negative electrode mixture 23 made to coat the current collector 22 in the coating step, a magnetic field in which the magnetic lines of force are oriented in one direction parallel to the plane of the current collector 22 coated with the negative electrode mixture 23 ; a drying step of drying the negative electrode mixture 23 to which the magnetic field has been applied in the magnetic field application step; and a rolling step of rolling a negative electrode mixture layer resulted from the drying step.
1. A method of manufacturing a nonaqueous electrolyte secondary battery that has a positive electrode and a negative electrode, the method comprising:
a coating step of coating a current collector with a graphite-containing negative electrode mixture;
a magnetic field application step of applying, to the negative electrode mixture made to coat the current collector in the coating step, a magnetic field in which magnetic lines of force are oriented in one direction parallel to a wide side plane of the current collector coated with the negative electrode mixture;
a drying step of drying the negative electrode mixture to which the magnetic field has been applied in the magnetic field application step; and
a rolling step of rolling a negative electrode mixture layer resulted from the drying step,
wherein the current collector is an elongated current collector and, in the magnetic field application step, a magnetic field is applied in which the magnetic lines of force are oriented in a width direction of the elongated current collector, wherein the width direction is defined as the direction that is orthogonal to the length direction of the elongated current collector and that runs from one long edge of the current collector to the other long edge.
2. The method of manufacturing a nonaqueous electrolyte secondary battery according to claim 1 , wherein, in the magnetic field application step, a magnetic field is first applied in which the magnetic lines of force are oriented in a direction orthogonal to the wide side plane of the current collector and a magnetic field is thereafter applied in which the magnetic lines of force are oriented in one direction parallel to the wide side plane of the current collector.
3. The method of manufacturing a nonaqueous electrolyte secondary battery according to claim 1 , wherein the density of the negative electrode mixture layer after the rolling step is at least 1.1 g/cm 3 .
4. The method of manufacturing a nonaqueous electrolyte secondary battery according to claim 1 , wherein the strength of the magnetic field applied to the negative electrode mixture in the magnetic field application step is at least 0.5 T.
5. The method of manufacturing a nonaqueous electrolyte secondary battery according to claim 1 , wherein the graphite is flat flake graphite.
6. A nonaqueous electrolyte secondary battery that has a positive electrode and a negative electrode, wherein
the negative electrode has an elongated current collector and a negative electrode mixture layer that contains at least graphite and is formed in a length direction of the current collector,
the graphite in the negative electrode mixture layer is arranged such that the (002) plane of at least 50 mass % of the graphite is parallel to a width direction of the current collector, wherein the width direction is defined as the direction that is orthogonal to the length direction of the elongated current collector and that runs from one long edge of the current collector to the other long edge, and the graphite in the negative electrode mixture layer is arranged such that the (002) plane of at least 50 mass % of the graphite is orthogonal to a wide side plane of the current collector and parallel to the width direction of the current collector.
7. The nonaqueous electrolyte secondary battery according to claim 6 , wherein the density of the negative electrode mixture layer is at least 1.1 g/cm 3 .