Process for preparing polyurea microcapsules
The present invention relates to a process for producing microcapsules with a polyurea wall, as well as to the microcapsules themselves and consumer products comprising these microcapsules. The process of the invention uses 3,5-diamino-1,2,4-triazole as a specific polyamine for forming the wall with the polyisocyanate.
1. A process for the preparation of polyurea microcapsules comprising
a) dissolving at least one polyisocyanate comprising at least two isocyanate functional groups, in a perfume to form a solution;
b) adding to the solution obtained in step a) an aqueous solution of an emulsifier or of a colloidal stabilizer;
c) adding to the mixture obtained in step b) 3,5-diamino-1,2,4-triazole to form a polyurea wall with the polyisocyanate wherein the polyurea wall encapsulates the perfume, so as to form a microcapsules slurry;
wherein the process is carried out without any addition of amino acid; and
wherein the microcapsules have greater stability in consumer products and improved perfume release compared to microcapsules that are not made with 3,5-diamino-1,2,4-triazole with the stability of the microcapsules being determined as not more than 60% of the perfume leaking out of the microcapsules when incorporated in a consumer product for a particular storage time and temperature, with the microcapsules being stable after 4 weeks storage at 38° C. in fabric softeners, detergents, body washes, deodorants or antiperspirants, for least 2 weeks storage at 40° C. in shampoos or hair conditioners, and for at least 2 days at 25° C. in body lotions.
2. A process according to claim 1 , for the preparation of polyurea microcapsules comprising:
a) dissolving at least one polyisocyanate comprising at least two isocyanate functional groups, in a perfume to form a solution, wherein the at least one polyisocyanate is in the form of a mixture of at least one aliphatic polyisocyanate and of at least one aromatic polyisocyanate, both comprising at least two isocyanate functional groups;
b) adding to the solution obtained in step a) an aqueous solution of an emulsifier or of a colloidal stabilizer;
c) adding to the mixture obtained in step b) 3,5-diamino-1,2,4-triazole to form a polyurea wall with the polyisocyanates wherein the polyurea wall encapsulates the perfume, so as to form a microcapsules slurry;
wherein the process is carried out without any addition of amino acid; and
wherein the microcapsules have greater stability in consumer products and improved perfume release compared to microcapsules that are not made with 3,5-diamino-1,2,4-triazole.
3. The process according to claim 2 , wherein the aliphatic polyisocyanate and the aromatic polyisocyanate are used in a respective molar ratio ranging from 80:20 to 10:90.
4. The process according to claim 3 , wherein the aliphatic polyisocyanate and the aromatic polyisocyanate are used in a respective molar ratio comprised between 60:40 and 20:80 and the polyurea microcapsules have an average diameter between 1 and 50 μm, between 5 and 35 μm, or between 5 and 20 μm.
5. The process according to claim 1 , wherein there is used an amount of between 25 and 60% of perfume, these percentages being defined by weight relative to the total weight of the obtained microcapsules slurry.
6. The process according to claim 1 , wherein the polyisocyanates comprise at least three isocyanate functional groups.
7. The process according to claim 2 , wherein the aromatic polyisocyanate comprises a phenyl, a toluyl, a xylyl, a naphthyl or a diphenyl moiety.
8. The process according claim 2 , wherein the aromatic polyisocyanate is selected from the group consisting of a polyisocyanurate of toluene diisocyanate, a trimethylol propane-adduct of toluene diisocyanate and a trimethylol propane-adduct of xylylene diisocyanate.
9. The process according to claim 2 , wherein the aliphatic polyisocyanate is selected from the group consisting of a trimer of hexamethylene diisocyanate, a trimer of isophorone diisocyanate and a biuret of hexamethylene diisocyanate.
10. The process according to claim 2 , wherein the mixture of an aliphatic polyisocyanate and of an aromatic polyisocyanate is a mixture of a biuret of hexamethylene diisocyanate with a trimethylol propane-adduct of xylylene diisocyanate.
11. The process according to claim 1 , wherein the polyisocyanate is used in an amount comprised between 2 and 20% by weight, relative to the total weight of the solution obtained in step a).
12. The process according to claim 1 , wherein the colloidal stabilizer is polyvinyl alcohol, a cellulose derivative, polyethylene oxide, a copolymer of polyethylene oxide and polyethylene or polypropylene oxide, a copolymer of acrylamide and acrylic acid, a cationic polymer or a mixture thereof.
13. The process according to claim 12 , wherein the colloidal stabilizer is polyvinyl alcohol or a cationic polymer, which is a copolymer of vinylpyrrolidone and of a quaternized vinylimidazol, or a mixture thereof.