IP Library Granted Patent US 9,493,810
Granted Patent B2
US 9,493,810 · App. 13/838,895 · Granted Nov 15, 2016

5-ALA for detection of brain tumors

Inventor: Alan M. Ezrin (Miami, FL)
Assignee: PIOMA, INC.
C12Q1/26C12Q1/48C12Q1/527G01N33/57484
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Quick Facts
Patent No.
US 9,493,810
App. No.
13/838,895
Granted
Nov 15, 2016
Kind
B2
Abstract

The present disclosure relates to methods for detecting brain tumors and assessing the recurrence of such tumors by administering a pharmaceutical composition comprising 5-aminolevulinic acid (5-ALA) and detecting the conversion of 5-ALA to protoporphyrin IX (PPIX) associated with brain-derived microparticles.

Claims (26)

1. A method for detecting a WHO grade III or grade IV brain tumor, wherein the method comprises

administering a pharmaceutical composition comprising 5-aminolevulinic acid (5-ALA) to a subject;

isolating microvesicles from a biological sample from the subject; and

detecting the level of conversion of 5-ALA to protoporphyrin IX (PPIX) associated with microvesicles shed from the WHO grade III or grade IV brain tumor in the biological sample from the subject, thereby detecting the WHO grade III or grade IV brain tumor.

2. The method of claim 1 , wherein the subject was previously treated for a brain tumor.

3. The method of claim 2 , wherein the subject was previously treated for a WHO grade III or grade IV brain tumor.

4. The method of claim 1 , wherein the WHO grade III or grade IV tumor is selected from the group consisting of anaplastic astrocytoma, glioblastoma, anaplastic oligodendroglioma, anaplastic ependymoma, anaplastic oligoastrocytoma, polar spongioblastoma, astroblastoma, and gliomatosis cerebri.

5. The method of claim 1 , wherein the WHO grade III or grade IV brain tumor is glioblastoma (GBM).

6. The method of claim 1 , wherein the biological sample is whole blood.

7. The method of claim 1 , wherein the biological sample is plasma or serum.

8. The method of claim 1 , wherein the biological sample is cerebrospinal fluid.

9. The method of claim 1 , wherein the biological sample is selected from the group consisting of urine, tears, milk, lymph fluid, synovial fluid, bronchoalveolar lavage, amniotic fluid, saliva, ocular fluid, ascites, and respiratory droplets.

10. The method of claim 1 , wherein the pharmaceutical composition is Gliolan™.

11. The method of claim 1 , wherein the pharmaceutical composition comprising 5-ALA is administered orally.

12. The method of claim 1 , wherein the pharmaceutical composition comprising 5-ALA is administered intratumorally.

13. The method of claim 1 , wherein the pharmaceutical composition comprises 5-ALA at a concentration of 5 mg/kg, 10 mg/kg, 20 mg/kg or 30 mg/kg.

14. The method of claim 1 , wherein the pharmaceutical composition comprising 5-ALA is administered for three, four, or five hours.

15. The method of claim 1 , wherein the level of conversion of 5-ALA to PPIX is detected by measuring fluorescence.

16. The method of claim 1 , wherein the level of conversion of 5-ALA to PPIX is detected by measuring the level of a metabolite along the 5-ALA to PPIX conversion pathway.

17. The method of claim 1 , wherein the level of conversion of 5-ALA to PPIX is detected by measuring the level of a converting enzyme.

18. The method of claim 17 , wherein the converting enzyme is coproporphyrinogen oxidase (CPOX).

19. A method for assessing the recurrence of WHO grade III and grade IV brain tumors, wherein the method comprises

administering a pharmaceutical composition comprising 5-aminolevulinic acid (5-ALA) to a subject;

isolating microvesicles from a biological sample from the subject; and

assessing the recurrence of WHO grade III and grade IV brain tumors by detecting 5-ALA associated with microvesicles shed from the WHO grade III or grade IV brain tumor in the biological sample from the subject.

20. The method of claim 19 , wherein the recurrence of WHO grade III and grade IV brain tumors is assessed by detecting the quantity of 5-ALA associated with the microvesicles shed from the WHO grade III or grade IV brain tumor.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2016
From: EZRIN, ALAN M.
To: PIOMA, INC.
Reel/Frame 039680/0280 →
Continuity (2)
Provisional Application 61656945 · Jun 7, 2012
Related Publication 20130330753A1 · Dec 12, 2013